The Removal of Naproxen from Aqueous Media by Using PAMPSA Doped Polyaniline

Abstract

In this study, the removal of naproxen from aqueous media was investigated using PAMPSA doped Polyaniline as adsorbent. Adsorbent amount (0.025-0.3 g / 50 ml), pH (3-9), contact time (1-1440 min), initial concentration (20-150 ppm) and temperature (25-50 ° C) were selected as parameters. The characterization of the adsorbent performed by using SEM (morphological analysis), FT-IR (functional group analysis) and XRD (minerological contents) techniques. The maximum removal efficiency of the adsorption process was found to be 68.99% for pH 7, 25 ° C temperature, 30 min contact time, 0.05g / 50 ml adsorbent amount and 150 ppm optimum conditions. It was determined that the adsorption kinetics matched with the pseudo-second order kinetic model. It has been determined that NPX adsorption on PAMPSA doped Polyaniline fits the isotherm models of Langmuir, Freundlich, Temkin and Harkins-Jura. Temkin R2 = 0.99> Freundlich R2 = 0.97> Langmuir R2 = 0.95> Harkins-Jura R2 = 0.86. It was determined that NPX adsorption best fit the Temkin isotherm model. The negative ΔH ° value indicates that the adsorption process is exothermic, the positive ΔS ° value indicates a random increase during the adsorption process at the solid / solution interface, and the positive ΔG ° value indicates that the adsorption process does not occur spontaneously.

Keywords

• Naproxen
• Polyaniline
• PAMPSA
• Adsorption

PAMPSA Yüklenmiş Polianilin Kullanılarak Sulu Ortamdan Naproksen Giderimi

Öz

Bu çalışmada adsorban olarak PAMPSA yüklenmiş polianilinin kullanılarak sulu ortamdan naproksen giderimi incelenmiştir. Adsorban miktarı (0.025-0.3 g/50 ml), pH(3-9), temas süresi (1-1440 dk), başlangıç konsantrasyonu (20-150 ppm) ve sıcaklık (25-50 °C) parametreler olarak seçilmiştir. Adsorbanın morfolojik yapıları SEM, fonksiyonel grup analizleri FT-IR, minerolojik içerikleri XRD teknikleri kullanılarak belirlenmiştir. pH 7, 25°C sıcaklık, 30 dk temas süresi, 0.05 g/50 ml adsorban miktarı ve 150 ppm en uygun koşullar için adsorpsiyon prosesi maksimum giderim veriminin %68.99 olduğu tespit edilmiştir. Adsorpsiyon kinetiğinin yalancı II. derece kinetik modelle eşleştiği belirlenmiştir. PAMPSA Yüklenmiş Polianilin üzerine NPX adsorpsiyonunun Langmuir, Freundlich, Temkin ve Harkins-Jura izoterm modellerine uyduğu belirlenmiştir. Temkin R2=0.99 > Freundlich R2=0.97 > Langmuir R2=0.95 > Harkins-Jura R2=0.86’dir. NPX adsorpsiyonunun en iyi Temkin izoterm modeline uyduğu belirlenmiştir. Negatif ΔH° değeri adsorpsiyon prosesinin ekzotermik olduğunu, positif ΔS° değerinin katı/çözelti arayüzünde adsorpsiyon işlemi sırasında rastgele bir artış olduğunu ve pozitif ΔG° değeri ise adsorpsiyon prosesinin kendiliğinden meydana gelmediğini göstermektedir.

Anahtar Kelimeler

• Naproksen
• Polianilin
• PAMPSA
• Adsorpsiyon

Kaynakça

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