PVDF nanofibers composite containing core-shell (ZnO@ZIF-8) for use in smart textile applications

Yıl 2023, Cilt: 3 Sayı: 2, 103 - 110, 31.07.2023

Miladi Atıghı Moein Jalalı Mahdi Hasanzadeh Seyed Mansour Bıdokı

https://doi.org/10.29228/JIENS.70341

Öz

Currently, electronic textiles (E-textiles) have gained tremendous attention. In recent years, there has been significant interest in metal-organic frameworks (MOFs), which are emerging porous materials and have gained immense interest in recent years. In this study, we successfully synthesized a core-shell zinc oxide @ zeolite imidazolate framework-8 (ZnO@ZIF-8) composite and used it to fabricate electrospun polyvinylidene fluoride (PVDF) nanofibrous composites. Nanofibers were produced using an electrospinning machine. We analyzed the synthesized (ZnO@ZIF-8) powder and PVDF and PVDF/(ZnO@ZIF-8) nanofibrous composite using field emission scanning electron microscopy and X-ray diffraction techniques to investigate their morphological and crystallographic structures. The results demonstrated the successful fabrication of uniform and bead-free nanofibers. The incorporation of (ZnO@ZIF-8) composite particles into the PVDF polymer solution resulted in an increased β-phase content in the fabricated PVDF/(ZnO@ZIF-8) nanofibrous composite compared to the pristine PVDF nanofibrous composite. The nanofibrous mat has various applications, including E-Textiles, flexible sensors, energy scavenging, smart textiles, wearable devices, and energy harvesting.

Anahtar Kelimeler

Electrospinning, Metal-organic framework, Nanofiber, PVDF, Zinc oxide

Teşekkür

We acknowledge the Research Laboratory of Yazd University for their support.

