KIRMIZI PUL BİBER ÖRNEKLERİNDE ELEMENT İÇERİĞİNİN BELİRLENMESİ

Yıl 2019, Cilt: 44 Sayı: 6, 1000 - 1007, 06.10.2019

Serpil Kılıç , Murat Kılıç

https://doi.org/10.15237/gida.GD19101

Cited By: 1

Öz

Çevresel kirlilikler, tarım ürünlerini tehdit etmekte ve
dolayısıyla insan sağlığı için risk oluşturmaktadır. Bu tarım ürünleri
içerisinde yer alan, kırmızıbiber, üretiminde kimyasal ilaçların kullanımı ise
sağlık için tehlike oluşturan bazı elementlerin kontamine olmasına sebep
olabilmektedir. Gıda sanayinde yaygın olarak kullanılan bir baharat çeşidi olan
ve özellikle gıdaları çeşnilendirmek için en çok kullanılan baharatlar arasında
yer alan kırmızıbiber tüketiminde, bu kontaminasyon insan sağlığını tehdit
edici unsur oluşturmaktadır. Bu çalışmada, kırmızıbibere kontamine olabilen
bazı metal kirleticiler (krom (Cr), kobalt (Co), bakır (Cu), demir (Fe), nikel
(Ni), selenyum (Se), çinko (Zn)) indüktif eşleşmiş plazma kütle spektrometrisi
kullanılarak (ICP-MS) tespit edildi. 
Analitik performansları; doğrusallık, tespit sınırı, ölçüm sınırı ve
geri kazanım olarak değerlendirildi. Metot validasyonu için sertifikalı
referans madde olarak Tomato Leaves 1573a kullanıldı. Çalışılan elementler için
geri kazanım,%98 ile %103 arasında değişmektedir. Örneklerde tüm metallerin
konsantrasyonları uluslararası ve Türk Gıda Kodeksinde belirtilen sınırları
aşmadığı gözlemlenmiştir.

Anahtar Kelimeler

Kırmızı pul biber, ICP-MS, metal analizi

Destekleyen Kurum

Akdeniz Üniversitesi

Proje Numarası

FBA-2017-2494

Teşekkür

Çalışmamızı FBA-2017-2494 proje numarası ile maddi olarak destekleyen Akdeniz Üniversitesi Bilimsel Araştırma Projeleri Koordinasyon Birimi’ne çok teşekkür ediyoruz.

DETERMINATION OF ELEMENT CONTENTS IN RED PEPPER SAMPLES

Öz

Environmental pollution threatens the agricultural
products and therefore poses a risk for human health. In the production of red
pepper which is one of these agricultural products, the use of chemical drugs,
may cause some elements with health hazards to be contaminated. The
contamination threatens human health in consumption of red pepper, which is
used in the food industry and is one of the most widely used spices for
seasoning foods. In this study, was determined of some metallic contaminants
(chromium (Cr), cobalt (Co), copper (Cu), iron (Fe), nickel (Ni), selenium
(Se), zinc (Zn)) in red pepper using inductive coupled plasma mass spectrometry
(ICP-MS). The validation procedure was applied for the evaluation of linearity,
repeatability, recovery, limit of detection, and quantification. Tomato Leaves
1573a was used as certified reference material for method validation. The
recovery ranged from 98% to 103% for studied elements. It is observed that the
concentrations of all metals in samples did not exceed the international and
Turkish codex values.

