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Mezbaha Atıksularından Elektrooksidasyon Sistemi ile KOİ ve Renk Giderilmesi Üzerine pH ve Akım Yoğunluğunun Etkisi

Yıl 2022, Sayı: 36, 106 - 110, 31.05.2022
https://doi.org/10.31590/ejosat.1111639

Öz

Çalışmada mezbaha atıksularından elektrooksidasyon sistemi ile Kimyasal oksijen ihtiyacı (KOİ) ve renk giderilirken sistemin giderim performansını etkileyen önemli parametrelerden akım yoğunluğu (4,06, 6,09, 8,12, 10,15 ve 12,18 mA/cm2) ve pH’nın (3,0, doğal pH (~7,0), 9,0 ve 11,0) etkisi incelenmiştir. Anot malzemesi olarak elek tipi Ti/Pt, katot malzemesi olarak elek tipi kaplanmamış Ti kullanılmıştır. Laboratuvar deneylerinden elde edilen sonuçlara göre, uygulanan akım yoğunluğunun artmasıyla KOİ ve renk gideriminde de artış meydana gelmiştir. Bu durum hem doğrudan hem de aracılı oksidasyon reaksiyonunun önemli bir rol oynadığı elektrooksidasyon sisteminin karakteristiğine bağlanabilir. Giderim verimlerinin başlangıç pH değerine bağlı olduğu kadar reaksiyon sonundaki pH değerine de bağlı olduğu bulunmuştur. Nötr ve zayıf bazik koşullarda sistemin giderim oranının daha iyi olduğu ve güçlü bazik koşullarda nispeten düşük olduğu ve mezbaha atıksularının laboratuvar ölçekte elektrooksidasyon sistemi ile arıtımında akım yoğunluğu ve pH etkin parametreler olduğu sonucuna varılmıştır.

Destekleyen Kurum

Balıkesir Üniversitesi Bilimasel Araştırma Projeleri Birimi

Proje Numarası

BAP-2019/044

Teşekkür

Bu çalışma Balıkesir Üniversitesi Bilimasel Araştırma Projeleri Birimi tarafından BAP-2019/044 numaralı proje ile desteklenmiştir.

