Beyaz Şapkalı Mantardan (Agaricus Bisporus) Üretilen Aktif Karbon Kullanılarak Sulu Çözeltilerinden Adsorpsiyon ile Metilen Violet Giderimi

Yıl 2022, Cilt: 12 Sayı: 3, 1413 - 1425, 01.09.2022

Özkan Aydın Ahmet F. Karabulut

https://doi.org/10.21597/jist.1144365

Öz

Bu çalışmada beyaz şapkalı kültür mantarından (Agaricus bisporus) üretilen aktif karbonun (AC), atık suların ıslahındaki potansiyelini ortaya koymak amacıyla metilen violet 2B (MV 2B) giderimindeki adsorpsiyon performansı incelenmiştir. Aktifleştirme prosesi, potasyum hidroksit (KOH) varlığında kimyasal aktivasyon yöntemi kullanılarak, tüp fırında azot atmosferinde gerçekleştirilmiştir. Adsorpsiyon olayını önemli ölçüde etkileyen pH, sıcaklık, başlangıç MV 2B çözelti konsantrasyonu ve adsorban miktarı parametreleri incelenmiştir. Deney sonuçlarından elde edilen veriler kullanılarak termodinamik, izoterm ve kinetik analizler yapılmıştır. Elde edilen pozitif entalpi (ΔH⁰) (30.658 kJ mol-1) değerinden işlemin endotermik olduğu ve negatif Gibbs serbestlik enerjisi (ΔG⁰) değerlerinden fiziksel bir adsorpsiyon işlemi meydana geldiği anlaşılmaktadır. Adsorpsiyon işlemi izoterm analizlerine göre Langmuir izoterm modeline (R2 = 0.98989) daha uygun olduğu, kinetik analize göre ise yalancı ikinci mertebe reaksiyon ile kontrol edildiği belirlenmiştir. Elde edilen AC’nin maksimum adsorpsiyon kapasitesinin 303.030 mg g-1 ve Brunauer–Emmett–Teller (BET) yöntemi ile yüzey alanının 1741.690 m2 g-1 olduğu belirlenmiştir.

Anahtar Kelimeler

Adsorpsiyon, aktif karbon, beyaz şapkalı mantar, metilen violet 2B, kinetik analiz izotermleri

Destekleyen Kurum

Osmaniye Korkut Ata Üniversitesi ve Atatürk Üniversitesi

Proje Numarası

yok

Teşekkür

Bu çalışmada Osmaniye Korkut Ata Üniversitesi ve Atatürk Üniversitesi’ne teşekkür ederiz.

Methylene Violet Removal by Adsorption from Aqueous Solutions Using Activated Carbon Produced from White Cap Mushroom (Agaricus Bisporus)

Öz

In this study, the adsorption performance of activated carbon (AC) produced from the white cap mushroom (Agaricus bisporus) in methylene violet 2B (MV 2B) removal was investigated in order to reveal its potential in wastewater treatment. The activation process was carried out in a nitrogen atmosphere in a tubular furnace using the chemical activation method in the presence of potassium hydroxide (KOH). The parameters of pH, temperature, initial MV 2B solution concentration and amount of adsorbent, which significantly affect the adsorption process, were investigated. Thermodynamic, isotherm and kinetic analyzes were carried out using the data obtained from the experimental results. It is understood that obtained positive value of entalpy (ΔH⁰) (30.658 kJ mol-1) indicates that the process is endothermic and the numerical value of Gibbs free energy (ΔG⁰) indicates that a physical adsorption process has taken place. It was determined that the adsorption process was more suitable for Langmuir isotherm model (R2 = 0.98989) according to isotherm analysis, and it was controlled by pseudo-second-order reaction according to kinetic analysis.The maximum adsorption capacity of the obtained AC was determined as 303.030 mg g-1 and the surface area was determined as 1741.690 m2 g-1 by Brunauer–Emmett–Teller (BET) method.

