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ZnO-Kitosan Kompoziti ile Ağır Metal Giderimi

Yıl 2022, Cilt , Sayı 35, 603 - 609, 30.04.2022
https://doi.org/10.31590/ejosat.1094734

Öz

Çalışmada Allium cepa (A. cepa) kabukları kullanılarak yeşil sentez ile ZnO partikülleri sentezlendi ve kitosan (Ch) ile oluşturulan ZnO- Ch kompozitin Nikel (II) (Ni (II)) giderim potansiyeli incelendi. Sentezlenen ZnO-Ch kompozitin taramalı elektron mikroskopisi (SEM), Fourier transform infrared (FTIR) ve X-ışını difraksiyonu (XRD) ile karakterizasyonu gerçekleştirildi. Çalışmada ZnO-Ch kompoziti ile kesikli sistemde Ni (II) adsorpsiyonu için pH (2,0-6,0), sıcaklık (25-55 oC), adsorban miktarı (0,25-1,0 g/L),temas süresi (15-1440 dk) ve başlangıç kirletici derişimi (20-300 mg/L) incelenerek optimum giderim koşulları incelenmiştir. Elde edilen optium koşullar pH 5,0, sıcaklık 25 0C, adsorban miktarı 0,5 g/L, temas süresi 300 dakika (dk) olarak belirlenmiştir. Ni (II) gideriminde kompozitin maksimum adsorpsiyon kapasitesi Langmuir izoterm modeline göre 222,22 mg/g olarak hesaplandı. Yapılan sıcaklık çalışmalarında artan sıcaklık ile adsorpsiyon kapasitesinin düşmesi sistemin ekzotermik olduğunu gösterdi.