Kaynakça

• Hasanzadeh M, Ghahhari MR, Bidoki SM (2021) Enhanced piezoelectric performance of PVDF-based electrospun nanofibers by utilizing in situ synthesized graphene-ZnO nanocomposites. Journal of Materials Science: Materials in Electronics. https://doi.org/10.1007/s10854-021-06132-w
• Moghadam BH, Hasanzadeh M, Simchi A (2020) Self-Powered Wearable Piezoelectric Sensors Based on Polymer Nanofiber–Metal–Organic Framework Nanoparticle Composites for Arterial Pulse Monitoring. ACS Appl Nano Mater 3(9):8742–8752. https://doi.org/10.1021/acsanm.0c01551
• You MH et al. (2018) A self-powered flexible hybrid piezoelectric-pyroelectric nanogenerator based on non-woven nanofiber membranes. J Mater Chem A Mater 6(8):3500–3509. https://doi.org/ 10.1039/c7ta10175a
• Bagherzadeh R, Abrishami S, Shirali A, and Rajabzadeh AR (2022) Wearable and flexible electrodes in nanogenerators for energy harvesting, tactile sensors, and electronic textiles: novel materials, recent advances, and future perspectives. Materials Today Sustainability 20:100233. https://doi.org/10.1016/j.mtsust.2022.100233
• Bagherzadeh R. Abrishami S, Shirali A, and Rajabzadeh AR (2022) Wearable and flexible electrodes in nanogenerators for energy harvesting, tactile sensors, and electronic textiles: novel materials, recent advances, and future perspectives. Materials Today Sustainability 20:100233. https://doi.org/10.1016/j.mtsust.2022.100233
• Tiwari S, Gaur A, Kumar C, Maiti P (2019) Enhanced piezoelectric response in nanoclay induced electrospun PVDF nanofibers for energy harvesting. Energy 171:485–492. https://doi.org/10.1016/j.energy.2019.01.043
• Sorayani Bafqi MS, Bagherzadeh R, Latifi M (2015) Fabrication of composite PVDF-ZnO nanofiber mats by electrospinning for energy scavenging application with enhanced efficiency. Journal of Polymer Research. https://doi.org/10.1007/s10965-015-0765-8
• Parangusan H, Ponnamma D, Al-Maadeed MAA (2018) Stretchable Electrospun PVDF-HFP/Co-ZnO Nanofibers as Piezoelectric Nanogenerators. Sci Rep. https://doi.org/10.1038/s41598-017-19082-3
• Shaukat RA et al. (2022) Ultra-robust tribo- and piezo-electric nanogenerator based on metal organic frameworks (MOF-5) with high environmental stability. Nano Energy 96:107128. https://doi.org/10.1016/j.nanoen.2022.107128
• Zhu J et al. (2019) Preparation of PVDF/TiO2 nanofibers with enhanced piezoelectric properties for geophone applications. Smart Mater Struct 28(8):085006. https://doi.org/10.1088/1361-665X/ab29a9
• Atighi M and Hasanzadeh M (2022) Design and Characterization of Electrospun PVDF Nanofibers Containing Graphene Oxide/Metal-Organic Framework Composites for Potential Piezoelectric Applications. The 15th International Seminar on Polymer Science and Technology, ISPST2022, 8-10 November of 2022, IUT, Isfahan, Iran.
• Atighi M, Hasanzadeh M (2023) In-situ growth of zinc-based metal-organic framework (Zn-MOF) on Ti3C2Tx MXene nanosheets. The 9th International Congress on Nanoscience & Nanotechnology, ICNN2022, 1-2 March 2023, University of Tehran, Tehran, Iran.
• Falahati G, Atighi M, Hasanzadeh M (2023) Synthesis and characterization of novel MOF-GO nanocomposite for adsorptive removal of organic dyes from aqueous solution. The 9th International Congress on Nanoscience & Nanotechnology, ICNN2022, 1-2 March 2023, University of Tehran, Tehran, Iran.
• Atighi M, Hasanzadeh M, Sadatalhosseini AA, Azimzadeh HR (2022) Metal–Organic Framework@Graphene Oxide Composite-Incorporated Polyacrylonitrile Nanofibrous Filters for Highly Efficient Particulate Matter Removal and Breath Monitoring. Ind Eng Chem Res. https://doi.org/10.1021/acs.iecr.2c03825
• Far HS, Hasanzadeh M, Nashtaei MS, Rabbani M (2021) Fast and efficient adsorption of palladium from aqueous solution by magnetic metal–organic framework nanocomposite modified with poly(propylene imine) dendrimer. Environmental Science and Pollution Research 28(44):62474–62486. https://doi.org/10.1007/s11356-021-15144-2
• Khosravi F, Soltan M, Hajiani M, Haji A (2019) Application of Polymeric Nanofibers for Removal of Dyes Graphical abstract. Journal of Studies in Color World 9(1):39–62.
• Lee YR, Jang MS, Cho HY, Kwon HJ, Kim S, Ahn WS (2015) ZIF-8: A comparison of synthesis methods. Chemical Engineering Journal 271:276–280. https://doi.org/10.1016/j.cej.2015.02.094
• Abedi A, Hasanzadeh M, Tayebi L (2019) Conductive nanofibrous Chitosan/PEDOT:PSS tissue engineering scaffolds. Mater Chem Phys 237:121882. https://doi.org/10.1016/j.matchemphys.2019.121882
• Maddah B, Yavaripour A, Ramedani SH, Hosseni H, Hasanzadeh M (2020) Electrospun PU nanofiber composites based on carbon nanotubes decorated with nickel-zinc ferrite particles as an adsorbent for removal of hydrogen sulfide from air. Environmental Science and Pollution Research 27(28):35515–35525. https://doi.org/10.1007/s11356-020-09324-9
• Zhan W, Kuang Q, Zhou J, Kong X, Xie Z, Zheng L (2013) Semiconductor@Metal–Organic Framework Core–Shell Heterostructures: A Case of ZnO@ZIF-8 Nanorods with Selective Photoelectrochemical Response. J Am Chem Soc 13585):1926–1933. https://doi.org/10.1021/ja311085e
• Ren G et al. (2019) ZnO@ZIF-8 core-shell microspheres for improved ethanol gas sensing. Sens Actuators B Chem 284:421–427. https://doi.org/10.1016/j.snb.2018.12.145
• Yu B, Wang F, Dong W, Hou J, Lu P, Gong J (2015) Self-template synthesis of core–shell ZnO@ZIF-8 nanospheres and the photocatalysis under UV irradiation, Mater Lett 156:50–53. https://doi.org/10.1016/j.matlet.2015.04.142
• Wu Y, Qu J, Daoud WA, Wang L, Qi T (2019) Flexible composite-nanofiber based piezo-triboelectric nanogenerators for wearable electronics. J Mater Chem A Mater 7(21):13347–13355. https://doi.org/10.1039/C9TA02345C
• Bafqi MSS, Sadeghi AH, Latifi M, Bagherzadeh R (2021) Design and fabrication of a piezoelectric out-put evaluation system for sensitivity measurements of fibrous sensors and actuators. Journal of Industrial Textiles 50(10):1643–1659. https://doi.org/10.1177/1528083719867443
• Cardoso VF, Minas G, Costa CM, Tavares CJ, Mendez SL (2011) Micro and nanofilms of poly(vinylidene fluoride) with controlled thickness, morphology and electroactive crystalline phase for sensor and actuator applications. Smart Mater Struct 2088):087002. https://doi.org/10.1088/0964-1726/20/8/087002
• Nunes JS, Wu A, Gomes J, Sencadas V, Vilarinho PM, Méndez SL (2009) Relationship between the microstructure and the microscopic piezoelectric response of the α- and β-phases of poly(vinylidene fluoride). Applied Physics A 95(3):875–880. https://doi.org/10.1007/s00339-009-5089-2