Beyaz Şapkalı Mantardan (Agaricus Bisporus) Üretilen Aktif Karbon Kullanılarak Sulu Çözeltilerinden Adsorpsiyon ile Metilen Violet Giderimi

Yıl 2022, Cilt: 12 Sayı: 3, 1413 - 1425, 01.09.2022

Özkan Aydın , Ahmet F. Karabulut

https://doi.org/10.21597/jist.1144365

Öz

Bu çalışmada beyaz şapkalı kültür mantarından (Agaricus bisporus) üretilen aktif karbonun (AC), atık suların ıslahındaki potansiyelini ortaya koymak amacıyla metilen violet 2B (MV 2B) giderimindeki adsorpsiyon performansı incelenmiştir. Aktifleştirme prosesi, potasyum hidroksit (KOH) varlığında kimyasal aktivasyon yöntemi kullanılarak, tüp fırında azot atmosferinde gerçekleştirilmiştir. Adsorpsiyon olayını önemli ölçüde etkileyen pH, sıcaklık, başlangıç MV 2B çözelti konsantrasyonu ve adsorban miktarı parametreleri incelenmiştir. Deney sonuçlarından elde edilen veriler kullanılarak termodinamik, izoterm ve kinetik analizler yapılmıştır. Elde edilen pozitif entalpi (ΔH⁰) (30.658 kJ mol-1) değerinden işlemin endotermik olduğu ve negatif Gibbs serbestlik enerjisi (ΔG⁰) değerlerinden fiziksel bir adsorpsiyon işlemi meydana geldiği anlaşılmaktadır. Adsorpsiyon işlemi izoterm analizlerine göre Langmuir izoterm modeline (R2 = 0.98989) daha uygun olduğu, kinetik analize göre ise yalancı ikinci mertebe reaksiyon ile kontrol edildiği belirlenmiştir. Elde edilen AC’nin maksimum adsorpsiyon kapasitesinin 303.030 mg g-1 ve Brunauer–Emmett–Teller (BET) yöntemi ile yüzey alanının 1741.690 m2 g-1 olduğu belirlenmiştir.

Anahtar Kelimeler

Adsorpsiyon, aktif karbon, beyaz şapkalı mantar, metilen violet 2B, kinetik analiz izotermleri

Destekleyen Kurum

Osmaniye Korkut Ata Üniversitesi ve Atatürk Üniversitesi

Proje Numarası

yok

Teşekkür

Bu çalışmada Osmaniye Korkut Ata Üniversitesi ve Atatürk Üniversitesi’ne teşekkür ederiz.

Methylene Violet Removal by Adsorption from Aqueous Solutions Using Activated Carbon Produced from White Cap Mushroom (Agaricus Bisporus)

Öz

In this study, the adsorption performance of activated carbon (AC) produced from the white cap mushroom (Agaricus bisporus) in methylene violet 2B (MV 2B) removal was investigated in order to reveal its potential in wastewater treatment. The activation process was carried out in a nitrogen atmosphere in a tubular furnace using the chemical activation method in the presence of potassium hydroxide (KOH). The parameters of pH, temperature, initial MV 2B solution concentration and amount of adsorbent, which significantly affect the adsorption process, were investigated. Thermodynamic, isotherm and kinetic analyzes were carried out using the data obtained from the experimental results. It is understood that obtained positive value of entalpy (ΔH⁰) (30.658 kJ mol-1) indicates that the process is endothermic and the numerical value of Gibbs free energy (ΔG⁰) indicates that a physical adsorption process has taken place. It was determined that the adsorption process was more suitable for Langmuir isotherm model (R2 = 0.98989) according to isotherm analysis, and it was controlled by pseudo-second-order reaction according to kinetic analysis.The maximum adsorption capacity of the obtained AC was determined as 303.030 mg g-1 and the surface area was determined as 1741.690 m2 g-1 by Brunauer–Emmett–Teller (BET) method.

Anahtar Kelimeler

Adsorption, activated carbon, white cap mushroom, methylene violet 2B, kinetic analysis isotherms

Proje Numarası

yok

Kaynakça

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