Araştırma Makalesi
BibTex RIS Kaynak Göster

Fenol-4-Sülfonik Asit ve 1,3-Bis(4-Piridil)Propan Tabanlı Yeni Organik Bileşiğin Hidrotermal Sentezi ve Karakterizasyonu

Yıl 2020, Cilt: 10 Sayı: 1, 163 - 170, 01.03.2020
https://doi.org/10.21597/jist.620043

Öz

Bu çalışmada, yeni iki-boyutlu organik bileşik [PSA2][BPP2] (psa=fenol-4-sülfonik asit, bpp=1,3-Bis(4-piridil)propan) hidrotermal yöntem ile sentezlendi, tek kristal X-ışını kırınımı, toz kristal X-ışını kırınım yöntemi (PXRD), element analizi ve katı-hal UV-vis spektroskopisi ile karakterize edildi. Kristal yapı analizi, bileşiğin ortorombik kristal sisteminde Pca21 uzay grubunda kristalleştiğini ve asimetrik biriminde iki psa ve iki bpp ligandından oluştuğunu göstermektedir. Fenol ve piridil grupları neredeyse düzlemseldir. Ek olarak, bileşiğin kristal yapısı moleküller arası O–H…O, C–H…O hidrojen bağlarının yanı sıra molekül içi C–H…π ve bpp molekülleri arasında meydana gelen π - π etkileşimleriyle iki-boyutlu yapıyı oluşturmuş ve yapısal kararlılık sağlamıştır.

Kaynakça

  • Atria AM, Corsini G, Garland MT, Baggio R, 2011. Poly[4,4′-(propane-1,3-diyl)dipyridiniumbis{tetraaquabis(μ2-5-carboxybenzene-1,2,4-tricarboxylato)bis[μ2-1,3-bis(4-pyridyl)propane]dicobalt(II)}pentahydrate]. Acta Crystallographica Section C Structural Chemistry, 67: m367–m370.
  • Clark RC, Reid JS, 1995. The analytical calculation of absorption in multifaceted crystals. Acta Crystallographica Section A Foundations and Advances, 51: 887–897.
  • Coban MB, 2017. Synthesis and photophysical properties of new Eu(III) complex. Balıkesir Üniversitesi Fen Bilimleri Enstitüsü Dergisi, 19: 7–15.
  • Coban MB, Amjad A, Aygun M, Kara H, 2017. Sensitization of Ho(III) and Sm(III) luminescence by efficient energy transfer from antenna ligands: Magnetic, visible and NIR photoluminescence properties of Gd(III), Ho(III) and Sm(III) coordination polymers. Inorganica Chimia Acta, 455: 25–33.
  • Coban MB, 2018. Hydrothermal synthesis, crystal structure, luminescent and magnetic properties of a new mononuclear Gd(III) coordination complex. Journal of Molecular Structure, 1162: 109–116.
  • Coban MB, Gungor E, Kara H, Baisch U, Acar Y, 2018. New mixed valence defect dicubane cobalt(II)/cobalt(III) complex: Synthesis, crystal structure, photoluminescence and magnetic properties. Journal of Molecular Structure, 1154: 579–586.
  • Coban MB, 2019. Magnetic and photophysical properties of new TbIII – based twodimensional hydrogen-bonded polymer. Journal of Molecular Structure, 1177: 331–337.
  • Dai Y-M, Shen H-Y, Huang J-F, 2005. Terephthalic acid–1,3-di-4-pyridylpropane (1/1). Acta Crystallographica Section E Crystallographica Communications, 61: o3410–o3411.
  • Dolomanov OV, Bourhis LJ, Gildea RJ, Howard JAK, Puschmann H, 2009. OLEX2 : a complete structure solution, refinement and analysis program. Journal of Applied Crystallography, 42: 339–341.