Kaynakça

  • Dananjaya, S. H. S., Kumar, R. S., Yang, M., Nikapitiya, C., Lee, J., & De Zoysa, M. (2018). Synthesis, characterization of ZnO-chitosan nanocomposites and evaluation of its antifungal activity against pathogenic Candida albicans. International journal of biological macromolecules, 108, 1281-1288.
  • Deliyanni, E. A., Lazaridis, N. K., Peleka, E. N., & Matis, K. A. (2004). Metals removal from aqueous solution by iron-based bonding agents. Environmental Science and Pollution Research, 11(1), 18-21.
  • Liu, D., Sun, D., & Li, Y. (2010). Removal of Cu (II) and Cd (II) from aqueous solutions by polyaniline on sawdust. Separation Science and Technology, 46(2), 321-329.
  • Liu, Z. R., & Zhou, S. Q. (2010). Adsorption of copper and nickel on Na-bentonite. Process safety and environmental protection, 88(1), 62-66.
  • Nguyen, N. V., Jeong, J., & Lee, J. C. (2013). Removal of chromium (VI) from the leachate of electronic scrap using non‐ionic Amberlite XAD‐7HP resin. Journal of Chemical Technology & Biotechnology, 88(6), 1014-1022.
  • Qiu, B., Xu, X. F., Deng, R. H., Xia, G. Q., Shang, X. F., & Zhou, P. H. (2019). Construction of chitosan/ZnO nanocomposite film by in situ precipitation. International journal of biological macromolecules, 122, 82-87.
  • Queiroz, M. F., Teodosio Melo, K. R., Sabry, D. A., Sassaki, G. L., & Rocha, H. A. O. (2014). Does the use of chitosan contribute to oxalate kidney stone formation?. Marine drugs, 13(1), 141-158.
  • Abdel-Ghani, N. T., El-Chaghaby, G. A., & Helal, F. S. (2015). Individual and competitive adsorption of phenol and nickel onto multiwalled carbon nanotubes. Journal of advanced research, 6(3), 405-415.
  • Alabbad, E. A. (2021). Efficacy assessment of natural zeolite containing wastewater on the adsorption behaviour of Direct Yellow 50 from; equilibrium, kinetics and thermodynamic studies. Arabian Journal of Chemistry, 14(4), 103041.
  • Barati, A., Asgari, M., Miri, T., & Eskandari, Z. (2013). Removal and recovery of copper and nickel ions from aqueous solution by poly (methacrylamide-co-acrylic acid)/montmorillonite nanocomposites. Environmental Science and Pollution Research, 20(9), 6242-6255.
  • Barkat, M., Chegrouche, S., Mellah, A., Bensmain, B., Nibou, D., & Boufatit, M. (2014). Application of algerian bentonite in the removal of cadmium (II) and chromium (VI) from aqueous solutions. Journal of Surface Engineered Materials and Advanced Technology, 2014.
  • Betiha, M. A., Moustafa, Y. M., Mansour, A. S., Rafik, E., & El-Shahat, M. F. (2020). Nontoxic polyvinylpyrrolidone-propylmethacrylate-silica nanocomposite for efficient adsorption of lead, copper, and nickel cations from contaminated wastewater. Journal of Molecular Liquids, 314, 113656.
  • Boran, F. (2021). Encapsulation of CuO nanoparticles inside the channels of the multi-walled carbon nanotubes functionalized with thermal stress. Diamond and Related Materials, 114, 108306.
  • Boran, F., TAŞKIRAN, İ., & Çetinkaya, S. (2019). Poli (sodyum 4-stiren sülfonat) Kaplı SnO2 Nanoparçacıklarının Sentezi, Karakterizasyonu ve Gaz Algılama Özelliklerinin İncelenmesi. Avrupa Bilim ve Teknoloji Dergisi, (17), 412-422.
  • Chang, Y. S., Au, P. I., Mubarak, N. M., Khalid, M., Jagadish, P., Walvekar, R., & Abdullah, E. C. (2020). Adsorption of Cu (II) and Ni (II) ions from wastewater onto bentonite and bentonite/GO composite. Environmental Science and Pollution Research, 27(26), 33270-33296.
  • Çınar, S., Kaynar, Ü. H., Aydemir, T., Kaynar, S. C., & Ayvacıklı, M. (2017). An efficient removal of RB5 from aqueous solution by adsorption onto nano-ZnO/Chitosan composite beads. International journal of biological macromolecules, 96, 459-465.
  • Erdem, S., Öztekin, M., & Açıkel, Y. S. (2021). Investigation of tetracycline removal from aqueous solutions using halloysite/chitosan nanocomposites and halloysite nanotubes/alginate hydrogel beads. Environmental Nanotechnology, Monitoring & Management, 16, 100576.
  • Gurel, L. (2010). senturk I, Bahadir T, Buyukgungor H (2010) Treatment of Nickel Plating Industrial Wastewater by Fungus Immobilized onto Rice Bran. J Microbial Biochem Technol, 2, 034-037.
  • Gürel, L. (2017). Applications of the biosorption process for nickel removal from aqueous solutions–A review. Chemical Engineering Communications, 204(6), 711-722.
  • Huang, C., Chung, Y. C., & Liou, M. R. (1996). Adsorption of Cu (II) and Ni (II) by pelletized biopolymer. Journal of Hazardous Materials, 45(2-3), 265-277.
  • Nesakumar, N., Rayappan, J. B. B., Jeyaprakas, B. G., & Krishnan, U. M. (2012). Influence of pH on structural morphology of ZnO nanoparticle. Journal of Applied Sciences, 12(16), 1758-1761.
  • Rajic, N., Stojakovic, D., Jovanovic, M., Logar, N. Z., Mazaj, M., & Kaucic, V. (2010). Removal of nickel (II) ions from aqueous solutions using the natural clinoptilolite and preparation of nano-NiO on the exhausted clinoptilolite. Applied Surface Science, 257(5), 1524-1532.
  • Shamhari, N. M., Wee, B. S., Chin, S. F., & Kok, K. Y. (2018). Synthesis and characterization of zinc oxide nanoparticles with small particle size distribution. Acta Chimica Slovenica, 65(3), 578-585.
  • Snell, F. D., & Snell, C. T. (1959). Colorimetric Methods of Ananysis: Including Photometric Methods by Forster Dee Snell. van Nostrand.
  • Yedurkar, S., Maurya, C., & Mahanwar, P. (2016). Biosynthesis of zinc oxide nanoparticles using ixora coccinea leaf extract—a green approach. Open Journal of Synthesis Theory and Applications, 5(1), 1-14.

