Cu (II) ADSORPTION WITH ACTIVATED CARBON OBTAINED FROM SEA URCHIN PREPARED BY ULTRASOUND-ASSISTED METHOD

Öz

In this study, activated carbon has been obtained by using sea urchin as an adsorbent substance, which is abundant, cheap, and natural in nature, as an alternative to active carbon used in heavy metal removal. Using the Ultrasound-assisted support, 1:1, 2:1, 3:1 (H3PO4/sea urchin) carbonization process was carried out by subjecting H3PO4 as the sea urchin activating agent. The BET surface area of the activated carbon obtained was characterized by total pore volume, ash content, and SEM analysis. Cu (II) removal in aqueous solutions were investigated with activated carbons. Experimental studies have been conducted to determine the effects of pH, contact time (min), adsorbent concentration (g/L), temperature, and initial metal concentration parameters affecting adsorption. The adsorption capacity of the activated carbon obtained from the sea urchin at 25 °C was calculated as 643 mg/g. Optimum conditions from the results were determined as pH 2.0, contact time 80 minutes, initial adsorbent concentration 10 mg/L, and temperature 25 °C. According to the results of the study, it has been concluded that the activated carbon obtained from the sea urchin can be an alternative adsorbent to other activated carbons in heavy metal removal.

Anahtar Kelimeler

• Ultrasound-assisted
• Copper (II)
• Sea urchin
• Activated carbon
• Adsorption

ULTRASES YÖNTEMİ İLE HAZIRLANAN DENİZ KESTANESİNDEN ELDE EDİLEN AKTİF KARBON İLE Cu (II) ADSORPSİYONU

Öz

Bu çalışmada, ağır metal gideriminde kullanılan aktif karbonlara farklı seçenek olarak doğada bol, ucuz ve doğal olarak bulunan adsorbent bir madde olarak deniz kestanesi kullanılarak aktif karbon elde edilmiştir. Ultrason desteği kullanılarak deniz kestanesi aktifleştirma maddesi olarak H3PO4 ‘ün kullanıldığı karbonizasyona tabi tutularak 1:1, 2:1, 3:1 (H3PO4 /deniz kestanesi) karbonizasyon işlemi gerçekleştirilmiştir. Elde edilen aktif karbonun BET yüzey alanı, toplam gözenek hacmi, kül içeriği ve SEM analizleriyle karakterize edilmiştir. Aktif karbonlar ile sulu çözeltilerdeki Cu (II) giderimi araştırılmıştır. Adsorpsiyonu etkileyen pH, temas süresi (dk), adsorbent konsantrasyonu (g/L), sıcaklık ve başlangıç metal konsantrasyonu parametrelerinin etkilerini belirlemek için deneysel çalışmalar yapılmıştır. Deniz kestanesinden elde edilen aktif karbonun 25 °C’de Cu (II) adsorplama kapasitesi 643 mg/g olarak hesaplanmıştır. Elde edilen sonuçlardan optimum koşullar pH 2.0, temas süresi 80 dakika, başlangıç adsorbent madde konsantrasyonu 10 mg/L ve sıcaklık 25 °C olarak belirlenmiştir. Çalışmanın sonuçlarına göre, deniz kestanesinden elde edilen aktif karbonun ağır metal gideriminde diğer aktif karbonlara alternatif bir adsorbent olabileceği sonucu elde edilmiştir.

Anahtar Kelimeler

• Ultrason destekli
• Bakır (II)
• Deniz kestanesi
• Aktif karbon
• Adsorpsiyon

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