Anahtar Kelimeler

Adsorption, activated carbon, white cap mushroom, methylene violet 2B, kinetic analysis isotherms

Proje Numarası

yok

Kaynakça

• Abbas SH, Kamar F ,Hossien Y, 2018. Adsorption of methyl violet 2B dye from aqueous solutions onto waste of Banana peel using fixed-bed column. International Journal of Civil Engineering and Technology, 9: 2094.
• Adeogun AI, Ofudje EA, Idowu MA, Kareem SO, Vahidhabanu S ,Babu BR, 2018. Biowaste-derived hydroxyapatite for effective removal of reactive yellow 4 dye: equilibrium, kinetic, and thermodynamic studies. ACS omega, 3(2): 1991-2000.
• Ahmad M, Lee SS, Dou X, Mohan D, Sung J-K, Yang JE ,Ok YS, 2012. Effects of pyrolysis temperature on soybean stover- and peanut shell-derived biochar properties and TCE adsorption in water. Bioresource Technology, 118: 536-544.
• Al-Tohamy R, Ali SS, Li F, Okasha KM, Mahmoud YA-G, Elsamahy T, Jiao H, Fu Y ,Sun J, 2022. A critical review on the treatment of dye-containing wastewater: Ecotoxicological and health concerns of textile dyes and possible remediation approaches for environmental safety. Ecotoxicology and Environmental Safety, 231: 113160.
• Al-Zaban MI, Alharbi NK, Albarakaty FM, Alharthi S, Hassan SH ,Fawzy MA, 2022. Experimental Modeling Investigations on the Biosorption of Methyl Violet 2B Dye by the Brown Seaweed Cystoseira tamariscifolia. Sustainability, 14(9): 5285.
• Alfatah T, Mistar EM ,Supardan MD, 2021. Porous structure and adsorptive properties of activated carbon derived from Bambusa vulgaris striata by two-stage KOH/NaOH mixture activation for Hg2+ removal. Journal of Water Process Engineering, 43: 102294.
• Bhowmik K, Debnath A, Nath R, Das S, Chattopadhyay K ,Saha B, 2016. Synthesis and characterization of mixed phase manganese ferrite and hausmannite magnetic nanoparticle as potential adsorbent for methyl orange from aqueous media: artificial neural network modeling. Journal of Molecular Liquids, 219: 1010-1022.
• Dada A, Olalekan A, Olatunya A ,Dada O, 2012. Langmuir, Freundlich, Temkin and Dubinin–Radushkevich isotherms studies of equilibrium sorption of Zn2+ unto phosphoric acid modified rice husk. IOSR Journal of Applied Chemistry, 3(1): 38-45.
• Desa SS, Ishii T ,Nueangnoraj K, 2021. Sulfur-Doped Carbons from Durian Peels, Their Surface Characteristics, and Electrochemical Behaviors. ACS omega, 6(38): 24902-24909.
• Foroutan R, Mohammadi R, Ahmadi A, Bikhabar G, Babaei F ,Ramavandi B, 2022. Impact of ZnO and Fe3O4 magnetic nanoscale on the methyl violet 2B removal efficiency of the activated carbon oak wood. Chemosphere, 286: 131632.
• Gunay Gurer A, Aktas K, Ozkaleli Akcetin M, Erdem Unsar A ,Asilturk M, 2021. Adsorption isotherms, thermodynamics, and kinetic modeling of methylene blue onto novel carbonaceous adsorbent derived from bitter orange peels. Water, Air, & Soil Pollution, 232(4): 1-17.
• Heidarinejad Z, Dehghani MH, Heidari M, Javedan G, Ali I ,Sillanpää M, 2020. Methods for preparation and activation of activated carbon: a review. Environmental Chemistry Letters, 18(2): 393-415.
• Hou H, Zhou R, Wu P ,Wu L, 2012. Removal of Congo red dye from aqueous solution with hydroxyapatite/chitosan composite. Chemical Engineering Journal, 211: 336-342.
• Hu S-C, Cheng J, Wang W-P, Sun G-T, Hu L-L, Zhu M-Q ,Huang X-H, 2021. Structural changes and electrochemical properties of lacquer wood activated carbon prepared by phosphoric acid-chemical activation for supercapacitor applications. Renewable Energy, 177: 82-94.
• Imam S, Muhammad AI, Babamale HF ,Zango ZU, 2021. Removal of Orange G Dye from Aqueous Solution by Adsorption: A Short Review. Journal of Environmental Treatment Techniques, 9(1): 318-327.
• Jawad AH, Abdulhameed AS, Wilson LD, Syed-Hassan SSA, ALOthman ZA ,Khan MR, 2021. High surface area and mesoporous activated carbon from KOH-activated dragon fruit peels for methylene blue dye adsorption: Optimization and mechanism study. Chinese Journal of Chemical Engineering, 32: 281-290.
