Adsorption of pollutants using different types of geological materials: a review

Öz

The increase in the amount of pollutants in the ecosystem led to the search of low-cost adsorbents. Despite the effective capacity of conventional adsorbents, such as activated carbon, attention has been directed to adsorbents that are naturally accessible due to their low cost of removing contaminants. This study is a survey of research on the ability of geological materials and modifications to adsorb ionic metals, heavy metals, organic compounds and pharmacological contaminants. Geological materials such as bentonite, kaolinite, montmorillonite, zeolite and calcite; zeolite and bentonite are effective in removing pesticides from antibiotics and wastes.

Anahtar Kelimeler

• Adsorption,geological materials,pollutans

Kirleticilerin farklı jeolojik materyaller kullanılarak adsorpsiyonu: bir inceleme

Öz

Ekosistemde kirletici miktarındaki artış, düşük maliyetli adsorbanların araştırılmasına  yol açmıştır. Aktif karbon gibi klasik adsorbanların etkili kapasitesine rağmen, kirleticilerin giderilmesinde düşük maliyetlerinden dolayı dikkatler,doğal olarak ulaşılabilen adsorbanlara yönelmiştir. Bu çalışma, jeolojik materyallerin ve modifikasyonlarının iyonik metaller, ağır metaller, organik bileşikler ve farmakolojik kirleticileri adsorblama yeteneği ile ilgili yapılan araştırmalar hakkında bir incelemedir. Bentonit, kaolinit, montmorillonit, zeolit ve kalsitgibi jeolojik materyaller; ağır metaller ve boyalar  için çeşitli oranlarda adsorbsiyon kapasitesine sahipken, zeolit ve bentonit antibiyotik ve atıklardan pestisitleri uzaklaştırmada etkilidir. 

Anahtar Kelimeler

• Adsorpsiyon,jeolojik materyaller,kirleticiler

Kaynakça

1. [1] Wang, S., and Peng, Y., “Natural zeolites as effective adsorbents in water and wastewater treatment,” Chemical Engineering Journal, 156, 11–24, 2010
2. [2] Lin, S.H., and Juang, R.S., “Heavy metal removal from water by sorption using surfactantmodified montmorillonite”, J. Hazard. Mater, B 92, 315–326, 2002.
3. [3] Abd El-Latif, MM., El-Kady, MF., Ibrahim, AM., and Ossman ME., “Alginate/polyvinyl alcohol-kaolin composite for removal of methylene blue from aqueous solution in a batch stirred tank reactor”, J Am Sci 6:280–292, 2012.
4. [4] Eriksson, E., Auffarth, K., Henze, M., and Ledin A.,” Characteristics of grey wastewater”, Urban Water, 4, 1, 85–104, 2002.
5. [5] Du, Q., Liu, S., Cao, Z.,and Wang, Y., “Ammonia removal from aqueous solution using natural Chinese clinoptilolite”, Separation and Purification Technology, 44 ,3, 229–234, 2005.
6. [6] Masel, R. I., Principles of Adsorption and Reaction on Solid Surfaces Wiley, New York, NY, 1996.
7. [7] Slejko, E.L., and Dekker, M., ‘Adsorption Technology: a step by step approach to process evaluation and application, Ed M.DKKER, New York, 1985.
8. [8] Do, D.D., “Adsorption Analysis: Equilibria and Kinetics, Imperial College Press, Singapore”, 1998.

