The Removal of Naproxen from Aqueous Media by Using PAMPSA Doped Polyaniline

Yıl 2021, Sayı: 27, 177 - 185, 30.11.2021

Adem Sarıhan

https://doi.org/10.31590/ejosat.949645

Öz

In this study, the removal of naproxen from aqueous media was investigated using PAMPSA doped Polyaniline as adsorbent. Adsorbent amount (0.025-0.3 g / 50 ml), pH (3-9), contact time (1-1440 min), initial concentration (20-150 ppm) and temperature (25-50 ° C) were selected as parameters. The characterization of the adsorbent performed by using SEM (morphological analysis), FT-IR (functional group analysis) and XRD (minerological contents) techniques. The maximum removal efficiency of the adsorption process was found to be 68.99% for pH 7, 25 ° C temperature, 30 min contact time, 0.05g / 50 ml adsorbent amount and 150 ppm optimum conditions. It was determined that the adsorption kinetics matched with the pseudo-second order kinetic model. It has been determined that NPX adsorption on PAMPSA doped Polyaniline fits the isotherm models of Langmuir, Freundlich, Temkin and Harkins-Jura. Temkin R2 = 0.99> Freundlich R2 = 0.97> Langmuir R2 = 0.95> Harkins-Jura R2 = 0.86. It was determined that NPX adsorption best fit the Temkin isotherm model. The negative ΔH ° value indicates that the adsorption process is exothermic, the positive ΔS ° value indicates a random increase during the adsorption process at the solid / solution interface, and the positive ΔG ° value indicates that the adsorption process does not occur spontaneously.

Anahtar Kelimeler

Naproxen , Polyaniline , PAMPSA , Adsorption

PAMPSA Yüklenmiş Polianilin Kullanılarak Sulu Ortamdan Naproksen Giderimi

Öz

Bu çalışmada adsorban olarak PAMPSA yüklenmiş polianilinin kullanılarak sulu ortamdan naproksen giderimi incelenmiştir. Adsorban miktarı (0.025-0.3 g/50 ml), pH(3-9), temas süresi (1-1440 dk), başlangıç konsantrasyonu (20-150 ppm) ve sıcaklık (25-50 °C) parametreler olarak seçilmiştir. Adsorbanın morfolojik yapıları SEM, fonksiyonel grup analizleri FT-IR, minerolojik içerikleri XRD teknikleri kullanılarak belirlenmiştir. pH 7, 25°C sıcaklık, 30 dk temas süresi, 0.05 g/50 ml adsorban miktarı ve 150 ppm en uygun koşullar için adsorpsiyon prosesi maksimum giderim veriminin %68.99 olduğu tespit edilmiştir. Adsorpsiyon kinetiğinin yalancı II. derece kinetik modelle eşleştiği belirlenmiştir. PAMPSA Yüklenmiş Polianilin üzerine NPX adsorpsiyonunun Langmuir, Freundlich, Temkin ve Harkins-Jura izoterm modellerine uyduğu belirlenmiştir. Temkin R2=0.99 > Freundlich R2=0.97 > Langmuir R2=0.95 > Harkins-Jura R2=0.86’dir. NPX adsorpsiyonunun en iyi Temkin izoterm modeline uyduğu belirlenmiştir. Negatif ΔH° değeri adsorpsiyon prosesinin ekzotermik olduğunu, positif ΔS° değerinin katı/çözelti arayüzünde adsorpsiyon işlemi sırasında rastgele bir artış olduğunu ve pozitif ΔG° değeri ise adsorpsiyon prosesinin kendiliğinden meydana gelmediğini göstermektedir.

Anahtar Kelimeler

Naproksen , Polianilin , PAMPSA , Adsorpsiyon

Teşekkür

Naproksen sodyumun (NPX) tedariğindeki destekleri sebebiyle Abdi İbrahim ilaç firmasına teşekkür ederim.

