Effect of Impregnation with Boron Compound Doped Rosin to the Combustion Resistance of Oriental Beech Wood (Fagus orientalis Lipsky)

Yıl 2021, Cilt: 24 Sayı: 2, 655 - 662, 01.06.2021

Taner Aşçı , Hakan Keskin

https://doi.org/10.2339/politeknik.726738

Öz

In this study, investigation of the combustion properties of Oriental beech wood (Fagus orientalis Lipsky) impregnated with boron compound (borax (Na2B4O710H2O), boric acid (H3BO3) doped rosin (C19H29COOH) was aimed. For this purpose, Oriental beech wood samples were prepared according to ASTM E 160-50 and impregnated with boron compound doped rosin by the method of medium-term dipping (24 hours) according to ASTM D 1413 and producers’ definition. Combustion properties of samples after impregnated process were determined according to ASTM E 160-50. As a part of the research, 6 different combination and contents of impregnation materials have been used in order to especially investigate resistance against combustion of wood material treated with boron compounds in different concentrations. As a result of the study, retention performance and leaching resistance of boron compounds can be increased through rosin addition. Consequently, impregnation materials with rosin decreased the flame sourced combustion (Fsc) temperatures depending on kind of impregnation material, extended combustion period and decreased weight loss ratio of the test samples in comparison to the control samples. On the contrary, weight loss ratios were affected negatively in Oriental beech test samples up to 3% when compared with samples which were impregnated with borax. Meanwhile, combustion periods increased in test samples up to 30%. Rosin, in terms of its combustion performance, can be preferred in impregnation with boron compounds depending on kind of wood and using area.

Anahtar Kelimeler

Combustion, impregnation, Rosin, boron compounds

Destekleyen Kurum

Gazi Üniversitesi, Bilimsel Araştırma Projeleri

Proje Numarası

07/2012-40

Teşekkür

Çalışmayı destekleyen başta danışmanım Prof. Dr. sayın Hakan Keskin olmak üzere BAP yoluyla kıymetli destekler sağlayan Gazi Üniversitesine Teşekkür ederim.

Kaynakça

• [1] Ors, Y. and Keskin, H., “Wood material technology,” Gazi Publishing, Ankara, 141-151. (2008).
• [2] Kartal,S.N., Imamura, Y., “Usage of boron compound as impregnation materials in wood and composites”. 3rd International Boron Symposium, 333, Eskişehir, (2004).
• [3] Baysal E., Sönmez A., Çolak M., Toker H., “Amount of leachant and water absorption levels of wood treated with borates and water repellents.” Bioresource Technology 97: 2271-2279, (2006).
• [4] Baysal E., “Fire features of Scots pine wood impregnated with boron compounds and natural tanning materials”. Erciyes University, Journal of Applied Science Institute, 59-61, (2003).
• [5] Obanda, D., Shupe, T. and Barnes, H.M., “Reducing leaching of boron-based wood preservatives – A review of research,” Bioresource Technology 99, 7312–7322, (2008).
• [6] Mohareb, A., “Development of leach-resistant boron compounds for wood protectıon ın exterior applications in Egypt.” Ph.D. Thesis, Gent University, (2005)
• [7] Lesar, B., Kralj, P., Humar, M., “Montan wax improves performance of boron-based wood preservatives”, International Biodeterioration& Biodegradation, 63; 306–310, (2009).
• [8] Örs, Y. and Keskin, H., “Wood Material Instruction” Gazi University Publish No:. 2000/352, Atlas Publishing, İstanbul, Turkey (2001).
• [9] Örs, Y., Atar, M., Peker, H., “The impact of different impregnation and surface treatment materials on combustion properties of Scots Pine and Chestnut trees.” Journal of Agriculture and Forestry, 541, (1999).
• [10] Temiz, A., Gezer E.D., Yıldız, U.C. and Yıldız, S., “Combustion properties of alder (Alnusglutinosa L.) Gaertn. subsp. barbata (C.A. Mey) Yalt.) and southern pine (Pinus sylvestris L.) wood treated with boron compounds,” Construction and Building Materials 22, 2165–2169, (2008).
• [11] Uysal, B., “The impacts of various chemical materials on combustion resistance of wood material,” Ph.D. Thesis, Gazi University Institute of Applied Sci., Ankara, 96-99, (1997).
• [12] Uysal, B., Kurt, Ş., “Combustion properties of Oriental Beech and Scots Pine wood impregnated withboron compounds”,I. National Boron Workshop Papers Handbook, 33-41, (2005).
• [13] Uysal, B., Kurt. Ş., Esen, R., Özcan, C., Yıldırım, M. N., Kılınç, İ., “The impact on combustion resistance of surface treatments applied to the Sapele wood impregnated with some chemicals” 6th International Advanced Technologies Symposium, 267-275, (2011).
• [14] Giachi, G., Capretti, C., Donato I., Macchioni, N. and Pizzo B., “New trials in the consolidation of waterlogged archaeological wood with different acetone-carried products,” Journal of Archaeological Science 38, 2957-2967, (2011).
• [15] TS 2476 “Sampling methods for physical and mechanical tests of wood materials and general features,” TSE, Ankara, Turkey, (1976).
• [16] Ors, Y., Atar M., Keskin, H. and Colakoglu, H.M., “Impacts of impregnation with boron compounds on the surface roughness of some woods and varnished surfaces,” J. of Applied Polymer Science (JAPS), 102(5): 4952-4954, (2006).
• [17] Unger, A., Schniewind A.P. and Unger W., Conservation of wood artifacts, Handbook, Published by Springer, USA, (2001).
• [18] ASTM E 160-50, “Standard test method for combustible properties of treated wood by the crib test,” Annual Book of ASTM Standards, West Conshohocken, PA, (1975).
• [19] ASTM D 1413-99, “Standard method of testing wood preservatives by laboratory soil block cultures,” Annual Book of ASTM Standards, West Conshohocken, PA, (2005).
• [20] Keskin, H., Ertürk, N.S., Çolakoglu, M.H. and Korkut S. “Combustion properties of rowan wood impregnated with various chemical materials,” International Journal of Physical Sciences (IJPS) 8(19): 1022-1028, (2013).
• [21] Baysal, E, Yalınkılıç, M.K., Çolak, M., Göktaş, O., “Combustion Properties of Calabrian Pine ( Pinus brutia Ten.) Wood Treated with Vegetable Tanning Extracts and Boron Compounds,” TUBITAK Journal of Agriculture, I.27, 245-252, (2003).
• [22] Kurt, R., Mengeloğlu, F., “The Effect Of Borıc Acıd / Borax Treatment On Selected Mechanıcal And Combustıon Propertıes Of Poplar Lamınated Veneer Lumber,” Journal of Wood Research 53(2): 113-120, (2008).
• [23] Wu, G. F., Xu, M., “Effects of boron compounds on the mechanical and fire properties of wood-chitosan and high-density polyethylene composites.” Bioresources, 9(3): 4173-4193, (2014).
• [24] Wang, F., Liu, J., Lyu, W., “Effect of boron compounds on properties of Chinese fir wood treated with PMUF resin.” Journal of Bioresources and Bioproducts, 4(1): 60–66, (2019).
• [25] Altuntaş, E., Karaoğul, E., Alma, M.H., “Odun-plastik kompozitlerin termal ve yanma özellikleri üzerine borlu bileşiklerin etkisi.” Turkish Journal of Forestry, 18(3): 247-250, (2017).