9. [9] Robinson, T., Chandran, B., and Nigam, P., “Removal of dyes from a synthetic textile dye effluent by biosorption on apple pomace and wheat straw,” Water Res 36, 2824–2830, 2002.
10. [10] Chen, Y-M., Tsao T-M., and Wang M-K., “Removal of crystal violet and methylene blue from aqueous solution using soil nano-clays”, International conference on environment science and engineering, IPCBEE, vol 8. IACSIT Press, Singapore, pp 252–254,2011.
11. [11] Purkait, MK., Maiti, A., DasGupta, S., and De, S.,”Removal of Congo red using activated carbon and its regeneration”, J Hazard Mater, 145, 287–295, 2007.
12. [12] Joo, JB., Park, B., and Yi, J., “Preparation of polyelectrolyte-functionalized mesoporous silicas for the selective adsorption of anionic dye in an aqueous solution”, J Hazard Mater, 168, 102–107, 2009.
13. [13] Babel, S., and Kurniawan, T.A, “Journal of Hazardous Materials”, B97, 219–243, 2003.
14. [14] El-Said, GF., “A Future Overview of the Usage of Minerals as an Eco-friendly Adsorbent for the Removal of Pollutants”, J Geol Geophys, 6, 3, 2017.
15. [15] Ong, L.K., Soetaredjo, F.E., Kurniawan, A., Ayucitra, A., Liu, J.C., and Ismadji, S., “Investigation on the montmorillonite adsorption of biocidal compounds incorporating thermodynamicalbased multicomponent adsorption isotherm,” Chem, Eng, J, 241, 9–18 ,2014.
16. [16] Mohan, D., and Singh, K.P., “Single- and multi-component adsorption of cadmium and zinc using activated carbon derived from bagasse--an agricultural waste”, Water Res, 36, 2304–2318, 2002.
17. [17] Bhattacharya, A.K., Mandal, S., and Das, S., “Adsorption of Zn(II) from aqueous solution by using different adsorbents”, Chem, Eng, J., 123, 43–51, 2006
18. [18] Arivoli, S., and Thenkuzhali, M., Kinetic, “mechanistic, thermodynamic and equilibrium studies on the adsorption of Rhodamine B by acid activated low cost carbon”, Electron J Chem 5, 187–200, 2008.
19. [19] Zhao, G., Jiang, L., He, Y., Li. J., Dong, H., Wang, X., and Hu, W., “Sulfonated graphene for persistent aromatic pollutant management,” Adv Mater 23,3959–3963, 2011.
20. [20] Anggraini, M., Kurniawan, A., Ong, L.K., Martin, M.A., Liu, J.C., Soetaredjo, F.E., Indraswati, N., and Ismadji, S, “Antibiotics detoxification from synthetic and real effluents using a novel MTAB surfactant—montmorillonite (organoclay) sorbent”, RSC Adv. 4, 16298–16311, 2014.
21. [21] Putra, E.K., Pranowo, R., Sunarso, J., Indraswati, N., and Ismadji, S., “Performance of activated carbon and bentonite for adsorption of amoxicillin from wastewater: mechanisms, isotherms and kinetics”, Water Res, 43, 2419–2430, 2009.
22. [22] Chaturvedi, A. K., Yadava, K. P., Pathak, K. C, and. Singh, V. N., “Defluoridation of water by adsorption on fly ash,” Water, Air, and Soil Pollution, vol. 49, no. 1-2, pp. 41–69, 1990.
23. [23] Sujana, M. G., Thakur, R. S., and. Rao, S. B., “Removal of fluoride from aqueous solution by using alum sludge,” Journal of Colloid and Interface Science, vol. 206, no. 1, pp. 94–101, 1998.
24. [24] Toyoda, A., and Taira, T., “A new method for treating fluorine wastewater to reduce sludge and running costs,” IEEE Transactions on Semiconductor Manufacturing, vol. 13, no. 3, pp. 305–309, 2000.
25. [25] WHO (World Health Organization), Fluorine and Fluorides, Environmental Health Criteria, Geneva, Switzerland, World Health Organization, 1984.
26. [26] Watson, R., “Climate change. Synthesis Report”, Cambridge University Press. UK, 2001.
27. [27] Jeong, J.Y., Kim, H.K., Kim, J.H. and Park, J.Y., “Electrochemical Removal of Nitrate Using ZVI Packed Bed Bipolar Electrolytic Cell”, Chemosphere, 89, 172-178,2012.
28. [28] Zhou, M., Fu, W., Gu, H. and Lei, L., “Nitrate Removal from Groundwater by a Novel Three-Dimensional Electrode Biofilm Reactor,” Electrochimica Acta, 52, 6052-6059,2007.
29. [29] Rytwo, G., Tropp, D., and Serban, C, “Adsorption of diquat, paraquat and methyl green on sepiolite: experimental results and model calculations”, Applied Clay Science, 20, 273–282, 2002.
