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Demirin asidik korozyonunu değerlendirmede Pyracantha coccinea (Rosaceae) meyvelerinin yeşil inhibisyon etkisi

Yıl 2024, Cilt: 13 Sayı: 4, 1291 - 1297, 15.10.2024
https://doi.org/10.28948/ngumuh.1527976

Öz

Bu çalışmanın amacı, Pyracantha coccinea meyvelerinin ekstrakt çözeltisinin ortam koşullarında bulunan demir elektrot üzerinde çevre dostu ve sürdürülebilir bir korozyon inhibitörü olarak potansiyelini araştırmaktır. Bu yeşil inhibitörün etkisi, potansiyodinamik polarizasyon ve elektrokimyasal impedans spektroskopisi (EIS) gibi farklı elektrokimyasal teknikler kullanılarak incelenmiştir. P. coccinea meyve ekstraktının üç farklı derişimleriyle yapılan deneylerin bir saatlik incelenmesinin ardından, meyve ekstraktının 1,0 M HCl çözeltisindeki demir elektrot üzerinde güçlü bir inhibisyon sergilediği belirlenmiştir. P. coccinea meyvelerinden elde edilen ekstrakt, güçlü bir inhibitör etki gösterdi ve pirakanta ekstraktı derişimindeki artışla birlikte, demir elektrotların HCl çözeltilerindeki koruyucu etkisi de artmıştır. Son olarak, P. coccinea meyve ekstraktı içeren ve içermeyen agresif HCl elektrolitindeki demir elektrotlarının yüzey morfolojilerini analiz etmek için alan emisyon taramalı elektron mikroskobu (FE-SEM) kullanılarak bir saatlik daldırma sonrasında yüzey görüntüleri alınmış ve P. coccinea ekstresi içeren yüzeyin boş olandan daha pürüzsüz olduğu sonucuna varılmıştır.

