Metal Nanoparticle Based Electrocatalyst Synthesis and Electrochemical Hydrogen Peroxide Sensor

Yıl 2024, , 260 - 274, 30.04.2024

Fırat Salman , Hilal Çelik Kazıcı , Mehmet Sait İzgi

https://doi.org/10.53433/yyufbed.1202386

Öz

Hydrogen peroxide plays an active role in biological processes. Therefore, the detection of hydrogen peroxide is very important in the food, medical, pharmaceutical, chemical industries, and medical fields. H2O2 is essential for human health and plays an active role in the regulation of various physiological processes. H2O2 concentrations are considered to be an important marker for various diseases such as Parkinson's and Alzheimer's disease, stroke, stress syndromes, atherosclerosis, malignancies, and mitochondrial abnormalities. Therefore, it is important to develop fast, inexpensive, reliable and suitable methods for the detection of hydrogen peroxide. It can be said that electrochemical methods are more sensitive, efficient, low-cost and time-saving methods than traditional methods for the determination of hydrogen peroxide. To update the latest research, the researchers were more interested in the study of the development of existing nanostructured electrocatalysts, electrode modification and the applications of new electrochemical sensors. This study focused on the synthesis of metal-supported particles, the investigation of the electrochemical behavior of hydrogen peroxide, and the development of electrodes with high catalytic activity for the hydrogen peroxide sensor. For this purpose, the electrocatalysts Cr-Fe-P/CNT, Cr-Fe-P/Eupergit CM, and Cr-Fe-P/CNT were prepared easily and quickly. The electrodes developed with these prepared electrocatalysts, the electrochemical behavior of hydrogen peroxide and the sensor activities of hydrogen peroxide were investigated by cyclic voltammetry.

Anahtar Kelimeler

Electrochemical sensor, Hydrogen peroxide, Metallic electrocatalys

Metal Nanopartikül Temelli Elekrokatalizör Sentezi ve Elektrokimyasal Hidrojen Peroksit Sensörü

Öz

Hidrojen peroksit biyolojik süreçlerde aktif bir rol oynar. Bundan dolayı gıda, medikal, ilaç, kimya endüstrileri ve tıp alanlarında hidrojen peroksitin tespiti çok önemlidir. H2O2 insan sağlığı için gereklidir ve çeşitli fizyolojik süreçlerin düzenlenmesinde aktif rol oynar. Parkinson ve alzheimer hastalığı, felç, stres sendromları, damar sertliği, maligniteler ve mitokondriyal anormallikler gibi çeşitli hastalıklar için H2O2 konsantrasyonlarının önemli bir belirteç olduğu kabul edilmektedir. Bu yüzden hidrojen peroksitin tespiti için hızlı, ucuz, güvenilir uygun yöntemler geliştirmek önemlidir. Hidrojen peroksit tayini için geleneksel yöntemlere karşı elektrokimyasal yöntemler, daha hassas, verimli, düşük maliyetli ve zaman kazandıran yöntemler olduğu söylenebilir. Araştırmacılar, en son araştırmaları güncellemek için mevcut nanoyapılı elektrokatalizörlerin geliştirilmesi, elektrot modifikasyonu ve yeni elektrokimyasal sensörlerin uygulamaları çalışmalarına daha fazla ilgilendiler. Bu çalışmada metal destekli partiküllerin sentezlenmesi, hidrojen peroksitin elektrokimyasal davranışının incelenmesi ve hidrojen peroksit sensörü için katalitik aktivitesi yüksek elektrotlar geliştirilmesi üzerine odaklanıldı. Bu amaçla Cr-Fe-P/CNT, Cr-Fe-P/Eupergit CM, Cr-Fe-P/CNT elektrokatalizörleri kolay ve hızlı bir şekilde hazırlandı. Hazırlanan bu elektrokatalizörler ile geliştirilen elektrotlar, hidrojen peroksitin elektrokimyasal davranışı ve hidrojen peroksit sensör aktiviteleri döngüsel voltametri ile incelenmiştir.

Anahtar Kelimeler

Elektrokimyasal sensör, Hidrojen peroksit, Metalik elektrokatalizör

Kaynakça

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