Sulak alanlarda potansiyel toksik element (PTE) kaynaklı bölgesel ekolojik risk araştırmalarında kullanılan analitik metotlar
Yıl 2021,
Sayı: 77, 211 - 222, 30.06.2021
Şakir Fural
,
Serkan Kükrer
Öz
Sulak alan ekosistemleri çok sayıda fauna ve flora türüne yaşam ortamı sunan, aynı zamanda insanların faydalandığı önemli doğal kaynak değerleridir. Son yıllarda artan antropojenik etkiler sulak alanlarda PTE kaynaklı ekolojik bozulmaya ve buralardan çeşitli yollarla faydalanan insanlar üzerinde sağlık risklerine neden olmaktadır. Bu nedenle, sulak alanlarda ekolojik bozulma ve sağlık riski analizleri yapmak için analitik metotlar geliştirilmiştir. Zenginleşme faktörü (Enrichment factor-EF), Kontaminasyon faktörü (Contamination factor-CF), Modifiye kontaminasyon derecesi (Modified contamination degree-mCd), Jeoakümülasyon indeksi (Geoaccumulation index-Igeo) ile elementlerin doğal ve antropojenik kaynakları tespit edilmektedir. Modifiye ekolojik risk indeksi (Modified ecological risk-mER) Modifiye potansiyel ekolojik risk indeksi (Modified potential ecological risk-mPER), Kirlilik yük indeksi (Pollution load index-PLI), Toksik risk indeksi (Toxic risk index-TRI), Modifiye edilmiş risk oranı (Modified hazard quotient-mHQ), Ekolojik kontaminasyon indeksi (Ecological contamination index-ECI) ve Kontaminasyon ağırlık indeksiyle (Contamination severity index-CSI) ekolojik risk değerlendirmesi yapılmaktadır. Kanserojen olmayan sağlık risklerinin tespiti için Tehlike indeksi (Hazard index- HI) ve Tehlike oranı (Hazard quotient-HQ), kanser riski tespiti için Yaşam boyu toplam kanser riski indeksi (Lifetime cancer risk index-LCR) hesaplanmaktadır. PTE’lerin ortak kaynaklarını tanımlamak ve taşınma süreçlerini tespit etmek için çok değişkenli istatistiksel analizler ve Coğrafi Bilgi Sistemleri’ne dayalı mekânsal analizler kullanılmaktadır. Bu çalışmada, yukarıda belirtilen metotların kapsamlı bir değerlendirmesi yapılmıştır.
Destekleyen Kurum
Destek alınmamıştır.
Teşekkür
Potansiyel toksik element kaynaklı bölgesel ekolojik risk araştırmalarımızdaki katkıları için Prof. Dr. A. Evren Erginal ve Prof. Dr. İsa Cürebal’a, makalenin son şeklini alması için görüş ve önerilerini sunarak katkı sağlayan değerli hakemlere teşekkür ederiz.
Kaynakça
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Analytical methods used in regional ecological risk assessment of potentially toxic elements (PTEs) in wetlands
Yıl 2021,
Sayı: 77, 211 - 222, 30.06.2021
Şakir Fural
,
Serkan Kükrer
Öz
Wetland ecosystems are important natural resources that provide a habitat for many fauna and flora species and they are highly beneficial for people as well. Increasing anthropogenic effects in recent years cause ecological degradation in wetlands as a result of PTE resulting in health risks for people who benefit from wetlands in various ways. Therefore, analytical methods have been developed for ecological degradation and health risk assessments in wetlands. Enrichment factor (EF), Contamination factor (CF), Modified contamination degree (mCd) and Geoaccumulation index (Igeo) are used to identify natural and anthropogenic sources of elements. Modified ecological risk (mER), Modified potential ecological risk (mPER), Pollution load index (PLI), Toxic risk index (TRI), Modified hazard quotient (mHQ), Ecological contamination index (ECI) and Contamination severity index (CSI) are utilized for ecological risk assessment. Hazard index (HI) and Hazard quotient (HQ) are used to detect non-carcinogenic health risks and Lifetime cancer risk index (LCR) is used to for the detection of cancer risk. Multivariate statistical analyzes and Geographic Information Systems based spatial analyzes are used to identify the common sources of PTEs and to determine their transportation processes. This study presents a comprehensive evaluation of the above-mentioned methods.
