Isıl işlem ile modifiye edilmiş arıtma çamuru kullanılarak sabit yataklı kolonda arsenik ve antimon giderimi

Yıl 2023, Cilt: 38 Sayı: 1, 629 - 638, 21.06.2022

Berna Kavacık , Deniz Dölgen

https://doi.org/10.17341/gazimmfd.1020632

Cited By: 2

Öz

Bu çalışmada, demir içeren içme suyu arıtma tesis çamurunun (DWTS) arsenik ve antimon giderim performansı araştırılmıştır. DWTS üç farklı sıcaklıkta (200, 400 ve 600ºC) termal arıtmaya tabi tutularak modifiye edilmiştir (DWTS-200). 200ºC, 1saat ısıl işlem uygulanmış malzeme ile maksimum arsenik giderimi elde edilmiştir. Malzemenin yüzey alanı ve gözenek hacmi BET metoduyla analiz edilmiş, faz kompozisyonu X-ışını difraksiyonu (XRD) ile belirlenmiştir. Yüzey morfolojileri ve element analizi taramalı elektron mikroskobu (SEM) ve X-ışını spektrometresi (EDS) ile gerçekleştirilmiştir. Sonuçlar DWTS-200 malzemesinin oldukça yüksek yüzey alanına sahip olduğunu (170 m2 g-1) ve amorf yapısının baskın olduğunu göstermiştir. Malzemenin ana fazları ağırlıklı olarak demir, kalsit, oksijen ve quartzdan oluşmuştur. 40 µg As L-1 ve 80 µg Sb L-1 konsantrasyonları için kırılma noktasına ulaşıncaya kadar arsenik için 6.000 L (133.000 yatak hacmi sayısı), antimon için 640 L (14.000 yatak hacmi sayısı) su arıtabildiği belirlenmiştir. Kolon tasarımı için gerekli kinetik parametreleri belirlemek ve kırılma eğrilerini tahmin etmek için Thomas ve Yoon-Nelson modelleri uygulanmıştır. Her iki model adsorpsiyon sürecinin dinamik davranışını açıklamak için uygun bulunmuştur. Thomas modeliyle arsenik için maksimum adsorpsiyon kapasitesi 6,53 mg g-1, antimon için 5,21 mg g-1 olarak elde edilmiştir. Ayrıca, DWTS-200 adsorban malzemeye rejenerasyon uygulanmış ve malzemenin rejenere edilerek kullanılabileceği görülmüştür.

Anahtar Kelimeler

Adsorpsiyon, antimon, arsenik, içme suyu arıtma çamuru, termal arıtma

Destekleyen Kurum

Dokuz Eylül Üniversitesi

Proje Numarası

BAP 2018.KB.FEN.036

Teşekkür

Bu çalışma Dokuz Eylül Üniversitesi, Bilimsel Araştırma Proje Programı (Proje No: BAP 2018.KB.FEN.036) tarafından desteklenmiştir.

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