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Micellar Liquid Chromatography MLC as an Environmental Friendly Anaylsis Method and Its Applications on Food Analyses

Year 2012, Volume: 10 Issue: 3, 57 - 62, 01.09.2012

Abstract

Micellar liquid chromatography MLC is a liquid chromatographic mode with mobile phases containing a surfactant above its critical micelle concentration. In MLC, surfactant concentrations in excess of the critical micelle concentration are used so that micelles are formed in the mobile phase. Depending on the type of surfactant and properties of the mobile phase concentration, ionic strength, temperature, and pressure , the shape of micelles is different. The most commonly used surfactant in MLC is sodium dodecyl sulfate SDS . Micellar phase has some advantages over other phases, including low cost, low toxicity, the possibility of separation of ionic and non-ionic compounds on the same analytical run and the reduced environmental impact. One of the main disadvantages of the micellar chromatography, the mobile phase should be continuously flushed through the chromatographic system. Daily cleaning and re-equilibration of column takes more time compared to reverse-phase chromatography and sometimes, column may be damaged. Micellar chromatography is widely used in food analyses. This review presents micellar chromatographic applications on food analyses

References

  • Lough, W.J.,Wainer, I.W., 1996. High Performance Liquid Chromatography, Fundamental Principles and Practice. 276 p. Blackie Academic & Professional London-New York.
  • Snyder, L., Kirkland, J., Glajch, J.L., 1997. HPLC Method Development. 767 p. Wiley-Interscience. New York, USA.
  • Dong, M. W., 2006. Modern HPLC for practicing scientists. 306 p. John Wiley&Sons, Inc., New Jersey USA.
  • Dalsgaard, H., Abbotts A. W., 2003. Improving Energy Efficiency. p. 16-30. Environmentally friendly food processing. 338 p., Published by Woodhead Publishing Limited England.
  • Richards, D.J., Frosch, R.A., 2003. The industrial green game: overview and perspectives. p.1-37. The Industrial Green Game. National Academy Press, USA.
  • Warner, J.C., Cannon, A.S., Dye, K.M., 2004. Green Assessment Review 24 (7-8): 775-799. Environmental Impact
  • Meyer V.R., 2004. Practical High Performance Liquid Chromatography, Fourth Edition. 351 p.Wiley-VCH Verlag GmbH&Co, Federal Republic of Germany.
  • Cleveland, C.J., Stern, D.I., Costanza, R., 2001. The economics of nature and the nature of economics, International Society for Ecological Economies, Edward Elgar Publishing, 293 p. Great Britain.
  • Jimenez, M.S., Velarte, R., Castillo, J., 2005. Direct determination of phenolic compounds and phospholipids in virgin olive oil by micellar liquid chromatography. Food Chemistry 100 (1): 8-14.
  • Momenbeik, F., Khorasani, J.H,. 2006. Analysis of sugars by micellar liquid chromatography with UV detection. Acta Chromatographica 16: 58-69.
  • Salvador, A., Chisvert, A., 2005. An environmentally friendly chromatography method for UV filters determination in cosmetics. Analytica Chimica Acta 537: 15-24.
  • Nagae N., Enami T., Kobayashi H., 2002. The retention behavior of reversed-phase HPLC columns when used under 100% aqueous mobile phase conditions. LCGC North America, 20 (10):964-972.
  • Berthod, A., Garcia-Alvarez-Coque, M.C., 2000. Micellar Liquid Chromatography. 622 p. Marcel Dekker Inc. Newyork.
  • Ruiz-Angel, M.J.,Caballero, R.D., Simo-Alfonso, E.F., Garcia-Alvarez-Coque, M.C., 2002. Micellar liquid chromatography: suitable technique for screening analysis. Journal of Chromatography A 947(1): 31-45. [15] Pyell, U., 2001. Micellar electrokinetic
  • chromatography-from theoretical concepts to real
  • samples-review, Fresenius Journal of Analytical
  • Chemistry 371(6): 691-703.
  • Berthod, A., 1997. Causes and remediation of reduced chromatography. Journal of Chromatography A780 (1-2): 191-206. in micellar liquid
  • Thomas, D.P., 2009. Efficiency enhancements in micellar liquid chromatography through selection of stationary phase and mobile phase organic modifier. Ph. D Thesis, Drexel University, 209 pp.
  • Jandera, P., Fischer, J., 1996. Chromatographic behaviour in reversed-phase high-performance liquid chromatography with micellar and submicellar mobile phases. Journal of Chromatography A728 (1996): 279-298.
  • Garcia, M.C., Torres-Lapasio, J.R., 2002. Hybrid Micellar Chromatography, p.736-742, Marcel Dekker Inc. Newyork. Encyclopedia of