Heavy Metal Removal with ZnO-Chitosan Composite

Yıl 2022, Cilt , Sayı 35, 603 - 609, 30.04.2022
https://doi.org/10.31590/ejosat.1094734

Öz

In the study, ZnO particles were synthesized by green synthesis using Allium cepa (A. cepa) shells and the Nickel (II) (Ni (II)) removal potential of the ZnO-Ch composite formed with chitosan (Ch) was investigated. Characterization of the synthesized ZnO-Ch composite was performed by scanning electron microscopy (SEM), Fourier transform infrared (FTIR) and X-ray diffraction (XRD). In the study, pH (2,0-6,0), temperature (25-55 oC), amount of adsorbent (0,,25-1,0 g/L), contact time for Ni (II) adsorption in batch system with ZnO-Ch composite. (15-1440 min) and initial pollutant concentration (20-300 mg/L) were examined and optimum removal conditions were investigated. The optimum conditions obtained were determined as pH 5,0, temperature 25 0C, amount of adsorbent 0,5 g/L, contact time 300 minutes (min). The maximum adsorption capacity of the composite in Ni (II) removal was calculated as 222,22 mg/g according to the Langmuir isotherm model. In temperature studies, the decrease in adsorption capacity with increasing temperature showed that the system was exothermic.

Kaynakça

  • Dananjaya, S. H. S., Kumar, R. S., Yang, M., Nikapitiya, C., Lee, J., & De Zoysa, M. (2018). Synthesis, characterization of ZnO-chitosan nanocomposites and evaluation of its antifungal activity against pathogenic Candida albicans. International journal of biological macromolecules, 108, 1281-1288.
  • Deliyanni, E. A., Lazaridis, N. K., Peleka, E. N., & Matis, K. A. (2004). Metals removal from aqueous solution by iron-based bonding agents. Environmental Science and Pollution Research, 11(1), 18-21.
  • Liu, D., Sun, D., & Li, Y. (2010). Removal of Cu (II) and Cd (II) from aqueous solutions by polyaniline on sawdust. Separation Science and Technology, 46(2), 321-329.
  • Liu, Z. R., & Zhou, S. Q. (2010). Adsorption of copper and nickel on Na-bentonite. Process safety and environmental protection, 88(1), 62-66.
  • Nguyen, N. V., Jeong, J., & Lee, J. C. (2013). Removal of chromium (VI) from the leachate of electronic scrap using non‐ionic Amberlite XAD‐7HP resin. Journal of Chemical Technology & Biotechnology, 88(6), 1014-1022.
  • Qiu, B., Xu, X. F., Deng, R. H., Xia, G. Q., Shang, X. F., & Zhou, P. H. (2019). Construction of chitosan/ZnO nanocomposite film by in situ precipitation. International journal of biological macromolecules, 122, 82-87.
  • Queiroz, M. F., Teodosio Melo, K. R., Sabry, D. A., Sassaki, G. L., & Rocha, H. A. O. (2014). Does the use of chitosan contribute to oxalate kidney stone formation?. Marine drugs, 13(1), 141-158.
  • Abdel-Ghani, N. T., El-Chaghaby, G. A., & Helal, F. S. (2015). Individual and competitive adsorption of phenol and nickel onto multiwalled carbon nanotubes. Journal of advanced research, 6(3), 405-415.
  • Alabbad, E. A. (2021). Efficacy assessment of natural zeolite containing wastewater on the adsorption behaviour of Direct Yellow 50 from; equilibrium, kinetics and thermodynamic studies. Arabian Journal of Chemistry, 14(4), 103041.
  • Barati, A., Asgari, M., Miri, T., & Eskandari, Z. (2013). Removal and recovery of copper and nickel ions from aqueous solution by poly (methacrylamide-co-acrylic acid)/montmorillonite nanocomposites. Environmental Science and Pollution Research, 20(9), 6242-6255.
  • Barkat, M., Chegrouche, S., Mellah, A., Bensmain, B., Nibou, D., & Boufatit, M. (2014). Application of algerian bentonite in the removal of cadmium (II) and chromium (VI) from aqueous solutions. Journal of Surface Engineered Materials and Advanced Technology, 2014.
