Fractal adsorption characteristics and statistical analysis approach of complex dye molecule on metal oxide particles—A case study of Reactive Black 5(RB 5) adsorption onto NiO nanoparticles
Öz
In this study, environmental conditions for high efficient dye adsorption; initial pH, initial dye concentration, temperature, adsorbent concentration were determined as 6.0, 40oC, 100 mgL-1 and 1 g L-1, respectively. Obtained results from SEM, FT-IR and XRD analyzes were evaluated and compared with foundings in literature.
It was found that the equilibrium data can be best represented with Langmuir isotherm model, and it was concluded that RB 5-NiO adsorption system behaviour was explained the pseudo-second order kinetic model successfully. It was concluded that dye-nanoadsorbent system was exothermic (ΔH <0) and voluntary (ΔG<0). In thermodynamic analysis, RB 5 to NiO system adsorption proved that system has no structural change (S <0) at the adsobent-solution interface.
RSM (Response Surface Method) was used to express the interaction between process variables and responses and to examine the adsorption data. Removal percentages were determined theoretically using Design Expert 9.0.6 software program, and quadratic regression model was developed. It was seen that the adsorption parameters for the highest color removal obtained by the classical method were compared with the parameters found from RSM approach obtained under the same experimental conditions support each other.
Anahtar Kelimeler
Destekleyen Kurum
Mersin Üniversitesi
Teşekkür
We would like to thank Mersin University Cemical Engineering Laboratories and Advanced Technology Education, Research and Application Center, which was used in determination of particle surface properties in experimental studies.
Kaynakça
- [1] Akram, M.W., Abdul Motin, S. M., Hoque, M.A., and Mustafi N.N., (2019). Design, construction and performance test of a solar still for water desalination in Bangladesh perspective. Conference Paper in AIP Conference Proceedings, 2121, 130001, https://doi.org/10.1063/1.5115947
- [2] Rahman, M.H., Mamtaz, R., and Ferdausi, S.A., (1997). Pilot solar desalination plants in Bangladesh. WEDC CONFERENCE. 23(1997), 178–181.
- [3] Saleh, A.S., (2015). Solar Desalination in Bangladesh:Progress, Prospect, and Challanges, Proceedings of the International Conference on Mechanical Engineering and Renewable Energy. (ICMERE2015) 26 – 29 November, Chittagong, Bangladesh.
- [4] Hallaji, K., Yazıcıgil, H., (1996). Optimal management of a coastal aquifer in Southern Turkey. Journal of Water Resources Planning and Management. Volume 12.2, Issue 4, 233-244.
- [5] Bhattacharyya A., (2013). Solar stills for desalination of water in rural households. Int. J. Environ. Sustain., 2, no. 1, 21-30.
- [6] Kulkarni, S.J., Kherde, P.M., (2013). Research on Advanced Biological Effluent Treatment: A Review. International Journal of Research & Review (www.gkpublication.in). 2, 508-512.
- [7] Sheshdeh, R.K., Nikou, M.R. K., Badii, K., Limaee, N.Y., Golkarnarenji, G., (2014). Equilibrium and kinetics studies for the adsorption of Basic Red 46 on nickel oxide nanoparticles-modified diatomite in aqueous solutions. Journal of the Taiwan Institute of Chemical Engineers. 45, 1792–1802.
- [8] Slosarczyk, A., Paszkiewicz, Z., Paluszkiewicz, C., (2005). FTIR and XRD evaluation of carbonated hydroxyapatite powders synthesized by wet methods. Journal of Molecular Structure. 657–661.
- [9] Tharaneedhar, V., Kumar, P.S., (2017). Saravanan, A. Ravikumar, C. Jaikumar, V. Prediction and interpretation of adsorption parameters for the sequestration of methylene blue dye from aqueous solution using microwave assisted corncob activated carbon. Sustainable Materials and Technologies. 11, 1–11.
- [10] Chowdhury, A.N., Rahim, A., Ferdosi, Y. J., Azam, M. S., Hossain, M. M., (2010). Cobalt–nickel mixed oxide surface: A promising adsorbent for the removal of PR dye from water. Applied Surface Science. 256, 3718–3724.