  • Monferrer-Pons, L., Capella-Peiro, M.E., Gil-Agusti, M., Esteve-Romero, J., 2003. Micellar liquid chromatography determination of B vitamins with direct injection and ultraviolet absorbance detection. Journal of Chromatography A 984(2): 223-231.
  • Thomas, D.P.,Foley, J.P., 2008. Improved efficiency in micellar liquid chromatography using triethylamine and 1-butanol as mobile phase additives to reduce surfactant adsorption. Journal of Chromatography A 1205:36–45.
  • Vidotti C.E., Costa W.F., Oliveira, C.C., 2005. Development of a green chromatographic method for determination of colorants in food samples, Talanta 68 (3): 516-521.
  • Paleologos, E.K., Chytiri, S.D., Savvaidis, I.N., Kontominas, M.G., 2003. Determination of biogenic amines as their benzoyl derivatives after cloudpoint extraction with micellar liquid chromatographic separation. 1010:217–224. Chromatography A
  • Szymański, A., Rykowska, I., Wasiak, W., 2006. Determination of bisphenol a in water and milk by micellar Chromatographica 17:161-172. Acta
  • Noguera-Orti, J.F., Villanueva-Camañas, R.M., Ramis-Ramos, G.,1999. Determination of phenolic antioxidants in vegetable and animal fats without previous extraction by dilution with n-propanol and micellar liquid chromatography. Analytica Chimica Acta 402: 81–86.
  • Raviolo, M.A., Rambla-Alegre, M., Clausell-Tormos, J., Capella-Peiro, M.E., Carda- Broch, S., Esteve- Romero, J., 2003. Determination of sulfonamides in milk after precolumn derivatisation by micellar liquid chromatography. Analytica Chimica Acta 593:152– 156.
  • Rambla-Alegre, M., Peris-Vicente, J., Marco-Peiro, S., Beltran-Martinavarro B., Esteve-Romero, J., 2010. Development of an analytical methodology to quantify melamine in milk using micellar liquid chromatography and validation according to EU Regulation 2002/654/EC.Talanta 81: 894–900.
  • Chin-Chen, M., Bose, D., Esteve-Romero, J., Peris- Vicente,J., Broch,S.,2011. Determination of putrescine and tyramine in fish by micellar liquid chromatography with UV detection using direct injection, The Open Analytical Chemistry Journal 5:22-26. Carda
  • Memon, N., Bhanger, M.I., Khuhawer, M.Y., 2005. Determination of preservatives in cosmetics and food samples by micellar liquid chromatography. Journal of Separation Science 28 (7):635-638.
  • Szymanski, A., 2008. Determination of sulfonamide residues in food by micellar liquid chromatography. Toxicology Mechanisms and Methods 18:473–481.
  • Delgado, M.A.R., Siinchez, M.J., Eonzilez, V., Montelongo, F.G., 1994. Influence of alcoholic modifiers on the selectivity of these paration of a group of polycyclic aromatic hydrocarbons by micellar liquid chromatography. Analytica Chimica Acta 298:423-430.
  • Ghorbani, A.R., Momenbeik, F., Khorasani, J.H., Amini, M.K., 2004. Simultaneous micellar liquid chromatographic analysis of seven water-soluble vitamins: simplex. Analytical and Bioanalytical Chemistry 379: 439-444. using super-modified
  • Gil-Agustí, M., Alvarez-Rodríguez, L., Monferrer- Pons, L., Bose, D., Durgbanshi A., Esteve-Romero, J., 2002. Chromatographic determination of carbaryl and other carbamates in formulations and water using brij-35. Analytical Letters 35 (10): 1721- 1734.
  • Vílchez, J.L., Navalón, A., Araujo, L., Prieto, A., 2007. marbofloxacin in milk samples by micellar liquid chromatography with fluorescence detection. Analytical Letters 40 (3): 601-613. and
  • Noguera-Orti, J.F., Villanueva-Camañas, R.M., Ramis-Ramos, G., 2000. Determination of synthetic antioxidants in dairy products and dietetic supplements by micellar liquid chromatography with direct sample injection.Chromatographia51 (1-2): 53-60.
  • Caballero, R.D., Torres-Lapasió, J.R., Baeza-Baeza J.J., García-Alvarez-Coque, M.C., 2001. Micellar chromatographic procedure with direct injection for the determination of sulfonamides in milk and honey samples. Journal of Liquid Chromatography & Related Technologies 24 (1): 117-131.
  • Momenbeik, F., Momeni, Z., Khorasani, J.H., 2005. Separation and determination of vitamins E and A in multivitamin syrup using micellar liquid chromatography and simplex optimization. Journal of Pharmaceutical and Biomedical Analysis 37(2): 383-387.
  • Ruiz-Angel, M.J., Garcia-Alvarez-Coque, M.C., 2008. Micellar liquid chromatography: How to start. LCGC http://www.chromatographyonline.com/lcgc/Micellar -Liquid-Chromatography-How-to- Start/ArticleStandard/Article/detail/549199. 9.
  • Gil-Agusti, M., Esteve-Romero, J., Carda-Broch, S., 2008. Anserine and carnosine determination in meat chromatography. Journal of Chromatography A 1189 (1-2): 444-450. pure micellar liquid