Kaynakça

  • B. Tan, Y. Liu, Z. Gong, X. Zhang, J. Chen, L. Guo, J. Xiong, J. Liu, R. Marzouki and W. Li, Pyracantha fortuneana alcohol extracts as biodegradable corrosion inhibitors for copper in H2SO4 media, Journal of Molecular Liquids, 397, 124117, 2024. https://doi.org/10.1016/j.molliq.2024.124117.
  • A. Abd-ElHamid, W. El-dougdoug, S. M. Syam, I. Aiad, S. M. Shaban and D. -H. Kim, Synthesis of gemini cationic surfactants-based pyridine Schiff base for steel corrosion and sulfate reducing bacteria mitigation, Journal of Molecular Liquids, 369, 120890, 2023. https://doi.org/10.1016/j.molliq.2022.120890.
  • H. Karima, B. Sameh, B. Baya, B. Louiza, H. Soraya, B. Hatem and B. Merzoug, Corrosion inhibition impact of Pyracantha coccinea M. Roem extracts and their use as additives in zinc electroplating: Coating morphology, electrochemical and weight loss investigations, Journal of the Taiwan Institute of Chemical Engineers, 121, 337-348, 2021. https://doi.org/10.1016/j.jtice.2021.04.007.
  • K. Dahmani, M. Galai, M. Ouakki, A. Elgendy, R. Ez-Zriouli, R. Lachhab, S. Briche and M. Cherkaoui, Corrosion inhibition of copper in sulfuric acid via environmentally friendly inhibitor (Myrtus Communis): Combining experimental and theoretical methods, Journal of Molecular Liquids, 347, 117982, 2022. https://doi.org/10.1016/j.molliq.2021.117982.
  • S. Wan, H. Wei, R. Quan, Z. Luo, H. Wang, B. Liao and X. Guo, Soybean extract firstly used as a green corrosion inhibitor with high efficacy and yield for carbon steel in acidic medium, Industrial Crops and Products, 187, 115354, 2022. https://doi.org/10.1016/j.indcrop.2022.115354.
  • H. E. Aadad, M. Galai, M. Ouakki, A. Elgendy, M. E. Touhami and A. Chahine, Improvement of the corrosion resistance of mild steel in sulfuric acid by new organic-inorganic hybrids of Benzimidazole-Pyrophosphate: Facile synthesis, characterization, experimental and theoretical calculations (DFT and MC), Surfaces and Interfaces, 24, 101084, 2021. https://doi.org/10.1016/j.surfin.2021.101084.
  • D. Özkır, The role of Lavandula sp. extract for effective inhibiting the mild steel corrosion in the hydrochloric acid solution, International Journal of Chemistry and Technology, 5(2), 125–132, 2021. https://dx.doi.org/10.32571/ijct.943385.
  • D. Özkır, The green inhibitive effect of Ptychostomum schleicheri (Bryophyta) extract on mild steel corrosion, Anatolian Bryology, 8(2), 114–122, 2022. https://doi.org/10.26672/anatolianbryology.1193546.
  • G. S. Sajadi, F. Salmanian, R. Naghizade and S. M. A. Hosseini, The inhibitive action of lemon verbena plant extract as an economical and eco-friendly corrosion inhibitor for mild steel in acidic solutions, International Journal of Electrochemical Science, 19, 100699, 2024. https://doi.org/10.1016/j.ijoes.2024.100699.
  • G. D. Pai, M. R. Rathod, S. K. Rajappa and A. A. Kittur, Effect of tabebuia heterophylla plant leaves extract on corrosion protection of low carbon steel in 1M HCl medium: Electrochemical, quantum chemical and surface characterization studies, Results in Surfaces and Interfaces, 15, 100203, 2024. https://doi.org/10.1016/j.rsurfi.2024.100203.
  • M. T. Muhammad, M. H. Hussin, M. H. Abu Bakar, T. S. Hamidon, S. S. Azahar, K. Awang, M. Litaudon and M. N. Azmi, Corrosion inhibitive performance of Kopsia teoi extracts towards mild steel in 0.5 M HCl solution, Materials Chemistry and Physics, 322, 129584, 2024. https://doi.org/10.1016/j.matchemphys.2024.129584.
  • D. Özkır, Insight into anti-corrosion effect of Mammillaria prolifera fruit extract as a green inhibitor for mild steel in HCl solution, Eurasian Journal of Science Engineering and Technology, 4(2), 071-077, 2023. https://doi.org/10.55696/ejset.1387199.