  • Betiha, M. A., Moustafa, Y. M., Mansour, A. S., Rafik, E., & El-Shahat, M. F. (2020). Nontoxic polyvinylpyrrolidone-propylmethacrylate-silica nanocomposite for efficient adsorption of lead, copper, and nickel cations from contaminated wastewater. Journal of Molecular Liquids, 314, 113656.
  • Boran, F. (2021). Encapsulation of CuO nanoparticles inside the channels of the multi-walled carbon nanotubes functionalized with thermal stress. Diamond and Related Materials, 114, 108306.
  • Boran, F., TAŞKIRAN, İ., & Çetinkaya, S. (2019). Poli (sodyum 4-stiren sülfonat) Kaplı SnO2 Nanoparçacıklarının Sentezi, Karakterizasyonu ve Gaz Algılama Özelliklerinin İncelenmesi. Avrupa Bilim ve Teknoloji Dergisi, (17), 412-422.
  • Chang, Y. S., Au, P. I., Mubarak, N. M., Khalid, M., Jagadish, P., Walvekar, R., & Abdullah, E. C. (2020). Adsorption of Cu (II) and Ni (II) ions from wastewater onto bentonite and bentonite/GO composite. Environmental Science and Pollution Research, 27(26), 33270-33296.
  • Çınar, S., Kaynar, Ü. H., Aydemir, T., Kaynar, S. C., & Ayvacıklı, M. (2017). An efficient removal of RB5 from aqueous solution by adsorption onto nano-ZnO/Chitosan composite beads. International journal of biological macromolecules, 96, 459-465.
  • Erdem, S., Öztekin, M., & Açıkel, Y. S. (2021). Investigation of tetracycline removal from aqueous solutions using halloysite/chitosan nanocomposites and halloysite nanotubes/alginate hydrogel beads. Environmental Nanotechnology, Monitoring & Management, 16, 100576.
  • Gurel, L. (2010). senturk I, Bahadir T, Buyukgungor H (2010) Treatment of Nickel Plating Industrial Wastewater by Fungus Immobilized onto Rice Bran. J Microbial Biochem Technol, 2, 034-037.
  • Gürel, L. (2017). Applications of the biosorption process for nickel removal from aqueous solutions–A review. Chemical Engineering Communications, 204(6), 711-722.
  • Huang, C., Chung, Y. C., & Liou, M. R. (1996). Adsorption of Cu (II) and Ni (II) by pelletized biopolymer. Journal of Hazardous Materials, 45(2-3), 265-277.
  • Nesakumar, N., Rayappan, J. B. B., Jeyaprakas, B. G., & Krishnan, U. M. (2012). Influence of pH on structural morphology of ZnO nanoparticle. Journal of Applied Sciences, 12(16), 1758-1761.
  • Rajic, N., Stojakovic, D., Jovanovic, M., Logar, N. Z., Mazaj, M., & Kaucic, V. (2010). Removal of nickel (II) ions from aqueous solutions using the natural clinoptilolite and preparation of nano-NiO on the exhausted clinoptilolite. Applied Surface Science, 257(5), 1524-1532.
  • Shamhari, N. M., Wee, B. S., Chin, S. F., & Kok, K. Y. (2018). Synthesis and characterization of zinc oxide nanoparticles with small particle size distribution. Acta Chimica Slovenica, 65(3), 578-585.
  • Snell, F. D., & Snell, C. T. (1959). Colorimetric Methods of Ananysis: Including Photometric Methods by Forster Dee Snell. van Nostrand.
  • Yedurkar, S., Maurya, C., & Mahanwar, P. (2016). Biosynthesis of zinc oxide nanoparticles using ixora coccinea leaf extract—a green approach. Open Journal of Synthesis Theory and Applications, 5(1), 1-14.

Ayrıntılar

Birincil Dil Türkçe
Konular Mühendislik
Bölüm Makaleler
Yazarlar

Gamze TOPAL CANBAZ (Sorumlu Yazar)
Cumhuriyet Üniversitesi | Cumhuriyet University
0000-0001-7615-7627
Türkiye


Unsal AÇIKEL
SİVAS CUMHURİYET ÜNİVERSİTESİ
0000-0003-4969-8502
Türkiye


Yeşim SAĞ AÇIKEL
HACETTEPE ÜNİVERSİTESİ
0000-0002-3026-0933
Türkiye

Destekleyen Kurum Sivas Cumhuriyet Üniversitesi Bilimsel Araştırma Projeleri (CÜBAP) tarafından desteklenmiştir.
Proje Numarası M-669
Teşekkür Bu çalışma, Sivas Cumhuriyet Üniversitesi Bilimsel Araştırma Projeleri (CÜBAP) tarafından M-669 proje numarası ile desteklenmiştir.
Yayımlanma Tarihi 30 Nisan 2022
Yayınlandığı Sayı Yıl 2022, Cilt , Sayı 35

