BibTex RIS Cite

3-MCPD and Glycidyl Esters in Potato Chips Sold in Turkey

Year 2016, Volume: 14 Issue: 3, 267 - 274, 01.09.2016

Abstract

3-Chloropropane 1,2-diol 3-MCPD is a food-based contaminant. 3-MCPD is declared as a genotoxic carcinogen formed in foods by the Scientific Committee on Food of the European Commission and the UK Food Advisory Committee has recommended reducing its level to minimum in foods. The objective of this study is to determine 3MCPD esters and glycidyl esters contents of commercially available potato chips sold in Turkey. For this purpose, various brands of potato chips were obtained from local markets. The effects of production method brands and frying oil were investigated statistically based on the formation of 3-MCPD esters and glycidyl esters in various brands of potato chips. Moreover, maximum consumption for potato chips was calculated based on tolerable daily intake of 3MCPD esters for individuals of average body weight. DGF C V 18 10 standard method was used for determination of 3-MCPD esters and glycidyl esters in potato chips. Maximum value for 3-MCPD esters was 2.97 mg/kg in B2 brand Sample Block 2 . Also, the highest amount of glycidyl esters was determined as 6.01 mg/kg in B2 brand Sample Block 2

References

  • EFSA (European Food Safety Authority), 2013. Analysis of occurrence of 3-monochloropropane- 1,2-diol (3-MCPD) in food in Europe in the years 2009-2011 and preliminary exposure assessment. EFSA Journal 11(9): 3381.
  • Li, C., Li, L., Jia H., Wang, Y., Shen, M., Nie, S., Xie M., 2016. Formation and reduction of 3- monochloropropane-1,2-diol esters in peanut oil during physical refining. Food Chemistry 199: 605- 611.
  • FSA, 2006. Update on chemical contaminants legislation, UK Food Standards Agency, İngiltere.
  • Divinová, V., Svejkovská, B., Doležal, M., Velíšek, J., 2007. Free and bound 3-chloropropane-1,2-diol in coffee surrogates and malts. Czech J. Food Science 25(1): 39–47.
  • Velisek,J., Davidek, J., Kubelka, V., Janicek, G., Svobodova, Z., Simicova, Z., 1980. New chlorine- containing hydrolysates. J. Agric. Food Chem. 28: 1142-1144.
  • Yemişçioğlu, F., Karabulut, M., 2012. Rafine Bitkisel Yağlarda 3-MCPD, Analiz 35, İzmir Gıda Laboratuvar Müdürlüğü, 14: 8-10.
  • Chung, H.Y., Chung, S.W.C., Chan, B.T.P., Ho, Y.Y., Xiao, Y., 2013. Dietary exposure of Hong Kong adults to fatty acid esters of 3- monochloropropane-1,2-diol. Food Additives & Contaminants 30(9): 1508-1512.
  • Risk Assessment Studies, 2012. Fatty Acid Esters of 3-Monochloropropane-1,2-diol (3-MCPD) in food. Centre for Food Safety, Hong Kong, Report No:50.
  • Andres,S., Appe, l. K.E., Lampen, A., 2013. Toxicology, occurrence and risk characterisation of the chloropropanols in food: 2-Monochloro-1,3- propanediol, 1,3-dichloro-2-propanol and 2,3- dichloro-1-propanol. Food and Chemical Toxicology 58: 467-478.
  • Zhang, X., Gao, B., Qin, F., Shi, H., Jiang, Y., Xu, X., (Lucy) Yu, L ., 2013. A free radical mediated formation of 3-monochloropropanediol (3-MCPD) fatty acid diesters. J. Agric. Food Chemistry 61(10): 2548-55.
  • Hamlet, C.G., Asuncion, L., Velisek, J., Dolezal, M., Zelinkova, Z., Crews, C., 2011. Formation and occurrence of esters of 3-chloropropane-1,2-diol (3- CPD) in foods: What we know and what we assume. Eur. J. Lipid Sci. Technol. 113(3): 279– 303.
  • European Commission. Commission Regulation (EC), 2001. Setting maximum levels for certain contaminants in foodstuffs No. L77: 1– 13.
  • Kim, H.Y., Lee, S.B., Lim, K.T., Kim, M.K., Kim, J.C., 2007. Subchronic inhalation toxicity study of 1,3-dichloro-2-propanol in rats. Ann. Occup. Hyg. 51(7): 633–643.
  • IARC, 2012. 1,3-Dichloro-2-propanol, International Agency for Research on Cancer(IARC), IARC Monographs on the Evaluation of the Carcinogenic Risks /mono101-011.pdf> (Erişim Tarihi: 01.08.2016).
  • Svejskovska, B., Novotný, O., Divinová, M., Réblová, Z., 2004. Esters of 3-chloropropane-1,2- diol in foodstuffs. Czech J. Food Sci. 22(5): 190– 196.
  • Chung, S.W.C., Kwong, K.P., Yau, J.C.W., Wong, A.M.C., Xiao, Y., 2008. Chloropropanols levels in foodstuffs marketed in Hong Kong. Journal of Food Composition and Analysis 21: 569-573.
  • Zelinkova, Z., Novotny, O., Schurek, J., Velíšek, J., Haslova, J., Dolezal, M., 2006. Occurrence of 3- MCPD fatty acid esters in human breast milk. Food Additives and Contaminants 25 (06):669–679.
  • Dingel, A., Matlssek, R., 2015. Esters of 3- monochloropropane-1,2-diol formation by deep frying during large scale production of potato crisps. Eur. Food Res. Technol. 241(5): 719–723. and glycidol: no
  • Zelinkova, Z., Velíšek, J., Dolezal, M., 2009.3- Chloropropane-1,2-diol fatty acid esters in potato products. Czech J. Food. Sci. 27: 421-424.
  • Vicente, E., Arisseto, A.P., Furlani, R.P.Z., Monteiro, V., Gonçalves, L.M., Pereira, A.L.D., Toledo, monochloropropane-1,2-diol (3-MCPD) in selected processed foods from the Brazilian market. Food Research International 77: 310-314. of 3
  • DGF, 2009. German Standard Methods for the Analysis of Fats and other Lipids: C-III 18 (09), Ester-bound 3-chloropropane-1,2-diol (3-MCPD- Esters) and glycidol (glycidyl esters): Determination in fats and oils by GC-MS, WVG.