Kaynakça
- Abrahim, G., & Parker, R. (2008). Assessment of heavy metal enrichment factors and the degree of contamination in marine sediments from Tamaki Estuary, Auckland, New Zealand. Environmental Monitoring and Assessment, 136, 227-238. https://doi.org/10.1007/s10661-007-9678-2
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https://doi.org/10.1016/j.mex.2018.03.005
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- Cürebal İ., Efe R., Soykan A., & Sönmez S. (2015). Impacts of anthropogenic factors on land degradation during the anthropocene in Turkey. Journal of Environmental Biology, 36, 51-58. https://pubmed.ncbi.nlm.nih.gov/26591882/
- Çavuşoğlu K., Gündoğan Y., Arıca Ç.Ş., & Kırındı T. (2007). Mytilus sp (midye), gammarus sp (nehir tırnağı) ve cladophora sp (yeşil alg) örnekleri kullanılarak Kızılırmak nehrindeki ağır metal kirliliğin araştırılması. Balıkesir Üniversitesi Fen Bilimleri Enstitüsü Dergisi, 9, 52-60. http://fbe.balikesir.edu.tr/dergi/20071/BAUFBE2007-1.pdf
- Eker, Ç. S. (2020). Distinct contamination indices for evaluating potentially toxic element levels in stream sediments: a case study of the Harşit Stream (NE Turkey). Arabian Journal of Geosciences, 13, (22), https://doi.org/1-18. 10.1007/s12517-020-06178-w
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- ESRI. (2021). How kriging works, https://desktop.arcgis.com/en/arcmap/10.3/tools/3d-analyst-toolbox/how-kriging- works.htm.
Falkenmark, M., Lundqvist, J. & Widstrand, C. (1989). Macro-scale water scarcity requires micro-scale approaches. Natural Resources Forum, 13, 258-267. http://dx.doi.org/10.1111/j.1477-8947.1989.tb00348.x
- Fural, Ş. (2020). İkizcetepeler baraj gölü çökellerinin (Balıkesir) ekolojik risk analizi. (Tez yayın numarası: 641963) [doktora tezi, Balıkesir Üniversitesi], YÖK Ulusal Tez Merkezi. https://tez.yok.gov.tr/UlusalTezMerkezi/tezSorguSonucYeni.jsp
- Fural, Ş., Kükrer, S., & Cürebal, İ. (2020). Geographical information systems based ecological risk analysis of metal accumulation in sediments of İkizcetepeler Dam Lake (Turkey). Ecological Indicators, 119. https://doi.org/10.1016/j.ecolind.2020.106784
- Fural, Ş., Kükrer, S., Cürebal, İ., & Aykır, D. (2021). Spatial distribution, environmental risk assessment, and source identification of potentially toxic metals in Atikhisar dam, Turkey. Environmental Monitoring and Assessment,193, https://doi.org/10.1007/s10661-021-09062-6
- Hakanson, L. (1980). An ecological risk index for aquatic pollution control: A sedimentological approach. Water Research, 14, 975-1001. https://doi.org/10.1016/0043-1354(80)90143-8
- Iqbal, J., Tirmizi SA., & Shah, MH. (2013). Statistical apportionment and risk assessment of selected metals in sediments from Rawal Lake (Pakistan). Environmental Monitoring and Assessment, 185, 729-743. https://doi.org/10.1007/s10661-012-2588-y
- Kaya, H., Erginal, G., Çakır, Ç., Gazioğlu, C., & Erginal, A. (2017). Ecological risk evaluation of sediment core samples, Lake Tortum (Erzurum, NE Turkey) using environmental indices. International Journal of Environment and Geoinformatics, 4, 227-239. https://doi.org/10.30897/ijegeo.348826
- Kır, İ., & Tuncay, Y. (2010). Kovada Gölü'nde Yaşayan İstakozlarda (Astacus leptodactylus) Bazı Ağır Metallerin Birikiminin İncelenmesi. Süleyman Demirel Üniversitesi Fen Edebiyat Fakültesi Fen Bilimleri Dergisi, 5, 179-186. https://dergipark.org.tr/tr/pub/sdufeffd/issue/11272/134705
- Kırıs, E., & Baltas, H. (2020). Assessing pollution levels and health effects of heavy metals in sediments around Cayeli copper mine area, Rize, Turkey. Environmental Forensics, 22,372-384. https://doi.org/10.1080/15275922.2020.1850572
- Kükrer, S. (2017). Pollution, source, and ecological risk assessment of trace elements in surface sediments of Lake Aktaş, NE Turkey. Human and Ecological Risk Assesment, 7, 1629-1644. https://doi.org/10.1080/10807039.2017.1332953
- Kükrer, S. (2018). Vertical and Horizontal Distribution, Source İdentification, Ecological and Toxic Risk Assessment of Heavy Metals in Sediments of Lake Aygır, Kars, Turkey. Environmental Forensics, (19), 122-133. https://doi.org/10.1080/15275922.2018.1448905
- Kükrer, S., Çakır, Ç., Kaya, H., & Erginal, E. A. (2019). Historical record of metals in Lake Küçükçekmece and Lake Terkos (Istanbul, Turkey) based on anthropogenic impacts and ecological risk assessment. Environmental Forensics, 4, 385-401. https://doi.org/10.1080/15275922.2019.1657985
- Kükrer, S., Erginal, A. E., Şeker, S., & Karabıyıkoğlu, M. (2015). Distribution and environmental risk evaluation of heavy metal in core sediments from Lake Çıldır (NE Turkey). Environ. Monit. Assess, 7, https://doi.org/10.1007/s10661-015-4685-1
- Laval-Martin, D. (1985). Spectrophotometric method of controlled pheophytinization for the determination of both chlorophylls and pheophytins in plant extracts. Analytical Biochemistry, 149, 121-129. https://doi.org/10.1016/0003-2697(85)90484-1
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