Evaluation of the thermodynamic behavior of white benzoin via inverse gas chromatography

Ayşe Erdoğan Çakar

Evaluation of the thermodynamic behavior of white benzoin via inverse gas chromatography

Öz

This study, the thermodynamic properties of white benzoin (WB) were examined by the inverse gas chromatography (IGC) method. To evaluate the polymer-solvent interaction parameters, the specific retention volume of the solvents, V_g^0 values were determined using various nonpolar and polar solvents in the temperature range of 373.2 –398.2 K. Then, from these data, the values of the Flory-Huggins theory polymer-solvent interaction parameters, χ_12^∞, equation of state theory, polymer-solvent interaction parameters, χ_12^*, effective exchange energy parameters, X_eff, and also the partial molar heat of mixing at infinite dilution of solvent, ∆H ̅_1^∞, the molar heat of vaporization of solvent, ∆H ̅_v, and the partial molar heat of sorption of solvent, ∆H ̅_s, were calculated. The results obtained were discussed.

Anahtar Kelimeler

Kaynakça

Atia Sharif HN, Rehman R, Mushtaq A, Rashid U (2016) Review on bioactive potential of Benzoin resin. Int J Chem Biochem Sci 10:106–110.
Hacini Z, Khedja F, Habib I, Kendour Z, Debba Z (2018) Evaluation of antibacterial and antioxidant activities of three types of benzoin resin. European Journal of Chemistry 9:408–411.
Katz E, García Fernandez C, Goloubinoff M (2002) Sumatra benzoin (Styrax spp.).
Evans WC, Evans D (2009) Trease and Evans’ Pharmacognosy Chapter 19—Hydrocarbons and derivatives. (Sixteenth Edition); Eds 2009:173–193.
Abbott S (2018) IGC Science: Principles and Practice. Adscientis Paris, France 44–49.
Boudriche L, Calvet R, Hamdi B, Balard H (2012) Surface properties evolution of attapulgite by IGC analysis as a function of thermal treatment. Colloids and Surfaces A: Physicochemical and Engineering Aspects 399:1–10.
Erdogan Cakar A (2026) Physicochemical characterization of thermodynamic parameters and isomer separation of Hemin by inverse gas chromatography. Brazilian Journal Of Chemical Engineering 43(1):241-253.
Zunino F, Palacios M, Bowen P, Scrivener K (2024) Surface properties of clinker phases and clay minerals characterized by inverse gas chromatography (IGC) and their link to reactivity. Cement and Concrete Research 178:107458.

Voelkel A, Andrzejewska E, Limanowska-Shaw H, Andrzejewski M (2005) Acid–base surface properties of glass-ionomers determined by IGC. Applied surface science 245:149–154.
Cakar AE, Cakar F, Ocak H, Karavelioglu S, Eran BB, Cankurtaran O (2023) Determination of thermodynamic properties and phase transition temperatures of phenylbenzoate-based calamitic liquid crystals by inverse gas chromatography method. Phase Transitions 96:731–745.
Bolvari A, Ward TC, Koning P, Sheehy D (1989) Experimental techniques for inverse gas chromatography. In: ACS Publications.
Hu D, Wang Q, Li J, Chen Y, Muhammad F, Zhang Y, Yalikun N, Huang H (2024) Thermodynamic properties of TPAC-EG deep eutectic solvents: A study based on the IGC method with molecular simulations. Journal of Molecular Liquids 407:125120.
Farshchi N, Abbasian A, Larijani K (2018) Assessment of the thermodynamic properties of DL-p-mentha-1, 8-diene, 4-isopropyl-1-methylcyclohexene (DL-limonene) by inverse gas chromatography (IGC). Journal of Chromatographic Science 56:671–678.
Yurtcu Celik S, Erdogan Cakar A, Ugraskan V, Yazici O (2026) Investigation of thermodynamic properties of agar via inverse gas chromatography. Journal of Polymer Research 33:64.
Voelkel A, Strzemiecka B, Milczewska K, Okulus Z (2015) Inverse gas chromatographic examination of polymer composites. Open Chemistry13:000010151520150104.
Smidsrød O, Guillet J (1969) Study of polymer-solute interactions by gas chromatography. Macromolecules 2:272–277.
Flory P, Orwoll R, Vrij A (1964) Statistical thermodynamics of chain molecule liquids. I. An equation of state for normal paraffin hydrocarbons. Journal of the American Chemical Society 86:3507–3514.
Revelli A-L, Mutelet F, Jaubert J-N, Garcia-Martinez M, Sprunger LM, Acree Jr WE, Baker GA (2010) Study of ether-, alcohol-, or cyano-functionalized ionic liquids using inverse gas chromatography. Journal of Chemical & Engineering Data 55:2434–2443.
McGlashan M, Potter D (1951) An apparatus for the measurements of the second virial coefficient using glycerol. In Proc R Soc.: 448–456.
Shillcock IM, Price GJ (2004) Interactions of solvents with low molar mass and side chain polymer liquid crystals measured by inverse gas chromatography. The Journal of Physical Chemistry B 108:16405–16414.
Voelkel A, Strzemiecka B, Marek AA, Zawadiak J (2014) Inverse gas chromatography investigation of oxidized polyolefins: Surface properties. Journal of Chromatography A 1337:194–201.
Yilmaz F, Cankurtaran Ö (1998) A study on the parameters of exchange enthalpy, X12, and entropy, Q12, in the equation-of-state theory for some polymer-solvent pairs. Polymer 39:1243–1247.
Çakar F, Cankurtaran O (2005) Determination of secondary transitions and thermodynamic interaction parameters of poly (ether imide) by inverse gas chromatography. Polymer Bulletin 55:95–104.
Myers MN (1971) Gas chromatography, principles, techniques, and application (Littlewood, AB). In Book Gas chromatography, principles, techniques, and application (Littlewood, AB) (Editor ed. eds.). City: ACS Publications.

