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Synthesis and Photophysical Properties of Pyrene-BODIPY Functionalized Subphthalocyanine Dyad

Yıl 2022, Cilt 7, Sayı 2, 74 - 80, 31.12.2022
https://doi.org/10.56171/ojn.1053225

Öz

The treatment of boron(III) subphthalocyanine chloride (SubPcCl) with borondipyrromethene (BODIPY) derivative consisting one pyrene group in toluene gave the corresponding axially substituted boron(III) subphthalocyanine dyad (SubPcBodiPy). Novel compound has been fully characterized by FTIR, mass, NMR (1H and 13C) spectroscopy and elemental analysis. Photophysical properties of SubPcBodiPy was investigated and compared with its precursors by fluorescence and absorption spectroscopy in THF. Accordingly, fluorescence lifetimes were measured directly by single exponential calculation.

Kaynakça

  • Ward M. D., (1997) “Photo-induced electron and energy transfer in non-covalently bonded supramolecular assemblies”, Chemical Society Reviews, vol.26, pp.365-375.
  • Balzani V., Bergamini G., Ceroni P., (2008) “From the photochemistry of coordination compounds to light-powered nanoscale devices and machines”, Coordination Chemistry Reviews, vol. 252, pp.2456-2469.
  • Holten D., Bocian D. F., Lindsey J. S., (2002) “Probing electronic communication in covalently linked multiporphyrin arrays. A guide to the rational design of molecular photonic devices” Accounts of Chemical Research, vol.35, pp.57-69.
  • Loudet A., Burgess K., (2007) “BODIPY dyes and their derivatives: syntheses and spectroscopic properties” Chemical Reviews, vol.107, pp.4891-4932.
  • Claessens C. G., González-Rodríguez D., Torres T., (2002) “Subphthalocyanines: singular nonplanar aromatic compounds synthesis, reactivity, and physical properties” Chemical Reviews, vol.102, pp.835-854.
  • Mutolo K.L., Mayo E.I., Rand B.P., Forrest S.R., Thompson M.E., (2006) “Enhanced opencircuit voltage in subphthalocyanine/C60 organic photovoltaic cells” Journal of American Chemical Society, vol.128, pp.8108-8109.
  • Xu S., Chen K., Tian H., (2005) “A colorimetric and fluorescent chemodosimeter: fluoride ion sensing by an axial-substituted subphthalocyanine” Journal of Materials Chemistry A, vol.15, pp.2676-2680.
  • Morse G. E., Helander M. G., Maka J. F., Lu Z. H., Bender T. P., (2010) “Fluorinated phenoxy boron subphthalocyanines in organic light-emitting diodes” ACS Applied Materials & Interfaces, vol.2(7), pp.1934-1944.
  • Renshaw K. C., Xu X., Forrest S. R., (2010) “A monolithically integrated organic photodetector and thin film transistor” Organic Electronics, vol.11, pp.175-178.
  • Li J. Y., Yeung H. S., Xu W., Li X., Ng D. K. P. (2008) “Highly Efficient Energy Transfer in Subphthalocyanine−BODIPY Conjugates” Organic Letters, vol.10, 23, pp.5421–5424.

Synthesis and Photophysical Properties of Pyrene-BODIPY Functionalized Subphthalocyanine Dyad

Yıl 2022, Cilt 7, Sayı 2, 74 - 80, 31.12.2022
https://doi.org/10.56171/ojn.1053225

Öz

The treatment of boron(III) subphthalocyanine chloride (SubPcCl) with borondipyrromethene (BODIPY) derivative consisting one pyrene group in toluene gave the corresponding axially substituted boron(III) subphthalocyanine dyad (SubPcBodiPy). Novel compound has been fully characterized by FTIR, mass, NMR (1H and 13C) spectroscopy and elemental analysis. Photophysical properties of SubPcBodiPy was investigated and compared with its precursors by fluorescence and absorption spectroscopy in THF. Accordingly, fluorescence lifetimes were measured directly by single exponential calculation.

Kaynakça

  • Ward M. D., (1997) “Photo-induced electron and energy transfer in non-covalently bonded supramolecular assemblies”, Chemical Society Reviews, vol.26, pp.365-375.
  • Balzani V., Bergamini G., Ceroni P., (2008) “From the photochemistry of coordination compounds to light-powered nanoscale devices and machines”, Coordination Chemistry Reviews, vol. 252, pp.2456-2469.
  • Holten D., Bocian D. F., Lindsey J. S., (2002) “Probing electronic communication in covalently linked multiporphyrin arrays. A guide to the rational design of molecular photonic devices” Accounts of Chemical Research, vol.35, pp.57-69.
  • Loudet A., Burgess K., (2007) “BODIPY dyes and their derivatives: syntheses and spectroscopic properties” Chemical Reviews, vol.107, pp.4891-4932.
  • Claessens C. G., González-Rodríguez D., Torres T., (2002) “Subphthalocyanines: singular nonplanar aromatic compounds synthesis, reactivity, and physical properties” Chemical Reviews, vol.102, pp.835-854.
  • Mutolo K.L., Mayo E.I., Rand B.P., Forrest S.R., Thompson M.E., (2006) “Enhanced opencircuit voltage in subphthalocyanine/C60 organic photovoltaic cells” Journal of American Chemical Society, vol.128, pp.8108-8109.
  • Xu S., Chen K., Tian H., (2005) “A colorimetric and fluorescent chemodosimeter: fluoride ion sensing by an axial-substituted subphthalocyanine” Journal of Materials Chemistry A, vol.15, pp.2676-2680.
  • Morse G. E., Helander M. G., Maka J. F., Lu Z. H., Bender T. P., (2010) “Fluorinated phenoxy boron subphthalocyanines in organic light-emitting diodes” ACS Applied Materials & Interfaces, vol.2(7), pp.1934-1944.
  • Renshaw K. C., Xu X., Forrest S. R., (2010) “A monolithically integrated organic photodetector and thin film transistor” Organic Electronics, vol.11, pp.175-178.
  • Li J. Y., Yeung H. S., Xu W., Li X., Ng D. K. P. (2008) “Highly Efficient Energy Transfer in Subphthalocyanine−BODIPY Conjugates” Organic Letters, vol.10, 23, pp.5421–5424.