Türkiye Piyasasında Satışa Sunulan Patates Cipslerinde 3-MCPD Esterleri ve Glisidil Esterleri Miktarları

Year 2016, Volume: 14 Issue: 3, 267 - 274, 01.09.2016

Abstract

3-Kloropropan 1,2-diol 3-MCPD maddesi gıda kaynaklı bulaşanlardandır. 3-MCPD, Avrupa Komisyonu’nun Gıda Bilimsel Komitesi tarafından genotoksik karsinojen olarak belirlenmiş ve İngiltere Gıda Danışma Komitesi tarafından gıda ve gıda maddelerinde minimum düzeylere indirilmesi önerilen proses tabanlı bulaşan olarak tanımlanmıştır. Bu çalışmanın amacı, piyasadan elde edilen ve farklı markalardan alınan patates cipslerinin 3-MCPD esterleri ve glisidil esterlerinin miktarlarının belirlenmesidir. Patates cipslerinde bulunan 3-MCPD esterleri ve glisidil esterleri miktarları üzerine üretim yönteminin markanın ve kızartma amacıyla kullanılan yağ tipinin etkisi istatistiksel olarak incelenmiştir. Ayrıca ortalama vücut ağırlığına sahip bir bireyin, saptanan miktarlarda 3-MCPD esteri içeren patates cipsi tüketim sınırları ve tolere edilebilir günlük alım miktarları üzerinden hesaplanmıştır. Patates cipslerinin toplam 3MCPD esterleri ve glisidil esterleri miktarlarının belirlenmesi için DGF C VI 18 10 standart yöntemi kullanılmıştır. En yüksek 3-MCPD esterleri miktarı 2.97 mg/kg olarak B2 markasında Örnekleme 1 bulunmuştur. Ayrıca en yüksek glisidil esterleri miktarı B2 markasında Örnekleme 2 6.01 mg/kg olarak tespit edilmiştir