  • Erkarslan U, Donmez A, Kara H, Aygun M, Coban MB, 2018. Synthesis, structure and photoluminescence performance of a new Er3+-cluster-based 2D coordination polymer. Journal of Cluster Science, 29: 1177–1183.
  • Hu Z, Li B, Ju W, Liang Y, Chen Z, 2016. Synthesis and structures of two new Cu(I) frameworks bearing1,3-bis(4-pyridyl)propane and inorganic linkers. Journal of Chemical Science, 128: 893–898.
  • Kara H, 2018. Synthesis and 3D crystal structure of new Ni(II)-ion-pair complex. Balıkesir Üniversitesi Fen Bilimleri Enstitüsü Dergisi, 20: 1–7.
  • Kocak C, Oylumluoglu G, Donmez A, Coban MB, Erkarslan U, Aygun M, Kara H, 2017. Crystal structure and photoluminescence properties of a new monomeric copper(II) complex: bis(3-{[(3-hydroxypropyl)imino]methyl}-4-nitrophenolato-κ3O,N,O')copper(II). Acta Crystallographica Section C Structural Chemistry, 73: 414–419.
  • Li H-H, Li H, Niu Z, Wang Y-P, 2015. Structural diversity of two novel Dy(III) metal-organic frameworks based on binuclear nodes with furan-2,5-dicarboxylic acid: Crystal structures and luminescent properties. Inorganic Chemistry Communications, 55: 103–107.
  • Oylumluoğlu G, 2018. 4,4- bipiridin ve 2-amino-1,4-benzendikarboksilik asit tabanlı yeni bilesigin sentezlenmesi ve hidrojen baglı 3D polimerik yapısı. Balıkesir Üniversitesi Fen Bilimleri Enstitüsü Dergisi, 20: 320–326.
  • Ren Y, Chai H, Tang L, Hou X, Wang J, 2016. Structural diversity and fluorescence properties of three 2-sulfoterephthalate Cd(II)/Zn(II) coordination polymers employing 1,4-bisbenzimidazole. Journal of Solid State Chemistry, 234: 103–109.
  • Sheldrick GM, 2015a. Crystal structure refinement with SHELXL. Acta Crystallographica Section C Structural Chemistry, 71: 3–8.
  • Sheldrick GM, 2015b. SHELXT – Integrated space-group and crystal-structure determination. Acta Crystallographica Section A Foundations and Advances, 71: 3–8.
  • Shen H-Y, Wang W-M, Gao H-L, Cui J-Z, 2016. Near-infrared luminescence and SMM behaviors of a family of dinuclear lanthanide 8-quinolinolate complexes. Royal Society of Chemistry Advances, 6: 34165–34174.
  • Spek AL, 2009. Structure validation in chemical crystallography. Acta Crystallographica Section D Structural Biology, 65: 148–155.
  • Sun Y-Y, Dong H-Z, Cheng L, 2008. 1,3-Bis[4-(4-pyridyl)pyrimidin-2-ylsulfanyl]propane. Acta Crystallographica Section E Crystallographica Communications, 64: o901–o901.
  • Yang E, Song X-C, Zhuang R-Q, 2008. 4,4′-(Propane-1,3-diyl)dipiperidinium sulfate monohydrate. Acta Crystallographica Section E Crystallographica Communications, 64: o1763–o1763.
  • Zhang J-Y, Shi J-X, Chen L-Y, Jia Q-X, Deng W, Gao E-Q, 2017. N-donor auxiliary ligand-directed assembly of Co(II) compounds with a 2,2′-dinitro-biphenyl-4,4′-dicarboxylate ligand: structures and magnetic properties. Crystal Engineering Communications, 19: 1738–1750.
  • Zhou RS, Shao J, Li Y, Song JF, 2017. Three new imidazole dicarboxylate metal compounds: Synthesis, structures, and magnetic property. Inorganic Nano-Metal Chemistry, 47: 509–514.