Ayrıntılar

Birincil Dil İngilizce
Konular Mühendislik, Kimya, Temel Bilimler
Bölüm Araştırma Makalesi
Yazarlar

Seda ÇETİNDERE> (Sorumlu Yazar)
GEBZE TEKNİK ÜNİVERSİTESİ
0000-0001-7599-8491
Türkiye

Erken Görünüm Tarihi 13 Mart 2022
Yayımlanma Tarihi 31 Aralık 2022
Yayınlandığı Sayı Yıl 2022, Cilt 7, Sayı 2

Kaynak Göster

Bibtex @araştırma makalesi { ojn1053225, journal = {Open Journal of Nano}, eissn = {2147-0081}, address = {Sakarya Üniversitesi Fatih Mah. Eşit Sok. No:7/A -11 54580 - Arifiye / SAKARYA}, publisher = {Mustafa CAN}, year = {2022}, volume = {7}, number = {2}, pages = {74 - 80}, doi = {10.56171/ojn.1053225}, title = {Synthesis and Photophysical Properties of Pyrene-BODIPY Functionalized Subphthalocyanine Dyad}, key = {cite}, author = {Çetindere, Seda} }
APA Çetindere, S. (2022). Synthesis and Photophysical Properties of Pyrene-BODIPY Functionalized Subphthalocyanine Dyad . Open Journal of Nano , 7 (2) , 74-80 . DOI: 10.56171/ojn.1053225
MLA Çetindere, S. "Synthesis and Photophysical Properties of Pyrene-BODIPY Functionalized Subphthalocyanine Dyad" . Open Journal of Nano 7 (2022 ): 74-80 <https://dergipark.org.tr/tr/pub/ojn/issue/68194/1053225>
Chicago Çetindere, S. "Synthesis and Photophysical Properties of Pyrene-BODIPY Functionalized Subphthalocyanine Dyad". Open Journal of Nano 7 (2022 ): 74-80
RIS TY - JOUR T1 - Synthesis and Photophysical Properties of Pyrene-BODIPY Functionalized Subphthalocyanine Dyad AU - SedaÇetindere Y1 - 2022 PY - 2022 N1 - doi: 10.56171/ojn.1053225 DO - 10.56171/ojn.1053225 T2 - Open Journal of Nano JF - Journal JO - JOR SP - 74 EP - 80 VL - 7 IS - 2 SN - -2147-0081 M3 - doi: 10.56171/ojn.1053225 UR - https://doi.org/10.56171/ojn.1053225 Y2 - 2022 ER -
EndNote %0 Open Journal of Nano Synthesis and Photophysical Properties of Pyrene-BODIPY Functionalized Subphthalocyanine Dyad %A Seda Çetindere %T Synthesis and Photophysical Properties of Pyrene-BODIPY Functionalized Subphthalocyanine Dyad %D 2022 %J Open Journal of Nano %P -2147-0081 %V 7 %N 2 %R doi: 10.56171/ojn.1053225 %U 10.56171/ojn.1053225
ISNAD Çetindere, Seda . "Synthesis and Photophysical Properties of Pyrene-BODIPY Functionalized Subphthalocyanine Dyad". Open Journal of Nano 7 / 2 (Aralık 2022): 74-80 . https://doi.org/10.56171/ojn.1053225
AMA Çetindere S. Synthesis and Photophysical Properties of Pyrene-BODIPY Functionalized Subphthalocyanine Dyad. ojn. 2022; 7(2): 74-80.
Vancouver Çetindere S. Synthesis and Photophysical Properties of Pyrene-BODIPY Functionalized Subphthalocyanine Dyad. Open Journal of Nano. 2022; 7(2): 74-80.
IEEE S. Çetindere , "Synthesis and Photophysical Properties of Pyrene-BODIPY Functionalized Subphthalocyanine Dyad", Open Journal of Nano, c. 7, sayı. 2, ss. 74-80, Ara. 2022, doi:10.56171/ojn.1053225

ISSN: 2147-0081
The Open Journal of Nano dergisinde yayınlanan tüm yayınlar Atıf-GayriTicari 4.0 Uluslararası (CC BY-NC 4.0) lisansı altında lisanlanmıştır.