  • D. Özkır, Oleaster leaf extract: a potential environmentally friendly inhibitor for mild steel, Eurasian Journal of Biological and Chemical Science, 7(1), 20-25, 2024. https://doi.org/10.46239/ejbcs.1425801.
  • A. R. Bilia, I. Morelli and A. Marsili, Two glicosides from Pyracantha coccinea roots: a new lignan and a new chalcone, Tetrahedron, 50, 5181-5188, 1994. https://doi.org/10.1016/S0040-4020(01)90428-4.
  • G. Fico, A. R. Bilia, I. Morelli and F. Tomè, Flavonoid distribution in Pyracantha coccinea plants at different growth phases, Biochemical Systematics and Ecology, 28, 673-678, 2000. https://doi.org/10.1016/S0305-1978(99)00109-X.
  • Y. Wu, Z. Gong, L. Guo and A. A. AlObaid, Batatas lam leaf extract as a biodegradable corrosion inhibitor for copper in 0.5 M H2SO4 solution, Sustainable Chemistry and Pharmacy, 39, 101601, 2024. https://doi.org/10.1016/j.scp.2024.101601.
  • M. Rehioui , M. Barbouchi, S. Abbout , B. Benzidia, S. Moussaoui, S. Bikri, R. Hsissou, H. Hammouch, H. Erramli and N. Hajjaji, Development of a promising nontoxic corrosion inhibitor based on Opuntia dillenii seed oil for iron corrosion in 3Wt% NaCl: Experimental and theoretical approaches, Chemical Data Collections, 46, 101037, 2023. https://doi.org/10.1016/j.cdc.2023.101037.
  • J.-h. Zhu, B.-l. Lin, T.-h. Duan, H.-q. Lin, G.-y. Zhang, X.-x. Zhou and Y.-y. Xu, Zea mays bracts extract as an eco-friendly corrosion inhibitor for steel in HCl pickling solution: Experimental and simulation studies, Arabian Journal of Chemistry, 17, 105895, 2024. https://doi.org/10.1016/j.arabjc.2024.105895.
  • G. Aksaray ve B. Doğru Mert, Çukurova Bölgesinde Yetişen Karadut Meyvesinin Yumuşak Çeliğin 0,5 M HCl Çözeltisindeki Korozyon Davranışına Etkisi, Kadirli Uygulamalı Bilimler Fakültesi Dergisi, 4(1), 89-103, 2024.
  • S. A. Hussein and A. A. Khadom, Okra leaves extract as green corrosion inhibitor for steel in sulfuric acid: Gravimetric, electrochemical, and surface morphological investigations, Results in Chemistry, 8, 101566, 2024. https://doi.org/10.1016/j.rechem.2024.101566.
  • K. Hjouji, E. Ech-chihbi, I. Atemni, M. Ouakki, T. Ainane, M. Taleb and Z. Rais, Datura stramonium plant seed extracts as a new green corrosion inhibitor for mild steel in 1M HCl solution: Experimental and surface characterization studies, Sustainable Chemistry and Pharmacy, 34, 101170, 2023. https://doi.org/10.1016/j.scp.2023.101170.
  • D. Özkır, The Consistent Effect of Citrus aurantium Fruit Peels Extract as New Type Green Inhibitor on Mild Steel Corrosion in HCl Solution, Bayburt University Journal of Science, 5(2), 165–172, 2022. https://dx.doi.org/bufbd.1117000.
  • R. K. Mehta, S. K. Gupta and M. Yadav, Studies on pyrimidine derivative as green corrosion inhibitor in acidic environment: Electrochemical and computational approach, Journal of Environmental Chemical Engineering, 10, 108499, 2022. https://doi.org/10.1016/j.jece.2022.108499
  • Z. Akounach, A. Al Maofari, M. Damej, S. El Hajjaji, A. Berisha, V. Mehmeti, N. Labjar, M. Bamaarouf and M. Benmessaoud, Contribution to the corrosion inhibition of aluminum in 1 M HCl by Pimpinella anisum extract. Experimental and theoretical studies (DFT, MC, and MD), International Journal of Corrosion and Scale Inhibition, 11 (1), 402-424, 2022. https://doi.org/10.17675/2305-6894-2022-11-1-24.
  • M. E. Mert ve B. Doğru Mert, Karbon Ayak İzinin Azaltılması için Korozyon İnhibitörü Olarak Son Kullanma Tarihi Geçmiş Depakin Tabletin İncelenmesi, Kadirli Uygulamalı Bilimler Fakültesi Dergisi, 3(1), 56–66, 2023.
  • T. Karazehir, M. E. Mert and B. Doğru Mert, Corrosion prevention of mild steel in acidic medium by 2-Pyrrolidin-1-yl-1,3-thiazole-5-carboxylic acid: Theoretical and experimental approach, Journal of Indian Chemical Society, 99(9), 100642, 2022. https://doi.org/10.1016/j.jics.2022.100642.