Çevre Dostu Bir Analiz Tekniği Olarak Misellar Sıvı Kromatografisi ve Gıda Analizlerinde Kullanımı

Year 2012, Volume: 10 Issue: 3, 57 - 62, 01.09.2012

Abstract

Misellar sıvı kromatografisi MSK , taşıyıcı fazın kritik misel konsantrasyonunun üzerinde yüzey aktif madde içerdiği bir sıvı kromatografisi yöntemidir. Misellar sıvı kromatografisinde kullanılan yüzey aktif maddelerin konsantrasyonu kritik misel konsantrasyonunu aştığında taşıyıcı fazda miseller oluşmaya başlar. Kullanılan yüzey aktif madde ve taşıyıcı fazın özelliklerine konsantrasyon, iyonik güç, sıcaklık, basınç bağlı olarak oluşan miseller de farklıdır. En yaygın olarak kullanılan yüzey aktif madde sodyum dodesil sülfattır. Misellar taşıyıcı faz düşük toksisite, düşük maliyet, aynı analitik çalışmada iyonik ve iyonik olmayan analitlerin eşzamanlı belirlenmesini sağlama ve çevreye olan olumsuz etkilerin azaltılması gibi bazı avantajlara sahiptir. En önemli dezavantajlarından biri ise taşıyıcı fazın kromatografik sistemden sürekli akıtılmak zorunda olunmasıdır. Günlük kolon temizliği ve kolon şartlandırılması ters faz sıvı kromatografisine kıyasla daha çok zaman alır ve bazen kolon zarar görebilir. Misellar kromatografi gıda analizlerinde yaygın olarak kullanılmaktadır. Bu derlemede MSK’nin gıda analizlerindeki uygulamaları hakkında bilgi verilmiştir