Hydrothermal Synthesis and Characterization of New Organic Compound Based on Phenol-4-Sulfonic Acid and 1,3-Bis(4-Pyridyl)Propane

Yıl 2020, Cilt: 10 Sayı: 1, 163 - 170, 01.03.2020
https://doi.org/10.21597/jist.620043

Öz

In this study, the new 2D organic compound [PSA2][BPP2] (psa=phenol-4-sulfonic acid, bpp=1,3-Bis(4-pyridyl)propane was hydrothermally synthesized and characterized by single-crystal X-ray diffraction, powder X-ray diffraction (PXRD), elemental analysis, and solid-state UV-vis absorption spectra. The crystal structure analysis of the compound indicates that complex crystallizes in the orthorhombic crystal system Pca21 space group and its asymmetric unit consists of two discrete psa and bpp ligand. The ring of phenol and pyridyl groups is almost planar. Additionally, crystal structure of the compound is linked via intermolecular O – H…O and C – H…O hydrogen bonds as well as intramolecular C–H…π and between the bpp molecules π - π interactions, which form two-dimensional structure and provide structural stability.

Kaynakça

  • Atria AM, Corsini G, Garland MT, Baggio R, 2011. Poly[4,4′-(propane-1,3-diyl)dipyridiniumbis{tetraaquabis(μ2-5-carboxybenzene-1,2,4-tricarboxylato)bis[μ2-1,3-bis(4-pyridyl)propane]dicobalt(II)}pentahydrate]. Acta Crystallographica Section C Structural Chemistry, 67: m367–m370.
  • Clark RC, Reid JS, 1995. The analytical calculation of absorption in multifaceted crystals. Acta Crystallographica Section A Foundations and Advances, 51: 887–897.
  • Coban MB, 2017. Synthesis and photophysical properties of new Eu(III) complex. Balıkesir Üniversitesi Fen Bilimleri Enstitüsü Dergisi, 19: 7–15.
  • Coban MB, Amjad A, Aygun M, Kara H, 2017. Sensitization of Ho(III) and Sm(III) luminescence by efficient energy transfer from antenna ligands: Magnetic, visible and NIR photoluminescence properties of Gd(III), Ho(III) and Sm(III) coordination polymers. Inorganica Chimia Acta, 455: 25–33.
  • Coban MB, 2018. Hydrothermal synthesis, crystal structure, luminescent and magnetic properties of a new mononuclear Gd(III) coordination complex. Journal of Molecular Structure, 1162: 109–116.
  • Coban MB, Gungor E, Kara H, Baisch U, Acar Y, 2018. New mixed valence defect dicubane cobalt(II)/cobalt(III) complex: Synthesis, crystal structure, photoluminescence and magnetic properties. Journal of Molecular Structure, 1154: 579–586.
  • Coban MB, 2019. Magnetic and photophysical properties of new TbIII – based twodimensional hydrogen-bonded polymer. Journal of Molecular Structure, 1177: 331–337.
  • Dai Y-M, Shen H-Y, Huang J-F, 2005. Terephthalic acid–1,3-di-4-pyridylpropane (1/1). Acta Crystallographica Section E Crystallographica Communications, 61: o3410–o3411.
  • Dolomanov OV, Bourhis LJ, Gildea RJ, Howard JAK, Puschmann H, 2009. OLEX2 : a complete structure solution, refinement and analysis program. Journal of Applied Crystallography, 42: 339–341.
  • Erkarslan U, Donmez A, Kara H, Aygun M, Coban MB, 2018. Synthesis, structure and photoluminescence performance of a new Er3+-cluster-based 2D coordination polymer. Journal of Cluster Science, 29: 1177–1183.
  • Hu Z, Li B, Ju W, Liang Y, Chen Z, 2016. Synthesis and structures of two new Cu(I) frameworks bearing1,3-bis(4-pyridyl)propane and inorganic linkers. Journal of Chemical Science, 128: 893–898.
  • Kara H, 2018. Synthesis and 3D crystal structure of new Ni(II)-ion-pair complex. Balıkesir Üniversitesi Fen Bilimleri Enstitüsü Dergisi, 20: 1–7.
  • Kocak C, Oylumluoglu G, Donmez A, Coban MB, Erkarslan U, Aygun M, Kara H, 2017. Crystal structure and photoluminescence properties of a new monomeric copper(II) complex: bis(3-{[(3-hydroxypropyl)imino]methyl}-4-nitrophenolato-κ3O,N,O')copper(II). Acta Crystallographica Section C Structural Chemistry, 73: 414–419.
  • Li H-H, Li H, Niu Z, Wang Y-P, 2015. Structural diversity of two novel Dy(III) metal-organic frameworks based on binuclear nodes with furan-2,5-dicarboxylic acid: Crystal structures and luminescent properties. Inorganic Chemistry Communications, 55: 103–107.
  • Oylumluoğlu G, 2018. 4,4- bipiridin ve 2-amino-1,4-benzendikarboksilik asit tabanlı yeni bilesigin sentezlenmesi ve hidrojen baglı 3D polimerik yapısı. Balıkesir Üniversitesi Fen Bilimleri Enstitüsü Dergisi, 20: 320–326.
  • Ren Y, Chai H, Tang L, Hou X, Wang J, 2016. Structural diversity and fluorescence properties of three 2-sulfoterephthalate Cd(II)/Zn(II) coordination polymers employing 1,4-bisbenzimidazole. Journal of Solid State Chemistry, 234: 103–109.
  • Sheldrick GM, 2015a. Crystal structure refinement with SHELXL. Acta Crystallographica Section C Structural Chemistry, 71: 3–8.
  • Sheldrick GM, 2015b. SHELXT – Integrated space-group and crystal-structure determination. Acta Crystallographica Section A Foundations and Advances, 71: 3–8.
  • Shen H-Y, Wang W-M, Gao H-L, Cui J-Z, 2016. Near-infrared luminescence and SMM behaviors of a family of dinuclear lanthanide 8-quinolinolate complexes. Royal Society of Chemistry Advances, 6: 34165–34174.
  • Spek AL, 2009. Structure validation in chemical crystallography. Acta Crystallographica Section D Structural Biology, 65: 148–155.
  • Sun Y-Y, Dong H-Z, Cheng L, 2008. 1,3-Bis[4-(4-pyridyl)pyrimidin-2-ylsulfanyl]propane. Acta Crystallographica Section E Crystallographica Communications, 64: o901–o901.
  • Yang E, Song X-C, Zhuang R-Q, 2008. 4,4′-(Propane-1,3-diyl)dipiperidinium sulfate monohydrate. Acta Crystallographica Section E Crystallographica Communications, 64: o1763–o1763.
  • Zhang J-Y, Shi J-X, Chen L-Y, Jia Q-X, Deng W, Gao E-Q, 2017. N-donor auxiliary ligand-directed assembly of Co(II) compounds with a 2,2′-dinitro-biphenyl-4,4′-dicarboxylate ligand: structures and magnetic properties. Crystal Engineering Communications, 19: 1738–1750.
  • Zhou RS, Shao J, Li Y, Song JF, 2017. Three new imidazole dicarboxylate metal compounds: Synthesis, structures, and magnetic property. Inorganic Nano-Metal Chemistry, 47: 509–514.
Toplam 24 adet kaynakça vardır.