Green inhibition effect of Pyracantha coccinea (Rosaceae) berries in assessing of acidic corrosion of iron

Yıl 2024, Cilt: 13 Sayı: 4, 1291 - 1297, 15.10.2024
https://doi.org/10.28948/ngumuh.1527976

Öz

The purpose of this study is to explore the potential of Pyracantha coccinea berries extract as a sustainable and environmentally friendly corrosion inhibitor on iron electrode under ambient conditions. This green inhibitor's impact was examined using different electrochemical experiments such as potentiodynamic polarization and electrochemical impedance spectroscopy (EIS). After a one-hour examination of the experiments with three different concentrations of Pyracantha coccinea berry extract, it was determined that the berry extract strongly inhibited the iron electrode in a solution containing 1.0 M HCl. The extract from Pyracantha coccinea berries revealed a strong inhibitor action, and iron electrode protection in HCl solutions increased as pyracantha extract concentrations increased. Finally, surface images were taken after an hour of immersion using a field-emission scanned electron microscope (FE-SEM) to analyse the surface morphology of the iron electrodes in aggressive HCl electrolyte with and without Pyracantha coccinea berry extract, and the surface containing the pyracantha extract was smoother than the blank one.

Kaynakça

  • B. Tan, Y. Liu, Z. Gong, X. Zhang, J. Chen, L. Guo, J. Xiong, J. Liu, R. Marzouki and W. Li, Pyracantha fortuneana alcohol extracts as biodegradable corrosion inhibitors for copper in H2SO4 media, Journal of Molecular Liquids, 397, 124117, 2024. https://doi.org/10.1016/j.molliq.2024.124117.
  • A. Abd-ElHamid, W. El-dougdoug, S. M. Syam, I. Aiad, S. M. Shaban and D. -H. Kim, Synthesis of gemini cationic surfactants-based pyridine Schiff base for steel corrosion and sulfate reducing bacteria mitigation, Journal of Molecular Liquids, 369, 120890, 2023. https://doi.org/10.1016/j.molliq.2022.120890.
  • H. Karima, B. Sameh, B. Baya, B. Louiza, H. Soraya, B. Hatem and B. Merzoug, Corrosion inhibition impact of Pyracantha coccinea M. Roem extracts and their use as additives in zinc electroplating: Coating morphology, electrochemical and weight loss investigations, Journal of the Taiwan Institute of Chemical Engineers, 121, 337-348, 2021. https://doi.org/10.1016/j.jtice.2021.04.007.
  • K. Dahmani, M. Galai, M. Ouakki, A. Elgendy, R. Ez-Zriouli, R. Lachhab, S. Briche and M. Cherkaoui, Corrosion inhibition of copper in sulfuric acid via environmentally friendly inhibitor (Myrtus Communis): Combining experimental and theoretical methods, Journal of Molecular Liquids, 347, 117982, 2022. https://doi.org/10.1016/j.molliq.2021.117982.
  • S. Wan, H. Wei, R. Quan, Z. Luo, H. Wang, B. Liao and X. Guo, Soybean extract firstly used as a green corrosion inhibitor with high efficacy and yield for carbon steel in acidic medium, Industrial Crops and Products, 187, 115354, 2022. https://doi.org/10.1016/j.indcrop.2022.115354.
  • H. E. Aadad, M. Galai, M. Ouakki, A. Elgendy, M. E. Touhami and A. Chahine, Improvement of the corrosion resistance of mild steel in sulfuric acid by new organic-inorganic hybrids of Benzimidazole-Pyrophosphate: Facile synthesis, characterization, experimental and theoretical calculations (DFT and MC), Surfaces and Interfaces, 24, 101084, 2021. https://doi.org/10.1016/j.surfin.2021.101084.
  • D. Özkır, The role of Lavandula sp. extract for effective inhibiting the mild steel corrosion in the hydrochloric acid solution, International Journal of Chemistry and Technology, 5(2), 125–132, 2021. https://dx.doi.org/10.32571/ijct.943385.
  • D. Özkır, The green inhibitive effect of Ptychostomum schleicheri (Bryophyta) extract on mild steel corrosion, Anatolian Bryology, 8(2), 114–122, 2022. https://doi.org/10.26672/anatolianbryology.1193546.
  • G. S. Sajadi, F. Salmanian, R. Naghizade and S. M. A. Hosseini, The inhibitive action of lemon verbena plant extract as an economical and eco-friendly corrosion inhibitor for mild steel in acidic solutions, International Journal of Electrochemical Science, 19, 100699, 2024. https://doi.org/10.1016/j.ijoes.2024.100699.
  • G. D. Pai, M. R. Rathod, S. K. Rajappa and A. A. Kittur, Effect of tabebuia heterophylla plant leaves extract on corrosion protection of low carbon steel in 1M HCl medium: Electrochemical, quantum chemical and surface characterization studies, Results in Surfaces and Interfaces, 15, 100203, 2024. https://doi.org/10.1016/j.rsurfi.2024.100203.