Kaynak Göster

Bibtex @araştırma makalesi { ejosat1094734, journal = {Avrupa Bilim ve Teknoloji Dergisi}, eissn = {2148-2683}, address = {}, publisher = {Osman SAĞDIÇ}, year = {2022}, number = {35}, pages = {603 - 609}, doi = {10.31590/ejosat.1094734}, title = {ZnO-Kitosan Kompoziti ile Ağır Metal Giderimi}, key = {cite}, author = {Topal Canbaz, Gamze and Açıkel, Unsal and Sağ Açıkel, Yeşim} }
APA Topal Canbaz, G. , Açıkel, U. & Sağ Açıkel, Y. (2022). ZnO-Kitosan Kompoziti ile Ağır Metal Giderimi . Avrupa Bilim ve Teknoloji Dergisi , (35) , 603-609 . DOI: 10.31590/ejosat.1094734
MLA Topal Canbaz, G. , Açıkel, U. , Sağ Açıkel, Y. "ZnO-Kitosan Kompoziti ile Ağır Metal Giderimi" . Avrupa Bilim ve Teknoloji Dergisi (2022 ): 603-609 <https://dergipark.org.tr/tr/pub/ejosat/issue/69001/1094734>
Chicago Topal Canbaz, G. , Açıkel, U. , Sağ Açıkel, Y. "ZnO-Kitosan Kompoziti ile Ağır Metal Giderimi". Avrupa Bilim ve Teknoloji Dergisi (2022 ): 603-609
RIS TY - JOUR T1 - ZnO-Kitosan Kompoziti ile Ağır Metal Giderimi AU - Gamze Topal Canbaz , Unsal Açıkel , Yeşim Sağ Açıkel Y1 - 2022 PY - 2022 N1 - doi: 10.31590/ejosat.1094734 DO - 10.31590/ejosat.1094734 T2 - Avrupa Bilim ve Teknoloji Dergisi JF - Journal JO - JOR SP - 603 EP - 609 VL - IS - 35 SN - -2148-2683 M3 - doi: 10.31590/ejosat.1094734 UR - https://doi.org/10.31590/ejosat.1094734 Y2 - 2022 ER -
EndNote %0 Avrupa Bilim ve Teknoloji Dergisi ZnO-Kitosan Kompoziti ile Ağır Metal Giderimi %A Gamze Topal Canbaz , Unsal Açıkel , Yeşim Sağ Açıkel %T ZnO-Kitosan Kompoziti ile Ağır Metal Giderimi %D 2022 %J Avrupa Bilim ve Teknoloji Dergisi %P -2148-2683 %V %N 35 %R doi: 10.31590/ejosat.1094734 %U 10.31590/ejosat.1094734
ISNAD Topal Canbaz, Gamze , Açıkel, Unsal , Sağ Açıkel, Yeşim . "ZnO-Kitosan Kompoziti ile Ağır Metal Giderimi". Avrupa Bilim ve Teknoloji Dergisi / 35 (Nisan 2022): 603-609 . https://doi.org/10.31590/ejosat.1094734
AMA Topal Canbaz G. , Açıkel U. , Sağ Açıkel Y. ZnO-Kitosan Kompoziti ile Ağır Metal Giderimi. EJOSAT. 2022; (35): 603-609.
Vancouver Topal Canbaz G. , Açıkel U. , Sağ Açıkel Y. ZnO-Kitosan Kompoziti ile Ağır Metal Giderimi. Avrupa Bilim ve Teknoloji Dergisi. 2022; (35): 603-609.
IEEE G. Topal Canbaz , U. Açıkel ve Y. Sağ Açıkel , "ZnO-Kitosan Kompoziti ile Ağır Metal Giderimi", Avrupa Bilim ve Teknoloji Dergisi, sayı. 35, ss. 603-609, Nis. 2022, doi:10.31590/ejosat.1094734