Kaynakça

• Ahmad, M., Fatima, M., Hossain, M., & Mondal, A. (2018). Evaluation of naproxen-induced oxidative stress, hepatotoxicity and in-vivo genotoxicity in male Wistar rats. Journal Of Pharmaceutical Analysis, 8(6), 400-406. doi: 10.1016/j.jpha.2018.04.002
• Amura, I., Shahid, S., Sarihan, A., Shen, J., Patterson, D. and Emanuelsson, E., (2021). Fabrication of self-doped sulfonated polyaniline membranes with enhanced antifouling ability and improved solvent resistance. Journal of Membrane Science, 620, p.117712.
• Bajpai, S., & Bhowmik, M. (2010). Adsorption of diclofenac sodium from aqueous solution using polyaniline as a potential sorbent. I. Kinetic studies. Journal Of Applied Polymer Science, n/a-n/a. doi: 10.1002/app.32263
• Binelli, A., Magni, S., Soave, C., Marazzi, F., Zuccato, E., & Castiglioni, S. et al. (2014). The biofiltration process by the bivalve D. polymorpha for the removal of some pharmaceuticals and drugs of abuse from civil wastewaters. Ecological Engineering, 71, 710-721. doi: 10.1016/j.ecoleng.2014.08.004
• Boyd, G., Zhang, S., & Grimm, D. (2005). Naproxen removal from water by chlorination and biofilm processes. Water Research, 39(4), 668-676. doi: 10.1016/j.watres.2004.11.013
• Ding, T., Lin, K., Yang, B., Yang, M., Li, J., Li, W., & Gan, J. (2017). Biodegradation of naproxen by freshwater algae Cymbella sp. and Scenedesmus quadricauda and the comparative toxicity. Bioresource Technology, 238, 164-173. doi: 10.1016/j.biortech.2017.04.018
• Erhayem, M., Al-Tohami, F., Mohamed, R. and Ahmida, K., (2015). Isotherm, Kinetic and Thermodynamic Studies for the Sorption of Mercury (II) onto Activated Carbon from <i>Rosmarinus officinalis</i> Leaves. American Journal of Analytical Chemistry, 06(01), pp.1-10.
• Feng, L., van Hullebusch, E., Rodrigo, M., Esposito, G., & Oturan, M. (2013). Removal of residual anti-inflammatory and analgesic pharmaceuticals from aqueous systems by electrochemical advanced oxidation processes. A review. Chemical Engineering Journal, 228, 944-964. doi: 10.1016/j.cej.2013.05.061
• Freundlich, H., (1907). Über die Adsorption in Lösungen. Zeitschrift für Physikalische Chemie, 57U(1). Górny, D., Guzik, U., Hupert-Kocurek, K., & Wojcieszyńska, D. (2019). Naproxen ecotoxicity and biodegradation by Bacillus thuringiensis B1(2015b) strain. Ecotoxicology And Environmental Safety, 167, 505-512. doi: 10.1016/j.ecoenv.2018.10.067
• Gribkova, O., Nekrasov, A., Trchova, M., Ivanov, V., Sazikov, V., Razova, A., Tverskoy, V. and Vannikov, A., (2011). Chemical synthesis of polyaniline in the presence of poly(amidosulfonic acids) with different rigidity of the polymer chain. Polymer, 52(12), pp.2474-2484.
• Kar, F., Yılgın, M. And Duranay, N., (2019). Aktifleştirilmiş zeolit ve polivinilprolidon kullanılarak sulu çözeltiden metilen mavisinin giderilmesinde adsorpsiyon parametrelerinin belirlenmesi. Düzce Üniversitesi Bilim ve Teknoloji Dergisi,.
• Kawashima, H. and Goto, H., (2011). Preparation and Properties of Polyaniline in the Presence of Trehalose. Soft Nanoscience Letters, 01(03), pp.71-75.
• Kızıltaş, H., (2021). Orange G’nin Sulu Çözeltilerden Uzaklaştırılması için α-Fe2O3 Nanopartiküllerinin Adsorban Olarak Kullanılması; Adsorpsiyon, Kinetik ve Termodinamik Özellikleri. Avrupa Bilim ve Teknoloji Dergisi (21). 43-52.
• Szreter, S. (2004). Industrialization and health. British Medical Bulletin, 69(1), 75-86. doi: 10.1093/bmb/ldh005
• Kucuk, İ., & Sarısakal, İ. (2020). Potansiyel Bir Adsorban Olarak Perlit İçeren Polisakkarit Esaslı Küresel Hibrit Tanecikler. Avrupa Bilim ve Teknoloji Dergisi, (20), 216-222. doi: 10.31590/ejosat.774982
• Lach, J., & Szymonik, A. (2019). Adsorption of Naproxen Sodium from Aqueous Solutions on Commercial Activated Carbons. Journal Of Ecological Engineering, 20(10), 241-251. doi: 10.12911/22998993/113419
• Langmuir, I., (1918). The Adsorptıon Of Gases On Plane Surfaces Of Glass, Mıca And Platınum. Journal of the American Chemical Society, 40(9), pp.1361-1403.
• Noutsopoulos, C., Koumaki, E., Mamais, D., Nika, M., Bletsou, A., & Thomaidis, N. (2015). Removal of endocrine disruptors and non-steroidal anti-inflammatory drugs through wastewater chlorination: The effect of pH, total suspended solids and humic acids and identification of degradation by-products. Chemosphere, 119, S109-S114. doi: 10.1016/j.chemosphere.2014.04.107
• Qurie, M., Khamis, M., Malek, F., Nir, S., Bufo, S., & Abbadi, J. et al. (2013). Stability and Removal of Naproxen and Its Metabolite by Advanced Membrane Wastewater Treatment Plant and Micelle-Clay Complex. CLEAN - Soil, Air, Water, 42(5), 594-600. doi: 10.1002/clen.201300179
• Sarihan, A. (2020). Development of high-permeable PSf/PANI-PAMPSA composite membranes with superior rejection performance. Materials Today Communications, 24, 101104. doi: 10.1016/j.mtcomm.2020.101104
• Sarihan, A., Shahid, S., Shen, J., Amura, I., Patterson, D., & Emanuelsson, E. (2019). Exploiting the electrical conductivity of poly-acid doped polyaniline membranes with enhanced durability for organic solvent nanofiltration. Journal Of Membrane Science, 579, 11-21. doi: 10.1016/j.memsci.2019.02.030
• Shen, J., Shahid, S., Amura, I., Sarihan, A., Tian, M. and Emanuelsson, E., (2018). Enhanced adsorption of cationic and anionic dyes from aqueous solutions by polyacid doped polyaniline. Synthetic Metals, 245, pp.151-159.
• Shen, J., Shahid, S., Sarihan, A., Patterson, D., & Emanuelsson, E. (2018). Effect of polyacid dopants on the performance of polyaniline membranes in organic solvent nanofiltration. Separation And Purification Technology, 204, 336-344. doi: 10.1016/j.seppur.2018.04.034
• Zhou, H. (2009). Populatıon Growth And Industrıalızatıon. Economic Inquiry, 47(2), 249-265. doi: 10.1111/j.1465-7295.2008.00151.x
• Zhu, S., Shi, M., Zhao, S., Wang, Z., Wang, J. and Wang, S., (2015). Preparation and characterization of a polyethersulfone/polyaniline nanocomposite membrane for ultrafiltration and as a substrate for a gas separation membrane. RSC Advances, 5(34), pp.27211-27223.