  • M. T. Muhammad, M. H. Hussin, M. H. Abu Bakar, T. S. Hamidon, S. S. Azahar, K. Awang, M. Litaudon and M. N. Azmi, Corrosion inhibitive performance of Kopsia teoi extracts towards mild steel in 0.5 M HCl solution, Materials Chemistry and Physics, 322, 129584, 2024. https://doi.org/10.1016/j.matchemphys.2024.129584.
  • D. Özkır, Insight into anti-corrosion effect of Mammillaria prolifera fruit extract as a green inhibitor for mild steel in HCl solution, Eurasian Journal of Science Engineering and Technology, 4(2), 071-077, 2023. https://doi.org/10.55696/ejset.1387199.
  • D. Özkır, Oleaster leaf extract: a potential environmentally friendly inhibitor for mild steel, Eurasian Journal of Biological and Chemical Science, 7(1), 20-25, 2024. https://doi.org/10.46239/ejbcs.1425801.
  • A. R. Bilia, I. Morelli and A. Marsili, Two glicosides from Pyracantha coccinea roots: a new lignan and a new chalcone, Tetrahedron, 50, 5181-5188, 1994. https://doi.org/10.1016/S0040-4020(01)90428-4.
  • G. Fico, A. R. Bilia, I. Morelli and F. Tomè, Flavonoid distribution in Pyracantha coccinea plants at different growth phases, Biochemical Systematics and Ecology, 28, 673-678, 2000. https://doi.org/10.1016/S0305-1978(99)00109-X.
  • Y. Wu, Z. Gong, L. Guo and A. A. AlObaid, Batatas lam leaf extract as a biodegradable corrosion inhibitor for copper in 0.5 M H2SO4 solution, Sustainable Chemistry and Pharmacy, 39, 101601, 2024. https://doi.org/10.1016/j.scp.2024.101601.
  • M. Rehioui , M. Barbouchi, S. Abbout , B. Benzidia, S. Moussaoui, S. Bikri, R. Hsissou, H. Hammouch, H. Erramli and N. Hajjaji, Development of a promising nontoxic corrosion inhibitor based on Opuntia dillenii seed oil for iron corrosion in 3Wt% NaCl: Experimental and theoretical approaches, Chemical Data Collections, 46, 101037, 2023. https://doi.org/10.1016/j.cdc.2023.101037.
  • J.-h. Zhu, B.-l. Lin, T.-h. Duan, H.-q. Lin, G.-y. Zhang, X.-x. Zhou and Y.-y. Xu, Zea mays bracts extract as an eco-friendly corrosion inhibitor for steel in HCl pickling solution: Experimental and simulation studies, Arabian Journal of Chemistry, 17, 105895, 2024. https://doi.org/10.1016/j.arabjc.2024.105895.
  • G. Aksaray ve B. Doğru Mert, Çukurova Bölgesinde Yetişen Karadut Meyvesinin Yumuşak Çeliğin 0,5 M HCl Çözeltisindeki Korozyon Davranışına Etkisi, Kadirli Uygulamalı Bilimler Fakültesi Dergisi, 4(1), 89-103, 2024.
  • S. A. Hussein and A. A. Khadom, Okra leaves extract as green corrosion inhibitor for steel in sulfuric acid: Gravimetric, electrochemical, and surface morphological investigations, Results in Chemistry, 8, 101566, 2024. https://doi.org/10.1016/j.rechem.2024.101566.
  • K. Hjouji, E. Ech-chihbi, I. Atemni, M. Ouakki, T. Ainane, M. Taleb and Z. Rais, Datura stramonium plant seed extracts as a new green corrosion inhibitor for mild steel in 1M HCl solution: Experimental and surface characterization studies, Sustainable Chemistry and Pharmacy, 34, 101170, 2023. https://doi.org/10.1016/j.scp.2023.101170.
  • D. Özkır, The Consistent Effect of Citrus aurantium Fruit Peels Extract as New Type Green Inhibitor on Mild Steel Corrosion in HCl Solution, Bayburt University Journal of Science, 5(2), 165–172, 2022. https://dx.doi.org/bufbd.1117000.
  • R. K. Mehta, S. K. Gupta and M. Yadav, Studies on pyrimidine derivative as green corrosion inhibitor in acidic environment: Electrochemical and computational approach, Journal of Environmental Chemical Engineering, 10, 108499, 2022. https://doi.org/10.1016/j.jece.2022.108499
  • Z. Akounach, A. Al Maofari, M. Damej, S. El Hajjaji, A. Berisha, V. Mehmeti, N. Labjar, M. Bamaarouf and M. Benmessaoud, Contribution to the corrosion inhibition of aluminum in 1 M HCl by Pimpinella anisum extract. Experimental and theoretical studies (DFT, MC, and MD), International Journal of Corrosion and Scale Inhibition, 11 (1), 402-424, 2022. https://doi.org/10.17675/2305-6894-2022-11-1-24.
  • M. E. Mert ve B. Doğru Mert, Karbon Ayak İzinin Azaltılması için Korozyon İnhibitörü Olarak Son Kullanma Tarihi Geçmiş Depakin Tabletin İncelenmesi, Kadirli Uygulamalı Bilimler Fakültesi Dergisi, 3(1), 56–66, 2023.
  • T. Karazehir, M. E. Mert and B. Doğru Mert, Corrosion prevention of mild steel in acidic medium by 2-Pyrrolidin-1-yl-1,3-thiazole-5-carboxylic acid: Theoretical and experimental approach, Journal of Indian Chemical Society, 99(9), 100642, 2022. https://doi.org/10.1016/j.jics.2022.100642.
Toplam 26 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Konular Malzeme Bilimi ve Teknolojileri, Kimya Mühendisliği (Diğer)
Bölüm Araştırma Makaleleri
Yazarlar

