Kuşburnu (Rosa canina L.) nektarında rutin ve toplam fenolik bileşiklerin ısıl parçalanma kinetiği

Yıl 2018, Cilt: 24 Sayı: 7, 1370 - 1375, 28.12.2018

Çetin Kadakal , Tolga Duman

Öz

Bu
çalışmanın amacı, kuşburnu nektarının 70 ile 95 °C sıcaklık aralığında periyodik
olarak farklı süreyle (0, 5, 10, 15, 20 ve 30 dk.) ısıl işleme tabi tutulmasına
bağlı olarak rutin ve toplam fenolik bileşik içeriğinde meydana gelen değişimin
belirlenmesidir. Kuşburnu nektarının rutin içeriği sıvı kromatografisi (HPLC)
ve toplam fenolik madde miktarı spektrofotometrik yöntemle analiz edilmiştir.
Isıl işlem sırasında, kuşburnu nektarında ısıl işlem uygulamasına bağlı olarak
rutin ve TFB içeriğinin bozunması birinci dereceden kinetik modele uymuştur.
Reaksiyonun sıcaklık bağımlılığı Arrhenius ilişkisi ile tanımlanmıştır. Rutin
ve TFB içeriğinin 70 ile 95 °C sıcaklık aralığındaki aktivasyon enerjileri
sırasıyla 46.90 ve 35.72 J/mol olarak bulunmuştur.

Anahtar Kelimeler

Parçalanma kinetiği, HPLC, Fenolik, Kuşburnu nektarı, Rutin, Suda çözünen vitamin

Thermal degradation kinetics of rutin and total phenolic compounds in rosehip (Rosa canina L.) nectar

Öz

In
this research it is attempted to determine the loss of rutin and total phenolic
compounds in rosehip nectar with the heating periods (0, 5, 10, 15, 20 and 30
min) at temperatures ranging from 70 to 95 °C. Spectrophotometric and liquid
chromatographic (HPLC) methods were used to determine the concentrations of total
phenolic compounds and rutin, respectively. Thermal degradations of TPC and
rutin in rosehip nectar were fitted to a first-order reaction kinetic model.
Arrhenius relationship was used in order to describe the temperature dependence
of reaction. Activation energies for rutin and TPC between 70 to 95 °C were
found to be 46.90 and 35.72 J/mol, respectively.

Anahtar Kelimeler

Degradation kinetics, HPLC, Phenolic, Rosehip nectar, Rutin, Water- soluble vitamin

Kaynakça

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