Ayrıntılar

Birincil Dil

İngilizce

Konular

Malzeme Bilimi ve Teknolojileri

Bölüm

Araştırma Makalesi

Yazarlar

Ayşe Erdoğan Çakar ^*
0000-0002-5568-3959
Türkiye

Yayımlanma Tarihi

30 Temmuz 2026

Gönderilme Tarihi

10 Mayıs 2026

Kabul Tarihi

17 Temmuz 2026

Yayımlandığı Sayı

Yıl 2026 Cilt: 6 Sayı: 2

IZ

https://izlik.org/JA38WU35RG

Kaynak Göster

RIS / Bibtex

APA

Erdoğan Çakar, A. (2026). Evaluation of the thermodynamic behavior of white benzoin via inverse gas chromatography. Journal of Innovative Engineering and Natural Science, 6(2), 368-376. https://izlik.org/JA38WU35RG

AMA

1.Erdoğan Çakar A. Evaluation of the thermodynamic behavior of white benzoin via inverse gas chromatography. JIENS. 2026;6(2):368-376. https://izlik.org/JA38WU35RG

Chicago

Erdoğan Çakar, Ayşe. 2026. “Evaluation of the thermodynamic behavior of white benzoin via inverse gas chromatography”. Journal of Innovative Engineering and Natural Science 6 (2): 368-76. https://izlik.org/JA38WU35RG.

EndNote

Erdoğan Çakar A (01 Temmuz 2026) Evaluation of the thermodynamic behavior of white benzoin via inverse gas chromatography. Journal of Innovative Engineering and Natural Science 6 2 368–376.

IEEE

[1]A. Erdoğan Çakar, “Evaluation of the thermodynamic behavior of white benzoin via inverse gas chromatography”, JIENS, c. 6, sy 2, ss. 368–376, Tem. 2026, [çevrimiçi]. Erişim adresi: https://izlik.org/JA38WU35RG

ISNAD

Erdoğan Çakar, Ayşe. “Evaluation of the thermodynamic behavior of white benzoin via inverse gas chromatography”. Journal of Innovative Engineering and Natural Science 6/2 (01 Temmuz 2026): 368-376. https://izlik.org/JA38WU35RG.

JAMA

1.Erdoğan Çakar A. Evaluation of the thermodynamic behavior of white benzoin via inverse gas chromatography. JIENS. 2026;6:368–376.

MLA

Erdoğan Çakar, Ayşe. “Evaluation of the thermodynamic behavior of white benzoin via inverse gas chromatography”. Journal of Innovative Engineering and Natural Science, c. 6, sy 2, Temmuz 2026, ss. 368-76, https://izlik.org/JA38WU35RG.

Vancouver

1.Ayşe Erdoğan Çakar. Evaluation of the thermodynamic behavior of white benzoin via inverse gas chromatography. JIENS [Internet]. 01 Temmuz 2026;6(2):368-76. Erişim adresi: https://izlik.org/JA38WU35RG