Demet Özkır 0000-0002-8096-5755

Erken Görünüm Tarihi 6 Eylül 2024
Yayımlanma Tarihi 15 Ekim 2024
Gönderilme Tarihi 4 Ağustos 2024
Kabul Tarihi 15 Ağustos 2024
Yayımlandığı Sayı Yıl 2024 Cilt: 13 Sayı: 4

Kaynak Göster

APA Özkır, D. (2024). Green inhibition effect of Pyracantha coccinea (Rosaceae) berries in assessing of acidic corrosion of iron. Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi, 13(4), 1291-1297. https://doi.org/10.28948/ngumuh.1527976
AMA Özkır D. Green inhibition effect of Pyracantha coccinea (Rosaceae) berries in assessing of acidic corrosion of iron. NÖHÜ Müh. Bilim. Derg. Ekim 2024;13(4):1291-1297. doi:10.28948/ngumuh.1527976
Chicago Özkır, Demet. “Green Inhibition Effect of Pyracantha Coccinea (Rosaceae) Berries in Assessing of Acidic Corrosion of Iron”. Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi 13, sy. 4 (Ekim 2024): 1291-97. https://doi.org/10.28948/ngumuh.1527976.
EndNote Özkır D (01 Ekim 2024) Green inhibition effect of Pyracantha coccinea (Rosaceae) berries in assessing of acidic corrosion of iron. Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi 13 4 1291–1297.
IEEE D. Özkır, “Green inhibition effect of Pyracantha coccinea (Rosaceae) berries in assessing of acidic corrosion of iron”, NÖHÜ Müh. Bilim. Derg., c. 13, sy. 4, ss. 1291–1297, 2024, doi: 10.28948/ngumuh.1527976.
ISNAD Özkır, Demet. “Green Inhibition Effect of Pyracantha Coccinea (Rosaceae) Berries in Assessing of Acidic Corrosion of Iron”. Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi 13/4 (Ekim 2024), 1291-1297. https://doi.org/10.28948/ngumuh.1527976.
JAMA Özkır D. Green inhibition effect of Pyracantha coccinea (Rosaceae) berries in assessing of acidic corrosion of iron. NÖHÜ Müh. Bilim. Derg. 2024;13:1291–1297.
MLA Özkır, Demet. “Green Inhibition Effect of Pyracantha Coccinea (Rosaceae) Berries in Assessing of Acidic Corrosion of Iron”. Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi, c. 13, sy. 4, 2024, ss. 1291-7, doi:10.28948/ngumuh.1527976.
Vancouver Özkır D. Green inhibition effect of Pyracantha coccinea (Rosaceae) berries in assessing of acidic corrosion of iron. NÖHÜ Müh. Bilim. Derg. 2024;13(4):1291-7.

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