Sübstitüe salisiliden Schiff bazı metal komplekslerinin sentezi ve karakterizasyonu

Ahmet Oral Sarıoğlu; Hatice Gamze Soğukömeroğulları

doi:10.17714/gumusfenbil.1492674

EN TR

Synthesis and characterization of Schiff base metal complexes from substituted salicylidene

Abstract

2-(((4-fluorophenyl)imino)methyl)-4-nitrophenol Schiff base was synthesized from the condensation reaction of 2-hydroxy-5-nitrobenzaldehyde and 4-fluoroaniline. The new Cu2+, Co2+, Ni2+, and Fe2+ metal complexes were prepared by reacting the Schiff base ligand with Cu2+, Co2+, Ni2+, and Fe2+ acetate salts, respectively. Complexes prepared with 2-(((4-fluorophenyl)imino)methyl)-4-nitrophenol ligand and metal salts have a ligand:metal stoichiometric ratio of (2:1).The compounds were structurally characterized using FT-IR, 13C- and 1H-NMR, molar conductivity, electronic absorption spectra, magnetic susceptibility and elemental analysis techniques. Both the nitrogen (N) donor atom of the azomethine group and the oxygen (O) donor atom of the phenolic OH group are responsible for coordinating the complexation process. A square plane structure has been proposed for [CuL2], and a tetrahedral structure has been proposed for [CoL2], [FeL2], and [NiL2].H2O complexes. When the molar conductivity values were examined (2.37-3.42 µS/cm), it was seen that the structures had no conductive properties.

Keywords

Characterization , Condensation , Metal complex , Schiff base

Sübstitüe salisiliden Schiff bazı metal komplekslerinin sentezi ve karakterizasyonu

Öz

2-hidroksi-5-nitrobenzaldehit ve 4-floroanilin'in kondenzasyon reaksiyonundan 2-(((4-florofenil)imino)metil)-4-nitrofenol Schiff bazı sentezlenmiştir. Schiff bazı ligandının sırasıyla Cu2+, Co2+, Ni2+ ve Fe2+ asetat tuzlarıyla reaksiyonundan yeni Cu2+, Co2+, Ni2+ ve Fe2+ metal kompleksleri hazırlanmıştır. 2-(((4-florofenil)imino)metil)-4-nitrofenol ligandı ve metal tuzları ile hazırlanan kompleksler, (2:1) ligand:metal sitokiyometrik oranına sahiptir. Tüm bileşiklerin yapısal olarak karakterizasyonu FT-IR, 1H- ve 13C-NMR, molar iletkenlik, elektronik absorpsiyon spektrum, manyetik duyarlılık ve elementel analiz yöntemleri kullanılarak incelenmiştir. Kompleksleşme azometin grubuna ait azot (N) donör atomu ve fenolik OH grubuna ait oksijen (O) donör atomu üzerinden koordine olarak gerçekleşmektedir. [CuL2] kompleksi için kare düzlem yapı, [CoL2], [FeL2] ve [NiL2].H2O kompleksleri için ise tetrahedral yapı önerilmiştir. Molar iletkenlik değerleri incelendiğinde (2.37-3.42 µS/cm) yapıların iletkenlik özelliğinin olmadığı görülmüştür.

Anahtar Kelimeler

Karakterizasyon , Kondenzasyon , Metal kompleks , Schiff bazı

Kaynakça

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Ayrıntılar

Birincil Dil

Türkçe

Konular

Geçiş Metal Kimyası

Bölüm

Araştırma Makalesi

Yazarlar

Ahmet Oral Sarıoğlu
0000-0001-7787-7968
Türkiye

Hatice Gamze Soğukömeroğulları ^*
0000-0002-0575-8131
Türkiye

Yayımlanma Tarihi

15 Aralık 2024

Gönderilme Tarihi

30 Mayıs 2024

Kabul Tarihi

4 Ekim 2024

Yayımlandığı Sayı

Yıl 2024 Cilt: 14 Sayı: 4

DOI

https://doi.org/10.17714/gumusfenbil.1492674

IZ

https://izlik.org/JA28KC38BH

APA

Sarıoğlu, A. O., & Soğukömeroğulları, H. G. (2024). Sübstitüe salisiliden Schiff bazı metal komplekslerinin sentezi ve karakterizasyonu. Gümüşhane Üniversitesi Fen Bilimleri Dergisi, 14(4), 1149-1160. https://doi.org/10.17714/gumusfenbil.1492674

Cited By

A study of the synthesis, characterization, cytotoxicity assessment, and molecular docking of Cu(II), Ni(II), and Co(II) ions with Schiff base and 1,10-phenanthroline

Journal of Molecular Structure

https://doi.org/10.1016/j.molstruc.2025.144090

Some new Schiff base derived thiosemicarbazones: Synthesis, spectroscopic characterization, and theoretical studies

Gümüşhane Üniversitesi Fen Bilimleri Enstitüsü Dergisi

https://doi.org/10.17714/gumusfenbil.1791390

e-ISSN: 2146-538X Yayın Modeli: Sürekli Yayın Atıf Dizinleri: TR Dizin , SCOPUS

Synthesis and characterization of Schiff base metal complexes from substituted salicylidene

Abstract

Keywords

Sübstitüe salisiliden Schiff bazı metal komplekslerinin sentezi ve karakterizasyonu

Öz

Anahtar Kelimeler

Kaynakça

Ayrıntılar

Birincil Dil

Konular

Bölüm

Yazarlar

Yayımlanma Tarihi

Gönderilme Tarihi

Kabul Tarihi

Yayımlandığı Sayı

DOI

IZ

Kaynak Göster

Cited By

A study of the synthesis, characterization, cytotoxicity assessment, and molecular docking of Cu(II), Ni(II), and Co(II) ions with Schiff base and 1,10-phenanthroline

Some new Schiff base derived thiosemicarbazones: Synthesis, spectroscopic characterization, and theoretical studies