Hidrazon Grubu Taşıyan vic-Dioksim Türevlerinin ve Onların Metal Komplekslerinin Sentezi ve Spektrofotometrik İncelemesi

Yıl 2017, Cilt: 7 Sayı: 4, 161 - 168, 31.12.2017

Nursabah Sarıkavaklı

Öz

Bu çalışmada, hidrazon ve vic-dioksim grubu içeren; (1Z,2E)-N’-[(1Z)-(4-bromofenil)metilen]-2-

(hidroksiimino)etanhidroksimhidrazid, L1H2, (1Z,2E)-N’-[(1Z)-(2-klorofenil)metilen]-2-(hidroksiimino)

etanhidroksimhidrazid, L2H2, (1Z,2E)-N’-[(1Z)-(3-klorofenil)metilen]-2-(hidroksiimino)etanhidroksimhidrazid,

L3H2 hidrazonoksim türevleri elde edilmiştir. Bu hidrazonoksim bileşikleri [(1Z,2E)-2-(hidroksiimino)

etanhidroksimhidrazid]’in aldehit ve ketonlarla verdiği kondenzasyon reaksiyonu ile sentezlenmiştir. Elde edilen

hidrazonoksim türevlerinin nikel(II), bakır(II), kobalt(II) kompleksleri izole edildikten sonra hem ligandların hem

de komplekslerin yapıları elementel analiz, manyetik süsseptibilite, erime noktası, 1H-NMR, 13C-NMR, UV-Vis,

FT-IR, TGA-DTG ile karakterize edildi.

Anahtar Kelimeler

FTIR, hidrazonoksim, kompleks, NMR, vic-dioksim

Synthesis and Spectrophotometrical Investigation of vic-Dioxim Derivatives Bearing Hydrazone Group and Their Metal Complexes

Öz

In this work an attempt has been to explore some important characteristics of the hydrazoneoxime

derivatives bearing hydrazone and vic-dioxime group, which were obtained from the materials such as: (1Z,2E)-

N’-[(1Z)-(4-bromophenyl)methylene]-2-(hydroxyimino)ethanehydroximohydrazide, L1H2, (1Z,2E)-N’-[(1Z)-(2-

chlorophenyl)methylene]-2-(hydroxyimino)ethanehydroximohydrazide, L2H2, (1Z,2E)-N’-[(1Z)-(3-chlorophenyl)

methylene]-2-(hydroxyimino)ethanehydroximohydrazide, L3H2. All these hydrazoneoxime compounds were

synthesized in terms of the reaction condensation of GH2, [(1Z,2E)-2-(hydroxyimino)ethanehydroximohydrazide]

with aldehydes and ketones. It has been found that some of complexes; e.g. nickel(II), copper(II), cobalt(II) from

the hydrazone-oxime derivatives have been isolated, and the structures of both ligands and complexes were

characterized by various techniques; by elemental analysis, magnetic susceptibility, melting point, 1H-NMR,

13C-NMR, UV-Vis, FT-IR and TGA-DTG.

Anahtar Kelimeler

FTIR, hydrazoneoxime, complex, NMR, vic-dioxime

Kaynakça

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