Kaynakça

  • Ahmed, Mohammad Boshir, John L. Zhou, Huu Hao Ngo, Wenshan Guo, Nikolaos S. Thomaidis, and Jiang Xu. 2017. “Progress in the Biological and Chemical Treatment Technologies for Emerging Contaminant Removal from Wastewater: A Critical Review.” Journal of Hazardous Materials 323:274–98.
  • Asfaha, Yemane G., Andinet Kebede Tekile, and Feleke Zewge. 2021. “Hybrid Process of Electrocoagulation and Electrooxidation System for Wastewater Treatment: A Review.” Cleaner Engineering and Technology 4:100261. Baker, Bakar Radhi, Radin Mohamed, Adel Al-Gheethi, and Hamidi Abdul Aziz. 2021. “Advanced Technologies for Poultry Slaughterhouse Wastewater Treatment: A Systematic Review.” Journal of Dispersion Science and Technology 42(6):880–99.
  • Bezirgiannidis, Athanasios, Aikaterini Plesia-Efstathopoulou, Spyridon Ntougias, and Paraschos Melidis. 2019. “Combined Chemically Enhanced Primary Sedimentation and Biofiltration Process for Low Cost Municipal Wastewater Treatment.” Journal of Environmental Science and Health, Part A 54(12):1227–32.
  • Crini, Grégorio, and Eric Lichtfouse. 2019. “Advantages and Disadvantages of Techniques Used for Wastewater Treatment.” Environmental Chemistry Letters 17(1):145–55. EPA, U. S. 2004. “Effluent Limitations Guidelines and New Source Performance Standards for the Meat and Poultry Products, Point Source Category.” Federal Register 69(173):54475–555.
  • Ganiyu, Soliu O., Elisama Vieira dos Santos, Emily Cintia Tossi de Araújo Costa, and Carlos A. Martínez-Huitle. 2018. “Electrochemical Advanced Oxidation Processes (EAOPs) as Alternative Treatment Techniques for Carwash Wastewater Reclamation.” Chemosphere 211:998–1006.
  • Hernández-Rodríguez, Evelyn Anaid, Luis Antonio Castillo-Suárez, Elia Alejandra Teutli-Sequeira, Verónica Martínez-Miranda, Guadalupe Vázquez Mejía, Ivonne Linares-Hernández, Fortunata Santoyo-Tepole, and Abraham Benavides. 2022. “Electro-Oxidation and Solar Electro-Oxidation of Commercial Carbamazepine: Effect of the Support Electrolyte.” Separation Science and Technology 57(3):465–83.
  • Luo, Yunlong. 2014. “A Review on the Occurrence of Micropollutants in the Aquatic Environment and Their Fate and Removal during Wastewater Treatment.” 474:619–41.
  • Ma, Pengfei, Hongrui Ma, Alessandro Galia, Simona Sabatino, and Onofrio Scialdone. 2019. “Reduction of Oxygen to H2O2 at Carbon Felt Cathode in Undivided Cells. Effect of the Ratio between the Anode and the Cathode Surfaces and of Other Operative Parameters.” Separation and Purification Technology 208:116–22.
  • Ozturk, Dilara, and Alper Erdem Yilmaz. 2019. “Treatment of Slaughterhouse Wastewater with the Electrochemical Oxidation Process: Role of Operating Parameters on Treatment Efficiency and Energy Consumption.” Journal of Water Process Engineering 31:100834.
  • Özyurt, Baran, and Şule Camcıoğlu. 2018. “Applications of Combined Electrocoagulation and Electrooxidation Treatment to Industrial Wastewaters.” Pp. 71–89 in Wastewater and water quality.
  • Phoon, Bao Lee, Chong Cheen Ong, Mohamed Shuaib Mohamed Saheed, Pau-Loke Show, Jo-Shu Chang, Tau Chuan Ling, Su Shiung Lam, and Joon Ching Juan. 2020. “Conventional and Emerging Technologies for Removal of Antibiotics from Wastewater.” Journal of Hazardous Materials 400:122961.
  • Rivera, Fernando F., Tzayam Pérez, Locksley F. Castañeda, and José L. Nava. 2021. “Mathematical Modeling and Simulation of Electrochemical Reactors: A Critical Review.” Chemical Engineering Science 239:116622.
  • da Silva, Salatiel W., Emma M. O. Navarro, Marco A. S. Rodrigues, Andréa M. Bernardes, and Valentín Pérez-Herranz. 2019. “Using P-Si/BDD Anode for the Electrochemical Oxidation of Norfloxacin.” Journal of Electroanalytical Chemistry 832:112–20.
  • Song, Peipei, Chengye Sun, Jun Wang, Shiyun Ai, Shujun Dong, Jie Sun, and Shuai Sun. 2022. “Efficient Removal of Cu-EDTA Complexes from Wastewater by Combined Electrooxidation and Electrocoagulation Process: Performance and Mechanism Study.” Chemosphere 287:131971.
  • Sun, Shengdan, Chuanping Feng, Shuang Tong, Yan Zhao, Nan Chen, and Ming Zhu. 2021. “Evaluation of Advanced Phosphorus Removal from Slaughterhouse Wastewater Using Industrial Waste-Based Adsorbents.” Water Science and Technology 83(6):1407–17.
  • Terán Hilares, Ruly, Diego F. Atoche-Garay, Daniel A. Pinto Pagaza, Muhammad Ajaz Ahmed, Gilberto J. Colina Andrade, and Júlio César Santos. 2021. “Promising Physicochemical Technologies for Poultry Slaughterhouse Wastewater Treatment: A Critical Review.” Journal of Environmental Chemical Engineering 9(2):105174.
  • Tong, Shuang, Shaoxiang Zhang, Yan Zhao, Chuanping Feng, Weiwu Hu, and Nan Chen. 2022. “Hybrid Zeolite-Based Ion-Exchange and Sulfur Oxidizing Denitrification for Advanced Slaughterhouse Wastewater Treatment.” Journal of Environmental Sciences 113:219–30.
  • Yu, Fangke, Yang Chen, Yuwei Pan, Yang Yang, and Hongrui Ma. 2020. “A Cost-Effective Production of Hydrogen Peroxide via Improved Mass Transfer of Oxygen for Electro-Fenton Process Using the Vertical Flow Reactor.” Separation and Purification Technology 241:116695.