References

  • Lough, W.J.,Wainer, I.W., 1996. High Performance Liquid Chromatography, Fundamental Principles and Practice. 276 p. Blackie Academic & Professional London-New York.
  • Snyder, L., Kirkland, J., Glajch, J.L., 1997. HPLC Method Development. 767 p. Wiley-Interscience. New York, USA.
  • Dong, M. W., 2006. Modern HPLC for practicing scientists. 306 p. John Wiley&Sons, Inc., New Jersey USA.
  • Dalsgaard, H., Abbotts A. W., 2003. Improving Energy Efficiency. p. 16-30. Environmentally friendly food processing. 338 p., Published by Woodhead Publishing Limited England.
  • Richards, D.J., Frosch, R.A., 2003. The industrial green game: overview and perspectives. p.1-37. The Industrial Green Game. National Academy Press, USA.
  • Warner, J.C., Cannon, A.S., Dye, K.M., 2004. Green Assessment Review 24 (7-8): 775-799. Environmental Impact
  • Meyer V.R., 2004. Practical High Performance Liquid Chromatography, Fourth Edition. 351 p.Wiley-VCH Verlag GmbH&Co, Federal Republic of Germany.
  • Cleveland, C.J., Stern, D.I., Costanza, R., 2001. The economics of nature and the nature of economics, International Society for Ecological Economies, Edward Elgar Publishing, 293 p. Great Britain.
  • Jimenez, M.S., Velarte, R., Castillo, J., 2005. Direct determination of phenolic compounds and phospholipids in virgin olive oil by micellar liquid chromatography. Food Chemistry 100 (1): 8-14.
  • Momenbeik, F., Khorasani, J.H,. 2006. Analysis of sugars by micellar liquid chromatography with UV detection. Acta Chromatographica 16: 58-69.
  • Salvador, A., Chisvert, A., 2005. An environmentally friendly chromatography method for UV filters determination in cosmetics. Analytica Chimica Acta 537: 15-24.
  • Nagae N., Enami T., Kobayashi H., 2002. The retention behavior of reversed-phase HPLC columns when used under 100% aqueous mobile phase conditions. LCGC North America, 20 (10):964-972.
  • Berthod, A., Garcia-Alvarez-Coque, M.C., 2000. Micellar Liquid Chromatography. 622 p. Marcel Dekker Inc. Newyork.
  • Ruiz-Angel, M.J.,Caballero, R.D., Simo-Alfonso, E.F., Garcia-Alvarez-Coque, M.C., 2002. Micellar liquid chromatography: suitable technique for screening analysis. Journal of Chromatography A 947(1): 31-45. [15] Pyell, U., 2001. Micellar electrokinetic
  • chromatography-from theoretical concepts to real
  • samples-review, Fresenius Journal of Analytical
  • Chemistry 371(6): 691-703.
  • Berthod, A., 1997. Causes and remediation of reduced chromatography. Journal of Chromatography A780 (1-2): 191-206. in micellar liquid
  • Thomas, D.P., 2009. Efficiency enhancements in micellar liquid chromatography through selection of stationary phase and mobile phase organic modifier. Ph. D Thesis, Drexel University, 209 pp.
  • Jandera, P., Fischer, J., 1996. Chromatographic behaviour in reversed-phase high-performance liquid chromatography with micellar and submicellar mobile phases. Journal of Chromatography A728 (1996): 279-298.
  • Garcia, M.C., Torres-Lapasio, J.R., 2002. Hybrid Micellar Chromatography, p.736-742, Marcel Dekker Inc. Newyork. Encyclopedia of
  • Monferrer-Pons, L., Capella-Peiro, M.E., Gil-Agusti, M., Esteve-Romero, J., 2003. Micellar liquid chromatography determination of B vitamins with direct injection and ultraviolet absorbance detection. Journal of Chromatography A 984(2): 223-231.
  • Thomas, D.P.,Foley, J.P., 2008. Improved efficiency in micellar liquid chromatography using triethylamine and 1-butanol as mobile phase additives to reduce surfactant adsorption. Journal of Chromatography A 1205:36–45.
  • Vidotti C.E., Costa W.F., Oliveira, C.C., 2005. Development of a green chromatographic method for determination of colorants in food samples, Talanta 68 (3): 516-521.
  • Paleologos, E.K., Chytiri, S.D., Savvaidis, I.N., Kontominas, M.G., 2003. Determination of biogenic amines as their benzoyl derivatives after cloudpoint extraction with micellar liquid chromatographic separation. 1010:217–224. Chromatography A
  • Szymański, A., Rykowska, I., Wasiak, W., 2006. Determination of bisphenol a in water and milk by micellar Chromatographica 17:161-172. Acta
  • Noguera-Orti, J.F., Villanueva-Camañas, R.M., Ramis-Ramos, G.,1999. Determination of phenolic antioxidants in vegetable and animal fats without previous extraction by dilution with n-propanol and micellar liquid chromatography. Analytica Chimica Acta 402: 81–86.
  • Raviolo, M.A., Rambla-Alegre, M., Clausell-Tormos, J., Capella-Peiro, M.E., Carda- Broch, S., Esteve- Romero, J., 2003. Determination of sulfonamides in milk after precolumn derivatisation by micellar liquid chromatography. Analytica Chimica Acta 593:152– 156.
  • Rambla-Alegre, M., Peris-Vicente, J., Marco-Peiro, S., Beltran-Martinavarro B., Esteve-Romero, J., 2010. Development of an analytical methodology to quantify melamine in milk using micellar liquid chromatography and validation according to EU Regulation 2002/654/EC.Talanta 81: 894–900.
  • Chin-Chen, M., Bose, D., Esteve-Romero, J., Peris- Vicente,J., Broch,S.,2011. Determination of putrescine and tyramine in fish by micellar liquid chromatography with UV detection using direct injection, The Open Analytical Chemistry Journal 5:22-26. Carda
  • Memon, N., Bhanger, M.I., Khuhawer, M.Y., 2005. Determination of preservatives in cosmetics and food samples by micellar liquid chromatography. Journal of Separation Science 28 (7):635-638.
  • Szymanski, A., 2008. Determination of sulfonamide residues in food by micellar liquid chromatography. Toxicology Mechanisms and Methods 18:473–481.
  • Delgado, M.A.R., Siinchez, M.J., Eonzilez, V., Montelongo, F.G., 1994. Influence of alcoholic modifiers on the selectivity of these paration of a group of polycyclic aromatic hydrocarbons by micellar liquid chromatography. Analytica Chimica Acta 298:423-430.
  • Ghorbani, A.R., Momenbeik, F., Khorasani, J.H., Amini, M.K., 2004. Simultaneous micellar liquid chromatographic analysis of seven water-soluble vitamins: simplex. Analytical and Bioanalytical Chemistry 379: 439-444. using super-modified
  • Gil-Agustí, M., Alvarez-Rodríguez, L., Monferrer- Pons, L., Bose, D., Durgbanshi A., Esteve-Romero, J., 2002. Chromatographic determination of carbaryl and other carbamates in formulations and water using brij-35. Analytical Letters 35 (10): 1721- 1734.
  • Vílchez, J.L., Navalón, A., Araujo, L., Prieto, A., 2007. marbofloxacin in milk samples by micellar liquid chromatography with fluorescence detection. Analytical Letters 40 (3): 601-613. and
  • Noguera-Orti, J.F., Villanueva-Camañas, R.M., Ramis-Ramos, G., 2000. Determination of synthetic antioxidants in dairy products and dietetic supplements by micellar liquid chromatography with direct sample injection.Chromatographia51 (1-2): 53-60.
  • Caballero, R.D., Torres-Lapasió, J.R., Baeza-Baeza J.J., García-Alvarez-Coque, M.C., 2001. Micellar chromatographic procedure with direct injection for the determination of sulfonamides in milk and honey samples. Journal of Liquid Chromatography & Related Technologies 24 (1): 117-131.
  • Momenbeik, F., Momeni, Z., Khorasani, J.H., 2005. Separation and determination of vitamins E and A in multivitamin syrup using micellar liquid chromatography and simplex optimization. Journal of Pharmaceutical and Biomedical Analysis 37(2): 383-387.
  • Ruiz-Angel, M.J., Garcia-Alvarez-Coque, M.C., 2008. Micellar liquid chromatography: How to start. LCGC http://www.chromatographyonline.com/lcgc/Micellar -Liquid-Chromatography-How-to- Start/ArticleStandard/Article/detail/549199. 9.
  • Gil-Agusti, M., Esteve-Romero, J., Carda-Broch, S., 2008. Anserine and carnosine determination in meat chromatography. Journal of Chromatography A 1189 (1-2): 444-450. pure micellar liquid
There are 41 citations in total.

