Synthesis, Characterization and Thermal Studies of New Carboxamide Ligand and Co(II), Ni(II), Cu(II) and Fe(II) Metal Complexes Containing Sulfonamide Group

Yıl 2022, Cilt: 12 Sayı: 3, 1723 - 1733, 01.09.2022

Rabia Büyükkonuk Özkılıç , Hatice Gamze Soğukömeroğulları , Mehmet Sönmez

https://doi.org/10.21597/jist.1109589

Cited By: 1

Öz

The new N-carboxamide ligand 2-benzoyl-N-(4-(aminosulfonyl)phenyl)-3-oxo-3-phenylpropanamide (HL) was synthesized from the reaction of dibenzoylacetic acid-Ncarboxyethylamide and sulfonylamide. Then, metal complexes were synthesized from the reaction of
ligand with Cu(OAc)2·H2O, Co(OAc)2·4H2O, Ni(OAc)2·4H2O and Fe(OAc)2 metal salts in a 1:2 metal:ligand cytochiometric ratio, respectively. The synthesized carboxamide ligand and its metal complexes were characterized by various techniques such as UV-Vis, FT-IR, NMR, elemental analysis, TGA-DTA.

Anahtar Kelimeler

Metal complex, N-Carboxamide ligand, Characterization, Thermal Studies

Sülfonamit Grubu İçeren Yeni Karboksamit Ligandı ve Co(II), Ni(II), Cu(II) ve Fe(II) Metal Komplekslerinin Sentezi, Karakterizasyonu ve Termal Çalışmaları

Öz

Yeni N-karboksamit ligandı 2-benzoil-N-(4-(aminosülfonil)fenil)-3-okso-3-fenilpropanamit
(HL), dibenzoilasetik asit-N-karboksietilamit ve sülfonilamitin reaksiyonundan sentezlendi. Daha
sonra ligandın sırasıyla Cu(OAc)2·H2O, Co(OAc)2·4H2O, Ni(OAc)2·4H2O ve Fe(OAc)2 metal tuzları ile 1:2 metal:ligand sitokiyometrik oranında reaksiyonundan metal kompleksleri sentezlendi. Sentezlenen karboksamid ligandı ve metal kompleksleri, UV-Vis, FT-IR, NMR, elementel analiz, TGA-DTA gibi çeşitli tekniklerle karakterize edildi.

Anahtar Kelimeler

Metal kompleks, N-Karboksamit ligand, Karakterizasyon, Termal Çalışmalar

Kaynakça

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