• Karaçetin G, Sivrikaya S ,Imamoğlu M, 2014. Adsorption of methylene blue from aqueous solutions by activated carbon prepared from hazelnut husk using zinc chloride. Journal of Analytical and Applied Pyrolysis, 110: 270-276.
• Kenawy E-R, Ghfar AA, Wabaidur SM, Khan MA, Siddiqui MR, Alothman ZA, Alqadami AA ,Hamid M, 2018. Cetyltrimethylammonium bromide intercalated and branched polyhydroxystyrene functionalized montmorillonite clay to sequester cationic dyes. Journal of Environmental Management, 219: 285-293.
• Kermani M, Izanloo H, Kalantary RR, Barzaki HS ,Kakavandi B, 2017. Study of the performances of low-cost adsorbents extracted from Rosa damascena in aqueous solutions decolorization. Desalination and Water Treatment, 80: 357-369.
• Kooh MRR, Dahri MK ,Lim LB, 2017. Removal of the methyl violet 2B dye from aqueous solution using sustainable adsorbent Artocarpus odoratissimus stem axis. Applied Water Science, 7(7): 3573-3581.
• Kooh MRR, Dahri MK ,Lim LBL, 2017. Removal of methyl violet 2B dye from aqueous solution using Nepenthes rafflesiana pitcher and leaves. Applied Water Science, 7(7): 3859-3868.
• Lazarotto JS, da Boit Martinello K, Georgin J, Franco DS, Netto MS, Piccilli DG, Silva LF, Lima EC ,Dotto GL, 2021. Preparation of activated carbon from the residues of the mushroom (Agaricus bisporus) production chain for the adsorption of the 2, 4-dichlorophenoxyacetic herbicide. Journal of Environmental Chemical Engineering, 9(6): 106843.
• Liadi MA, Mu’azu ND, Jarrah N, Zubair M, Alagha O, Al-Harthi MA ,Essa MH, 2021. Comparative performance study of ZnCl2 and NaOH sludge based activated carbon for simultaneous aqueous uptake of phenolic compounds. International Journal of Environmental Analytical Chemistry, 101(14): 2428-2452.
• Liang Y, Huang G, Zhang Q, Yang Y, Zhou J ,Cai J, 2021. Hierarchical porous carbons from biowaste: Hydrothermal carbonization and high-performance for Rhodamine B adsorptive removal. Journal of Molecular Liquids, 330: 115580.
• Massoudinejad M, Asadi A, Vosoughi M, Gholami M ,Karami MA, 2015. A comprehensive study (kinetic, thermodynamic and equilibrium) of arsenic (V) adsorption using KMnO4 modified clinoptilolite. Korean journal of chemical engineering, 32(10): 2078-2086.
• Meenatchi T, Priyanka V, Subadevi R, Liu W-R, Huang C-H ,Sivakumar M, 2021. Probe on hard carbon electrode derived from orange peel for energy storage application. Carbon letters, 31(5): 1033-1039.
• Al zaban H, Saffari J, Mohammadi S ,Shojaei S, 2020. The removal of methyl violet 2B dye using palm kernel activated carbon: thermodynamic and kinetics model. International Journal of Environmental Science and Technology, 17(3): 1773-1782.
• Oginni O, Singh K, Oporto G, Dawson-Andoh B, McDonald L ,Sabolsky E, 2019. Effect of one-step and two-step H3PO4 activation on activated carbon characteristics. Bioresource Technology Reports, 8: 100307.
• Peng L, Qin P, Lei M, Zeng Q, Song H, Yang J, Shao J, Liao B ,Gu J, 2012. Modifying Fe3O4 nanoparticles with humic acid for removal of Rhodamine B in water. Journal of Hazardous Materials, 209: 193-198.
• Reffas A, Bouguettoucha A, Chebli D ,Amrane A, 2016. Adsorption of ethyl violet dye in aqueous solution by forest wastes, wild carob. Desalination and Water Treatment, 57(21): 9859-9870.
• Sharma K, Sharma S, Sharma V, Mishra PK, Ekielski A, Sharma V ,Kumar V, 2021. Methylene blue dye adsorption from wastewater using hydroxyapatite/gold nanocomposite: Kinetic and thermodynamics studies. Nanomaterials, 11(6): 1403.
• Thongpat W, Taweekun J ,Maliwan K, 2021. Synthesis and characterization of microporous activated carbon from rubberwood by chemical activation with KOH. Carbon letters, 31(5): 1079-1088.
• Witkowska D, Słowik J ,Chilicka K, 2021. Heavy metals and human health: Possible exposure pathways and the competition for protein binding sites. Molecules, 26(19): 6060.
• Xiong X-J, Meng X-J ,Zheng T-L, 2010. Biosorption of CI Direct Blue 199 from aqueous solution by nonviable Aspergillus niger. Journal of Hazardous Materials, 175(1-3): 241-246.