Oksitetrasiklin hidroklorürün doğal zeolit ile sulu çözeltilerden giderimi

Yıl 2023, Cilt: 38 Sayı: 3, 1505 - 1518, 06.01.2023

Gülşah Başkan Unsal Açıkel Menderes Levent

https://doi.org/10.17341/gazimmfd.1008501

Öz

Antibiyotik kalıntılarının su kaynaklarındaki toksisitesi çevreyi olumsuz etkilemektedir. Son yıllarda yapılan çalışmalar antibiyotikler gibi organik kirleticilerin ucuz ve çevreye uyumlu adsorbentlerle sulu çözeltilerden giderimine odaklanmıştır. Bu çalışmada, doğal Manisa-Gördes klinoptiloliti oksitetrasiklin hidroklorür (OTC-HCL) adsorpsiyonu, kesikli sisteminde 298-323 K'de incelenmiştir. pH, başlangıç konsantrasyonu, adsorban dozu, temas süresi, karıştırma hızı ve sıcaklığın adsorpsiyon üzerindeki etkileri incelenmiş ve optimum parametreler belirlenmiştir. Adsorpsiyon izotermleri Langmuir, Freundlich, Dubinin-Radushkevich (D-R), Temkin modelleri kullanılarak analiz edilmiştir. Kinetik sabitler yalancı birinci derece, yalancı ikinci derece, inratapartikül difüzyon ve Elovich modelleriyle belirlenmiştir. Doğal zeolitin OTC-HCL adsorpsiyonu, en iyi Freundlich izotermine ve sözde ikinci dereceden kinetik modeline uymuştur. Doğal zeolitin maksimum adsorpsiyon kapasitesi 323 K'de 60,97 mg/g olarak belirlenmiştir. Termodinamik çalışmalar, OTC-HCL’nin doğal zeolit ile adsorpsiyonunun kendiliğinden ve endotermik olduğunu göstermiştir. Doğal zeolitin fizikokimyasal karakterizasyonu adsorpsiyondan önce ve sonra, N2 adsorpsiyon-desorpsiyon, XRD, FTIR, SEM-EDX analizleri ile gerçekleştirilmiştir. Doğal zeolitin BET spesfik yüzey alanı, adsorpsiyon sürecine bağlı olarak adsorpsiyon sonrasında azalmıştır. Karakterizasyon sonuçları, doğal zeolit yüzeyinde OTC-HCL moleküllerinin başarılı bir adsorbe olduğunu göstermiştir.

Anahtar Kelimeler

Oksitetrasiklin hidroklorür, klinoptilolit, zeolit, antibiyotik, adsorpsiyon, izoterm

Destekleyen Kurum

Sivas Cumhuriyet Üniversitesi Bilimsel Araştırma Projeleri Birimi

Proje Numarası

(BAP/M-764 kodlu proje)

Teşekkür

Bu çalışma Sivas Cumhuriyet Üniversitesi Bilimsel Araştırma Projeleri Birimi (BAP/M-764 kodlu proje) tarafından desteklenmektedir. Yazarlar, Deva Holding-İstanbul-Türkiye ve Gordes Zeolite-İzmir-Türkiye tarafından sağlanan antibiyotik ve zeolit için teşekkürlerini bildiriyorlar.

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