Anahtar Kelimeler

Red pepper, ICP-MS, metal analysis

Proje Numarası

FBA-2017-2494

Kaynakça

• Abechi, E.S., Okunola O.J., Zubairul, S.M.J., Usman, A.A., Apene, E. (2010). Evaluation of heavy metals in roadside soils of major streets in Jos mtropolis, Nigeria. Journal of Environmental Chemistry and Ecotoxicology, 2(6), 98-102.
• Al-Fartusie, F.S., Mohssan, S.N. (2017). Essential Trace Elements and Their Vital Roles in Human Body. Indian Journal of Advances in Chemical Science, 5(3), 127-136.
• Alvarez, V.B., Pascall, M.A. (2011). Packaging. Encyclopedia of Dairy Sciences (Second Edition) Academic Press, 16–23.
• Anonim (2015). https://biruni.tuik.gov.tr/bitkiselapp/bitkisel.zul. Erişim tarihi: 10.09.2015.
• Anonymous (1997). Codex Alimentarius Commission (CAC), Procedural Manual, 10th ed., Joint FAO/WHO Food Standards Programme, Rome.
• Anonymous (2013). http://faostat3.fao.org/wds/rest/exporter/streamexcel, Erişim Tarihi: 29.11.2015.
• Anonymous (2014b). http://faostat3.fao.org/wds/rest/exporter/streamexcel. Erişim Tarihi: 15.08.2016.
• Basta, N.T., Ryan, J.A., Chaney, R.L. (2005). Trace Element Chemistry in Residual-Treated Soil. Journal of Environmental Quality, 34(1), 49-63.
• Battaglia, V., Compagnone, A., Bandino, A., Bragadin, M., Rossi, C.A., Zanetti, F., Colombatto, S., Grillo, M.A., Toninello, A. (2009). Cobalt induces oxidative stress in isolated liver mitochondria responsible for permeability transition and intrinsicapoptosis in hepatocyte primary cultures. The International Journal of Biochemistry and Cell Biology, 41, 586-594.
• Bingöl, M.E., Geven, F., Güney, K., Ketenoğlu, O., Erdoğan, N. (2010). Egzoz Gazlarının Bitkilere Etkileri ve Koruma Önerileri. Biyoloji Bilimleri Araştırma Dergisi, 3(2), 63-67.
• Brown, K.M., Arthur, J.R. (2001). Selenium, selenoproteins and human health a review. Public Health Nutrition, 4(2B), 593-599.
• Bruce, A., Bergstrom, L. (1983). User requirements for data bases and applications in nutrition research. Food Nutr Bull, 5, 24-29.
• Chary, N.S., Kamala, C.T., Samuel Suman Raj, D. (2008). Assessing risk of heavy metals from consuming food grown on sewage irrigated soils and food chain transfer. Ecotoxicology and Environmental Safety, 69(3), 513-524.
• Erdogan, A. (2004). The aflatoxin contamination of some pepper types sold in Turkey. Chemosphere, 56, 321–325.
• Formicki, G., Stawarz, R., Gren, A., Muchacka, R. (2012). Cadmium, Copper, Lead and Zinc Concentrations in Low Qualıty Wines and Alcohol Containing Drinks from İtaly, Bulgaria and Poland. Journal of Microbiology, Biotechnology and Food Sciences 1 (February Special issue), 753-757.
• Fraga, C.G. (2005). Relevance, essentiality and toxicity of trace elements in human health. Molecular Aspects of Medicine, 26, 235–244.
• Jeremias, C.T.L. David, B. Royden, J. (2006). Severe ataxia, myelopathy, and peripheral neuropathy due to acquired copper deficiency in a patient with history of gastrectomy. Journal of Parenteral and Enteral Nutrition, 30, 446-450.
• Kilic, S., Kilic, M. (2018). Laboratuvar Yeterlilik Testi Biber Tozu Örneğinde ICP-MS ile Element Analizi. AKÜ FEMÜBİD, 18 (011202), 112-117.
• Kumbur, H., Özsoy, HD., Özer, Z. (2008). Mersin İlinde Tarımsal Alanlarda Kullanılan Kimyasalların Su Kalitesi Üzerine Etkilerinin Belirlenmesi. Ekoloji, 17(68), 54-58.
• Mubeen, H., Naeem, I., Taskeen, A. Saddiqe, Z. (2009). Investigations of heavy metals in commercial spices brands. New York Science Journal, 2, 20–26.
• Naglaa, F.E. 2015. Soliman. Metals Contents in Spices and Herbs Available on the Egyptian Market: Assessment of Potential Human Health Risk. The Open Conference Proceedings Journal, 6, 24-29.
• Notten, M.J.M., Oosthoek, A.J.P., Rozema, J., Aerts, R. (2005). Heavy metal concentrations in a soil– plant–snail food chain along a terrestrial soil pollution gradient. Environmental Pollution, 138(1), 178–190.
• Ramonaityte, D.T. (2001). Copper, zinc, tin and lead in canned evaporated milk, produced in Lithuania:the initial content and change in storage. Food Additives and Contaminants, 18(1), 31-37.
• Roychowdhury, T., Tokunaga, H., Ando, M. (2003). Survey of arsenic and other heavy metals in food composites and drinking water and estimation of dietary intake by the villagers from an arsenic-affected area of West Bengal, India. The Science of the Total Environment, 308, 15-35.
• Stresty, T.V.S., Madhava, R.K.V. (1999). Ultrastructural alterations in response to zinc and nickel stress in the root cell of pigeonpea. Environmental and Experimental Botany, 41, 3-13.
• Sydor, M. Zamble, D.B. (2013). Nickel metallomics: General themes guiding nickel homeostasis. In: B. Lucia, (Ed.), Metallomics and the Cell. Metal Ions in Life Sciences, Vol. 12. Ch. 11. Dordrecht: Springer.
• USEPA (2012). Waste and cleanup risk assessment. http://www2.epa.gov/risk/waste-and-cleanup-risk-assessment.
• Vural, H. (1993). Ağır Metal İyonlarının Gıdalarda Oluşturduğu Kirlilikler. Çevre Dergisi, 8, 3-8.
• Wessling-Resnick, M. (2014). Iron. In: A. C. Ross, B. Caballero, R. J. Cousins, K. L. Tucker, R. G. Ziegler, (Ed.), Modern Nutrition in Health and Disease, 11th ed. Baltimore, MD: Lippincott Williams & Wilkins, 176-188p.
• William,T.C., Frank, B.H. (2004). Role of chromium in human health and in diabetes, Diabetes Care, 27(11), 2741-2751.
• Yentür, G., Er, B. (2012). Gıdalarda aflatoksin varlığının değerlendirilmesi. Türk Hijyen ve Deneysel Biyoloji Dergisi, 69(1), 41-52.