The Effect of pH and Current Density on COD and Color Removal from Slaughterhouse Wastewater by Electrooxidation System

Yıl 2022, Sayı: 36, 106 - 110, 31.05.2022
https://doi.org/10.31590/ejosat.1111639

Öz

In the study, the effect of current density (4,06, 6,09, 8,12, 10,15 ve 12,18 mA/cm2) and pH (3,0, ~7,0 (natural), 9,0, and 11,0), which are important parameters affecting the removal performance of the system, while removing chemical oxygen demand (COD) and color from slaughterhouse wastewater with the electrooxidation system was investigated. Sieve type Ti/Pt was used as anode material and sieve type uncoated Ti was used as cathode material. According to the results obtained from laboratory experiments, COD and color removal increased with the increase of applied current density. This can be attributed to the characteristic of the electrooxidation system, in which both direct and mediated oxidation reactions play an important role. It was found that the removal efficiencies depend not only on the initial pH but also, on the pH after the reaction completion. It has been observed that the removal efficiencies of the system are better in neutral and weakly basic conditions, and it is relatively low in strongly basic conditions, and current density and pH are effective parameters in the treatment of slaughterhouse wastewater by the lab-scale electrooxidation system.

Proje Numarası

BAP-2019/044

Kaynakça

  • Ahmed, Mohammad Boshir, John L. Zhou, Huu Hao Ngo, Wenshan Guo, Nikolaos S. Thomaidis, and Jiang Xu. 2017. “Progress in the Biological and Chemical Treatment Technologies for Emerging Contaminant Removal from Wastewater: A Critical Review.” Journal of Hazardous Materials 323:274–98.
  • Asfaha, Yemane G., Andinet Kebede Tekile, and Feleke Zewge. 2021. “Hybrid Process of Electrocoagulation and Electrooxidation System for Wastewater Treatment: A Review.” Cleaner Engineering and Technology 4:100261. Baker, Bakar Radhi, Radin Mohamed, Adel Al-Gheethi, and Hamidi Abdul Aziz. 2021. “Advanced Technologies for Poultry Slaughterhouse Wastewater Treatment: A Systematic Review.” Journal of Dispersion Science and Technology 42(6):880–99.
  • Bezirgiannidis, Athanasios, Aikaterini Plesia-Efstathopoulou, Spyridon Ntougias, and Paraschos Melidis. 2019. “Combined Chemically Enhanced Primary Sedimentation and Biofiltration Process for Low Cost Municipal Wastewater Treatment.” Journal of Environmental Science and Health, Part A 54(12):1227–32.
  • Crini, Grégorio, and Eric Lichtfouse. 2019. “Advantages and Disadvantages of Techniques Used for Wastewater Treatment.” Environmental Chemistry Letters 17(1):145–55. EPA, U. S. 2004. “Effluent Limitations Guidelines and New Source Performance Standards for the Meat and Poultry Products, Point Source Category.” Federal Register 69(173):54475–555.
  • Ganiyu, Soliu O., Elisama Vieira dos Santos, Emily Cintia Tossi de Araújo Costa, and Carlos A. Martínez-Huitle. 2018. “Electrochemical Advanced Oxidation Processes (EAOPs) as Alternative Treatment Techniques for Carwash Wastewater Reclamation.” Chemosphere 211:998–1006.
  • Hernández-Rodríguez, Evelyn Anaid, Luis Antonio Castillo-Suárez, Elia Alejandra Teutli-Sequeira, Verónica Martínez-Miranda, Guadalupe Vázquez Mejía, Ivonne Linares-Hernández, Fortunata Santoyo-Tepole, and Abraham Benavides. 2022. “Electro-Oxidation and Solar Electro-Oxidation of Commercial Carbamazepine: Effect of the Support Electrolyte.” Separation Science and Technology 57(3):465–83.
  • Luo, Yunlong. 2014. “A Review on the Occurrence of Micropollutants in the Aquatic Environment and Their Fate and Removal during Wastewater Treatment.” 474:619–41.