30. [30] Roulia, M., and Vassiliadis, A.A.,”Sorption characterization of a cationic dye retained by clays and perlite”, Microporous and Mesoporous Materials, 116, (1–3), 732–740, 2008.
31. [31] Sandhya, B., and Tonni, A.K., “Low-cost adsorbents for heavy metals uptake from contaminated water: a review”, Journal of Hazardous Materials, B97, 219–243, 2003.
32. [32] Guggenheim, S., and Martin RT., “Definition of clay and clay mineral: joint report of the AIPEA nomenclature and CMS nomenclature committees”, Clay, Clay Miner, 43,255–256, 1995.
33. [33] Chen, C.C., and Hayes, KF., “X-ray absorption spectroscopy investigation of aqueous Co(II) and Sr(II) sorption at clay-water interfaces”, Geochim Cosmochim Acta, 63, 3205–3215, 1999.
34. [34] Murray, H,” Industrial clays case study”, Int Inst Environ Dev (IIED), 64, 1–9, 2002.
35. [35] Odom, IE., “Smectite clay minerals: properties and uses,” Philos Trans R Soc, A, 311, 391, 1984.
36. [36] Lagaly, G., “Surface and interlayer reactions: bentonites as adsorbents”, In, Churchman GJ, Fitzpatrick RW, Eggleton RA (eds) Clays controlling the environment. Proceedings of the 10th international clay conference, Adelaide, Australia. CSIRO Publishing, Melbourne, pp 137–144, 1995.
37. [37] Robertson, RHS., Fuller’s Earth: A History of calcium montmorillonite, Volturna Press, U.K, 1986.
38. [38] Hajjaji, M., and El Arfaoui, H., “Adsorption of methylene blue and zinc ions on raw and acid-activated bentonite from Morocco”, Applied Clay Science, 46, 418–421, 2009.
39. [39] Rafiei, H.R., Shirvani, M., Ogunseitan, O.A., “Removal of lead from aqueous solutions by a poly (acrylic acid)/ bentonite nanocomposite”, Appl Water Sci 6, 331–338, 2016.
40. [40] Saad, A. A., and Fares, D. A., “Adsorption of Cu & Ni on Bentonite Clay from Waste Water”, Athens Journal of Natural & Formal Sciences, vol.1, No.1, 2014.
41. [41] Mahfoud, B., Salah, C., Abdelhamid, M., Belgacem, B., Djamel N., and Makhlouf, B., “Application of Algerian Bentonite in the Removal of Cadmium (II) and Chromium (VI) from Aqueous Solutions”, Journal of Surface Engineered Materials and Advanced Technology, 4, 210-226, 2014.
42. [42] Bellir, K., Bencheikh-Lehocine, M., and Meniai, A-H., “Removal of methylene blue from aqueous solutions using an acid activated Algerian bentonite: equilibrium and kinetic studies”, Int Renew Energy Congr , 360–367, 2010.
43. [43] Raymond, K., Rhesa, P.U., Yi-Hsu, J., Aning, A., Felycia E.S., Jaka, S., Suryadi, I., “Acid Green 25 removal from wastewater by organo-bentonite from Pacitan”, Applied Clay Science, 48, 81–86, 2010.
44. [44] Tabak, A., Baltas, N., Afsin, B., Emirik, M., Caglar, B., and Eren, E, “Adsorption of reactive red 120 from aqueous solutions by cetylpyridinium-bentonite,” J. Chem. Technol. Biotechnol, 85, 1199–1207,2010.
45. [45] Yesi, Sisnandy, F.P., Ju, Y.H., Soetaredjo, F.E., and Smadji, S.,” Adsorption of acid blue 129 from aqueous solutions onto raw and surfactant modified bentonite: application of temperaturedependent forms of adsorption isotherms. Adsorpt. Sci. Technol,” 28, 847–868, 2010.
46. [46] Nevim, G., Esra, C., “Adsorption kinetics of the antibiotic ciprofloxacin on bentonite, activated carbon, zeolite, and pumice”, Desalination and Water Treatment, 53, 785–793,2015.
47. [47] Fernanda, M., Lidiane, C., and Nilce O., “The Use of Converter Slag (Magnetite) and Bentonite Clay for Amoxicillin Adsorption from Polluted Water”, Electron. J. Chem, 5, 3, 213-217, 2013.
48. [48] Mohamed, El Miz., Samira, S., Ikrame, C., Ali, El Bachiri., Marie-Laure, F., and Abdesselam T., “Characterization and Adsorption Study of Thymol on Pillared Bentonite”, Open Journal of Physical Chemistry, 4, 98-116, 2014.
49. [49] Yan, Z., De-yue, Q ., and Yue-jun, Q,. L. M.,. “Research on Absorption Treatment of Waste Water of Pirimiphos Methyl by Bentonite,” Fine Chem Intermed,2011(4), 2011.