Ayrıntılar

Birincil Dil Türkçe
Konular Metroloji,Uygulamalı ve Endüstriyel Fizik
Bölüm Fizik / Physics
Yazarlar

Mustafa Burak Çoban 0000-0003-3488-5284

Yayımlanma Tarihi 1 Mart 2020
Gönderilme Tarihi 13 Eylül 2019
Kabul Tarihi 10 Ekim 2019
Yayımlandığı Sayı Yıl 2020 Cilt: 10 Sayı: 1

Kaynak Göster

APA Çoban, M. B. (2020). Fenol-4-Sülfonik Asit ve 1,3-Bis(4-Piridil)Propan Tabanlı Yeni Organik Bileşiğin Hidrotermal Sentezi ve Karakterizasyonu. Journal of the Institute of Science and Technology, 10(1), 163-170. https://doi.org/10.21597/jist.620043
AMA Çoban MB. Fenol-4-Sülfonik Asit ve 1,3-Bis(4-Piridil)Propan Tabanlı Yeni Organik Bileşiğin Hidrotermal Sentezi ve Karakterizasyonu. Iğdır Üniv. Fen Bil Enst. Der. Mart 2020;10(1):163-170. doi:10.21597/jist.620043
Chicago Çoban, Mustafa Burak. “Fenol-4-Sülfonik Asit Ve 1,3-Bis(4-Piridil)Propan Tabanlı Yeni Organik Bileşiğin Hidrotermal Sentezi Ve Karakterizasyonu”. Journal of the Institute of Science and Technology 10, sy. 1 (Mart 2020): 163-70. https://doi.org/10.21597/jist.620043.
EndNote Çoban MB (01 Mart 2020) Fenol-4-Sülfonik Asit ve 1,3-Bis(4-Piridil)Propan Tabanlı Yeni Organik Bileşiğin Hidrotermal Sentezi ve Karakterizasyonu. Journal of the Institute of Science and Technology 10 1 163–170.
IEEE M. B. Çoban, “Fenol-4-Sülfonik Asit ve 1,3-Bis(4-Piridil)Propan Tabanlı Yeni Organik Bileşiğin Hidrotermal Sentezi ve Karakterizasyonu”, Iğdır Üniv. Fen Bil Enst. Der., c. 10, sy. 1, ss. 163–170, 2020, doi: 10.21597/jist.620043.
ISNAD Çoban, Mustafa Burak. “Fenol-4-Sülfonik Asit Ve 1,3-Bis(4-Piridil)Propan Tabanlı Yeni Organik Bileşiğin Hidrotermal Sentezi Ve Karakterizasyonu”. Journal of the Institute of Science and Technology 10/1 (Mart 2020), 163-170. https://doi.org/10.21597/jist.620043.
JAMA Çoban MB. Fenol-4-Sülfonik Asit ve 1,3-Bis(4-Piridil)Propan Tabanlı Yeni Organik Bileşiğin Hidrotermal Sentezi ve Karakterizasyonu. Iğdır Üniv. Fen Bil Enst. Der. 2020;10:163–170.
MLA Çoban, Mustafa Burak. “Fenol-4-Sülfonik Asit Ve 1,3-Bis(4-Piridil)Propan Tabanlı Yeni Organik Bileşiğin Hidrotermal Sentezi Ve Karakterizasyonu”. Journal of the Institute of Science and Technology, c. 10, sy. 1, 2020, ss. 163-70, doi:10.21597/jist.620043.
Vancouver Çoban MB. Fenol-4-Sülfonik Asit ve 1,3-Bis(4-Piridil)Propan Tabanlı Yeni Organik Bileşiğin Hidrotermal Sentezi ve Karakterizasyonu. Iğdır Üniv. Fen Bil Enst. Der. 2020;10(1):163-70.