References

  • EFSA (European Food Safety Authority), 2013. Analysis of occurrence of 3-monochloropropane- 1,2-diol (3-MCPD) in food in Europe in the years 2009-2011 and preliminary exposure assessment. EFSA Journal 11(9): 3381.
  • Li, C., Li, L., Jia H., Wang, Y., Shen, M., Nie, S., Xie M., 2016. Formation and reduction of 3- monochloropropane-1,2-diol esters in peanut oil during physical refining. Food Chemistry 199: 605- 611.
  • FSA, 2006. Update on chemical contaminants legislation, UK Food Standards Agency, İngiltere.
  • Divinová, V., Svejkovská, B., Doležal, M., Velíšek, J., 2007. Free and bound 3-chloropropane-1,2-diol in coffee surrogates and malts. Czech J. Food Science 25(1): 39–47.
  • Velisek,J., Davidek, J., Kubelka, V., Janicek, G., Svobodova, Z., Simicova, Z., 1980. New chlorine- containing hydrolysates. J. Agric. Food Chem. 28: 1142-1144.
  • Yemişçioğlu, F., Karabulut, M., 2012. Rafine Bitkisel Yağlarda 3-MCPD, Analiz 35, İzmir Gıda Laboratuvar Müdürlüğü, 14: 8-10.
  • Chung, H.Y., Chung, S.W.C., Chan, B.T.P., Ho, Y.Y., Xiao, Y., 2013. Dietary exposure of Hong Kong adults to fatty acid esters of 3- monochloropropane-1,2-diol. Food Additives & Contaminants 30(9): 1508-1512.
  • Risk Assessment Studies, 2012. Fatty Acid Esters of 3-Monochloropropane-1,2-diol (3-MCPD) in food. Centre for Food Safety, Hong Kong, Report No:50.
  • Andres,S., Appe, l. K.E., Lampen, A., 2013. Toxicology, occurrence and risk characterisation of the chloropropanols in food: 2-Monochloro-1,3- propanediol, 1,3-dichloro-2-propanol and 2,3- dichloro-1-propanol. Food and Chemical Toxicology 58: 467-478.
  • Zhang, X., Gao, B., Qin, F., Shi, H., Jiang, Y., Xu, X., (Lucy) Yu, L ., 2013. A free radical mediated formation of 3-monochloropropanediol (3-MCPD) fatty acid diesters. J. Agric. Food Chemistry 61(10): 2548-55.
  • Hamlet, C.G., Asuncion, L., Velisek, J., Dolezal, M., Zelinkova, Z., Crews, C., 2011. Formation and occurrence of esters of 3-chloropropane-1,2-diol (3- CPD) in foods: What we know and what we assume. Eur. J. Lipid Sci. Technol. 113(3): 279– 303.
  • European Commission. Commission Regulation (EC), 2001. Setting maximum levels for certain contaminants in foodstuffs No. L77: 1– 13.
  • Kim, H.Y., Lee, S.B., Lim, K.T., Kim, M.K., Kim, J.C., 2007. Subchronic inhalation toxicity study of 1,3-dichloro-2-propanol in rats. Ann. Occup. Hyg. 51(7): 633–643.
  • IARC, 2012. 1,3-Dichloro-2-propanol, International Agency for Research on Cancer(IARC), IARC Monographs on the Evaluation of the Carcinogenic Risks /mono101-011.pdf> (Erişim Tarihi: 01.08.2016).
  • Svejskovska, B., Novotný, O., Divinová, M., Réblová, Z., 2004. Esters of 3-chloropropane-1,2- diol in foodstuffs. Czech J. Food Sci. 22(5): 190– 196.
  • Chung, S.W.C., Kwong, K.P., Yau, J.C.W., Wong, A.M.C., Xiao, Y., 2008. Chloropropanols levels in foodstuffs marketed in Hong Kong. Journal of Food Composition and Analysis 21: 569-573.
  • Zelinkova, Z., Novotny, O., Schurek, J., Velíšek, J., Haslova, J., Dolezal, M., 2006. Occurrence of 3- MCPD fatty acid esters in human breast milk. Food Additives and Contaminants 25 (06):669–679.
  • Dingel, A., Matlssek, R., 2015. Esters of 3- monochloropropane-1,2-diol formation by deep frying during large scale production of potato crisps. Eur. Food Res. Technol. 241(5): 719–723. and glycidol: no
  • Zelinkova, Z., Velíšek, J., Dolezal, M., 2009.3- Chloropropane-1,2-diol fatty acid esters in potato products. Czech J. Food. Sci. 27: 421-424.
  • Vicente, E., Arisseto, A.P., Furlani, R.P.Z., Monteiro, V., Gonçalves, L.M., Pereira, A.L.D., Toledo, monochloropropane-1,2-diol (3-MCPD) in selected processed foods from the Brazilian market. Food Research International 77: 310-314. of 3
  • DGF, 2009. German Standard Methods for the Analysis of Fats and other Lipids: C-III 18 (09), Ester-bound 3-chloropropane-1,2-diol (3-MCPD- Esters) and glycidol (glycidyl esters): Determination in fats and oils by GC-MS, WVG.
There are 21 citations in total.