50. [50] Moore, D., and Reynolds, R., X-ray diffraction and the identification and analysis of clay minerals, Oxford University Press, New York, 1997.
51. [51] Adebowale, K.O., Unuabonah, I.E,. and Olu-Owolabi B.I., “Adsorption of some heavy metal ions on sulfate- and phosphate-modified kaolin”, Applied Clay Science 29, 145– 148, 2005.
52. [52] Kamel, M.M., Ibrahm, M.A., Ismael, A.M., and.El-Motaleeb, M.A., “Adsorption of some heavy metal ions from aqueous solutions by using kaolinite clay”, Ass, Univ, Bull, Environ, Res, Vol, 7, No 1, 2004.
53. [53] Qingfeng, W., Hanlie, H., and Xiaoling, Z., “Studies on the Adsorption of p-Aminoazobenzene onto Kaolinite”, The Open Surface Science Journal, 4, 14-18, 2012.
54. [54] Kayode, O., Adebowale., Bamidele, I., Olu-Owolabi., Emmanuel, C., and Chigbundu., “Removal of Safranin-O from Aqueous Solution by Adsorption onto Kaolinite Clay”, Journal of Encapsulation and Adsorption Sciences, 4, 89-104, 2014.
55. [55] Soumia, Z., Fatima Zohra, El B., “Adsorption of tannery anionic dyes by modified kaolin from aqueous solution”, Desalination and Water Treatment, ISSN, 1944-3994, 2014.
56. [56] Sadiq, J.B., Ahmed, F. H., and Zahraa., H.A., “Removal Reactive Blue Dye from Wastewater by Adsorption on White Iraqi Kaolin clay”, Journal of Babylon University, Pure and Applied Sciences, No.,7, Vol.,22, 2014.
57. [57] Muhammad, S., Makshoof, A., Umer ,S., Rabia, R., Sadia, A., Sana, Z., and Muhammad, A., “Removal of formaldehyde from aqueous solution by adsorption on kaolin and bentonite: a comparative study”, Turkish J. Eng. Env. Sci,.36 , 263 – 270, 2012.
58. [58] Morteza, M., Shamsuddin, S., and Kumars E., “Nitrate Adsorption on Clay Kaolin: Batch Tests”, Journal of Chemistry Volume, Article ID 397069, 7 pages,2015.
59. [59] Jaafar S., “Adsorption study—dye removal using clay” A B. Chem. Eng, Thesis, Faculty of Chemical Engineering and Natural Resources, University College of Engineering & Technology, 2006.
60. [60] Nurdan, G., and Okan O., “Study of Montmorillonite Clay for the Removal of Copper (II) by Adsorption”, Full Factorial Design Approach and Cascade Forward Neural Network, Hindawi Publishing Corporation The Scientific World Journal Volume, Article ID 342628, 11 pages, 2013.
61. [61] He, H., Guo, J., Xie, X., and Peng, J., “Experimental study of the selective adsorption of heavy metals onto clay minerals”, Chinese Journal of Geochemistry, https://link.springer.com/article/10.1007/BF03166865, 2000.
62. [62] Brigatti, M.F., Colonna, S., Malferraria, D., Medici, L., and Poppi L., “Mercury adsorption by montmorillonite and vermiculite: a combined XRD, TG-MS, and EXAFS study”, Applied Clay Science, 28, 1– 8, 2005.
63. [63] Susmita, S. G., and Krishna, G. B., “Treatment of water contaminated with Pb(II) and Cd(II) by adsorption on kaolinite, montmorillonite and their acid-activated forms”, Indian Journal of chemical technology, Vol. 16, pp,457-470, November 2009.
64. [64] Tahir, H., Hammed, U., Sultan, M., and Jahanze, Q., “Batch adsorption technique for the removal of malachite green and fast green dyes by using montmorillonite clay as adsorbent,” Afr J Biotechnol, 9, 8206–8214, 2010.
65. [65] Günay, A., Bahri, E., Sedef, D., and Atilla E., “Investigation of equilibrium, kinetic, thermodynamic and mechanism of Basic Blue 16, adsorption by Montmorillonitic Clay, Adsorption”, v 19, Issue 2-4, 757-768, DOI 10.1007, s10450-013-9509-4, April 2013.
66. [66] Djelloul, B., Tabet Ainad, D., and Djillali, B., “Removal of Anionic Dye by Natural Algerian Montmorillonite”, J Environ Anal Chem, an open access journal, Volume 2, Issue 2, 2015.
67. [67] Barbooti, M., M, Su H., Punamiya, P,. and Sarkar, D., “Oxytetracycline sorption onto Iraqi montmorillonite”, Int. J. Environ. Sci. Technol, 11:69–76, 2014.
68. [68] Karthikeyan, G., Anitha, P., and Alagumuthu, G., “Fluoride adsorption studies of montmorillonite clay”, Indian Journal of Chemical Technology, Vol. 12, pp. 263-272, 2005.