  • Ma, Pengfei, Hongrui Ma, Alessandro Galia, Simona Sabatino, and Onofrio Scialdone. 2019. “Reduction of Oxygen to H2O2 at Carbon Felt Cathode in Undivided Cells. Effect of the Ratio between the Anode and the Cathode Surfaces and of Other Operative Parameters.” Separation and Purification Technology 208:116–22.
  • Ozturk, Dilara, and Alper Erdem Yilmaz. 2019. “Treatment of Slaughterhouse Wastewater with the Electrochemical Oxidation Process: Role of Operating Parameters on Treatment Efficiency and Energy Consumption.” Journal of Water Process Engineering 31:100834.
  • Özyurt, Baran, and Şule Camcıoğlu. 2018. “Applications of Combined Electrocoagulation and Electrooxidation Treatment to Industrial Wastewaters.” Pp. 71–89 in Wastewater and water quality.
  • Phoon, Bao Lee, Chong Cheen Ong, Mohamed Shuaib Mohamed Saheed, Pau-Loke Show, Jo-Shu Chang, Tau Chuan Ling, Su Shiung Lam, and Joon Ching Juan. 2020. “Conventional and Emerging Technologies for Removal of Antibiotics from Wastewater.” Journal of Hazardous Materials 400:122961.
  • Rivera, Fernando F., Tzayam Pérez, Locksley F. Castañeda, and José L. Nava. 2021. “Mathematical Modeling and Simulation of Electrochemical Reactors: A Critical Review.” Chemical Engineering Science 239:116622.
  • da Silva, Salatiel W., Emma M. O. Navarro, Marco A. S. Rodrigues, Andréa M. Bernardes, and Valentín Pérez-Herranz. 2019. “Using P-Si/BDD Anode for the Electrochemical Oxidation of Norfloxacin.” Journal of Electroanalytical Chemistry 832:112–20.
  • Song, Peipei, Chengye Sun, Jun Wang, Shiyun Ai, Shujun Dong, Jie Sun, and Shuai Sun. 2022. “Efficient Removal of Cu-EDTA Complexes from Wastewater by Combined Electrooxidation and Electrocoagulation Process: Performance and Mechanism Study.” Chemosphere 287:131971.
  • Sun, Shengdan, Chuanping Feng, Shuang Tong, Yan Zhao, Nan Chen, and Ming Zhu. 2021. “Evaluation of Advanced Phosphorus Removal from Slaughterhouse Wastewater Using Industrial Waste-Based Adsorbents.” Water Science and Technology 83(6):1407–17.
  • Terán Hilares, Ruly, Diego F. Atoche-Garay, Daniel A. Pinto Pagaza, Muhammad Ajaz Ahmed, Gilberto J. Colina Andrade, and Júlio César Santos. 2021. “Promising Physicochemical Technologies for Poultry Slaughterhouse Wastewater Treatment: A Critical Review.” Journal of Environmental Chemical Engineering 9(2):105174.
  • Tong, Shuang, Shaoxiang Zhang, Yan Zhao, Chuanping Feng, Weiwu Hu, and Nan Chen. 2022. “Hybrid Zeolite-Based Ion-Exchange and Sulfur Oxidizing Denitrification for Advanced Slaughterhouse Wastewater Treatment.” Journal of Environmental Sciences 113:219–30.
  • Yu, Fangke, Yang Chen, Yuwei Pan, Yang Yang, and Hongrui Ma. 2020. “A Cost-Effective Production of Hydrogen Peroxide via Improved Mass Transfer of Oxygen for Electro-Fenton Process Using the Vertical Flow Reactor.” Separation and Purification Technology 241:116695.
Toplam 18 adet kaynakça vardır.

Ayrıntılar

Birincil Dil Türkçe
Konular Mühendislik
Bölüm Makaleler
Yazarlar

Onur Sözüdoğru 0000-0001-7885-2930

Sermin Günaslan 0000-0003-2395-2808

Baybars Ali Fil 0000-0003-3085-224X

Proje Numarası BAP-2019/044
Erken Görünüm Tarihi 11 Nisan 2022
Yayımlanma Tarihi 31 Mayıs 2022
Yayımlandığı Sayı Yıl 2022 Sayı: 36

Kaynak Göster

APA Sözüdoğru, O., Günaslan, S., & Fil, B. A. (2022). Mezbaha Atıksularından Elektrooksidasyon Sistemi ile KOİ ve Renk Giderilmesi Üzerine pH ve Akım Yoğunluğunun Etkisi. Avrupa Bilim Ve Teknoloji Dergisi(36), 106-110. https://doi.org/10.31590/ejosat.1111639