Details

Primary Language Turkish
Journal Section Research Article
Authors

Begüm Önal This is me

Onur Özdikicierler This is me

Fahri Yemişçioğlu This is me

Publication Date September 1, 2016
Published in Issue Year 2016 Volume: 14 Issue: 3

Cite

APA Önal, B., Özdikicierler, O., & Yemişçioğlu, F. (2016). Türkiye Piyasasında Satışa Sunulan Patates Cipslerinde 3-MCPD Esterleri ve Glisidil Esterleri Miktarları. Akademik Gıda, 14(3), 267-274.
AMA Önal B, Özdikicierler O, Yemişçioğlu F. Türkiye Piyasasında Satışa Sunulan Patates Cipslerinde 3-MCPD Esterleri ve Glisidil Esterleri Miktarları. Akademik Gıda. September 2016;14(3):267-274.
Chicago Önal, Begüm, Onur Özdikicierler, and Fahri Yemişçioğlu. “Türkiye Piyasasında Satışa Sunulan Patates Cipslerinde 3-MCPD Esterleri Ve Glisidil Esterleri Miktarları”. Akademik Gıda 14, no. 3 (September 2016): 267-74.
EndNote Önal B, Özdikicierler O, Yemişçioğlu F (September 1, 2016) Türkiye Piyasasında Satışa Sunulan Patates Cipslerinde 3-MCPD Esterleri ve Glisidil Esterleri Miktarları. Akademik Gıda 14 3 267–274.
IEEE B. Önal, O. Özdikicierler, and F. Yemişçioğlu, “Türkiye Piyasasında Satışa Sunulan Patates Cipslerinde 3-MCPD Esterleri ve Glisidil Esterleri Miktarları”, Akademik Gıda, vol. 14, no. 3, pp. 267–274, 2016.
ISNAD Önal, Begüm et al. “Türkiye Piyasasında Satışa Sunulan Patates Cipslerinde 3-MCPD Esterleri Ve Glisidil Esterleri Miktarları”. Akademik Gıda 14/3 (September 2016), 267-274.
JAMA Önal B, Özdikicierler O, Yemişçioğlu F. Türkiye Piyasasında Satışa Sunulan Patates Cipslerinde 3-MCPD Esterleri ve Glisidil Esterleri Miktarları. Akademik Gıda. 2016;14:267–274.
MLA Önal, Begüm et al. “Türkiye Piyasasında Satışa Sunulan Patates Cipslerinde 3-MCPD Esterleri Ve Glisidil Esterleri Miktarları”. Akademik Gıda, vol. 14, no. 3, 2016, pp. 267-74.
Vancouver Önal B, Özdikicierler O, Yemişçioğlu F. Türkiye Piyasasında Satışa Sunulan Patates Cipslerinde 3-MCPD Esterleri ve Glisidil Esterleri Miktarları. Akademik Gıda. 2016;14(3):267-74.

25964   25965    25966      25968   25967


88x31.png

Bu eser Creative Commons Atıf-GayriTicari 4.0 (CC BY-NC 4.0) Uluslararası Lisansı ile lisanslanmıştır.

Akademik Gıda (Academic Food Journal) is licensed under a Creative Commons Attribution-NonCommercial 4.0 International (CC BY-NC 4.0).