69. [69] Bish, D.L., and Ming, D.W., “Applications of natural zeolites in water and wastewater treatment, Natural Zeolites: Occurrence, Properties”, Applications, 45, 2001.
70. [70] Kallo, D., “Applications of natural zeolites in water and wastewater treatment, in: D.L. Bish, D.W.Ming (Eds.)”, Natural Zeolites, Occurrence, Properties, Applications, 519–550, 2001.
71. [71] Hedstrom, A., “Ion exchange of ammonium in zeolites: a literature review”, Journal of Environmental Engineering, ASCE, 127, 673–681, 2001.
72. [72] Kesraouiouki, S., Cheeseman, C.R., and Perry R., “Natural zeolite utilization in pollution-control—a review of applications to metals effluents”, Journal of Chemical Technology and Biotechnology, 59, 121–126, 1994.
73. [73] Caputo, D., and Pepe, F., “Experiments and data processing of ion exchange equilibria involving Italian natural zeolites”, a review, Microporous and Mesoporous Materials, 105, 222–231, 2007.
74. [74] Tarek, S., Jamil, H.S., Ibrahim, I.H., Abd El-Maksoud, S.T., and El-Wakeel, “Application of zeolite prepared from Egyptian kaolin for removal of heavy metals: Optimum conditions, “ Desalination 258, 34–40, 2010.
75. [75] Malamis, S., and. Katsou, E., “A review on zinc and nickel adsorption on natural and modified zeolite, bentonite and vermiculite”, Examination of process parameters, kinetics and isotherms, Journal of Hazardous Materials, 252– 253, 428– 461,2013.
76. [76] Nurul, W., Hongwei, W., Ha, M.A., Dongke, Z., “Removal of ammonium from greywater using natural zeolite”, Desalination 277, 15–23, 2011.
77. [77] Mohsen, H., “Adsorption and removal of tetracyclin antibiotic from water by zeolite adsorbent”, International Journal of Geology, Earth & Environmental Sciences, ISSN, 2277-2081, Vol. 7, (1), pp. 55-64, January-April, 2017.
78. [78] Mária, V., Ján, D., Katarína, Š., “Removal of selected pesticides by adsorption”, Acta Chimica Slovaca, Vol. 6, No. 1, pp. 25—28, 2013.
79. [79] Baltrusaitis, J., and Grassian, V. H., “Calcite surface in humid environments”, Surf. Sci, 603, L99-L104, 2009.
80. [80] Villegas-Jiménez, A., Mucci, A., and Whitehead, M. A., “Theoretical insights into the hydrated (10.4) calcite surface: structure, energetics, and bonding relationships,” Langmuir 25, 6813-24,2009.
81. [81] Green-Pedersen, H., and Jensen, B. T., “Nickel adsorption on MnO2, Fe(OH)3, montmorillonite, humic acid and calcite: A comparative study”, Environmental Technology, 18, 807-815,1997.
82. [82] Lakshtanov, L. Z., and Stipp, S. L. S., “Experimental study of nickel(II) interaction with calcite” Adsorption and coprecipitation. Geochimica et Cosmochimica Acta , 71, 15, 3686-3697, 2007.
83. [83] Zachara J.M., Cowan, C. E., and Resch, C.T,” Sorption of divalent metals on calcite,” Geochim, Cosmochim, Acta 55, 1549-1562,1991.
84. [84] Román-Ross, G., Cuello, G. J., Turrillas, X., Fernández-Martínez, A., and Charlet, L., “Arsenite sorption and co-precipitation with calcite. Geochim. Cosmochim”, Acta 233, 328 – 336, 2006.
85. [85] Rouff, A.A., and Reeder, R. J., “Electrolyte and pH effects on Pb(II)-calcite sorption processes: the role of the PbCO03(aq) complex”, Journal of Colloid and Interface Science 286(1), 61-67, 2005.
86. [86] Van der Weijden, R. D., and Comans, R. N. J., Sorption and sorption reversibility of cadmium on calcite in the presence of phosphate and sulfate,” Mar. Chem,. 57, 119-132, 1997.
87. [87] Gülten, A., and Elif T., “Competitive Adsorption of Basic Dyes onto Calcite in Single and Binary Component Systems”, Separation Science and Technology, 45, 1471–1481, 2010.
88. [88] Ben Nasr, A., Walha, K,. Puel, F,. Mangin, D,. Ben Amar, R. and Charcosset, C., “Precipitation and adsorption during fluoride removal from water by calcite in presence of acid, Desalin. Water Treat”, doi: 10.1080/19443994.2013.799441, 2013.
89. [89] Kostantinos, K., Maximos, P., and Georgios, N., “Removal of phosphate species from solution by adsorption onto calcite used as natural adsorbent”, Journal of Hazardous Materials, A, 139, 447 –452, 2007.