Details

Primary Language Turkish
Journal Section Collection
Authors

Bülent Şık This is me

Taner Erkaymaz This is me

Gizem Yıldız This is me

Publication Date September 1, 2012
Published in Issue Year 2012 Volume: 10 Issue: 3

Cite

APA Şık, B., Erkaymaz, T., & Yıldız, G. (2012). Çevre Dostu Bir Analiz Tekniği Olarak Misellar Sıvı Kromatografisi ve Gıda Analizlerinde Kullanımı. Akademik Gıda, 10(3), 57-62.
AMA Şık B, Erkaymaz T, Yıldız G. Çevre Dostu Bir Analiz Tekniği Olarak Misellar Sıvı Kromatografisi ve Gıda Analizlerinde Kullanımı. Akademik Gıda. September 2012;10(3):57-62.
Chicago Şık, Bülent, Taner Erkaymaz, and Gizem Yıldız. “Çevre Dostu Bir Analiz Tekniği Olarak Misellar Sıvı Kromatografisi Ve Gıda Analizlerinde Kullanımı”. Akademik Gıda 10, no. 3 (September 2012): 57-62.
EndNote Şık B, Erkaymaz T, Yıldız G (September 1, 2012) Çevre Dostu Bir Analiz Tekniği Olarak Misellar Sıvı Kromatografisi ve Gıda Analizlerinde Kullanımı. Akademik Gıda 10 3 57–62.
IEEE B. Şık, T. Erkaymaz, and G. Yıldız, “Çevre Dostu Bir Analiz Tekniği Olarak Misellar Sıvı Kromatografisi ve Gıda Analizlerinde Kullanımı”, Akademik Gıda, vol. 10, no. 3, pp. 57–62, 2012.
ISNAD Şık, Bülent et al. “Çevre Dostu Bir Analiz Tekniği Olarak Misellar Sıvı Kromatografisi Ve Gıda Analizlerinde Kullanımı”. Akademik Gıda 10/3 (September 2012), 57-62.
JAMA Şık B, Erkaymaz T, Yıldız G. Çevre Dostu Bir Analiz Tekniği Olarak Misellar Sıvı Kromatografisi ve Gıda Analizlerinde Kullanımı. Akademik Gıda. 2012;10:57–62.
MLA Şık, Bülent et al. “Çevre Dostu Bir Analiz Tekniği Olarak Misellar Sıvı Kromatografisi Ve Gıda Analizlerinde Kullanımı”. Akademik Gıda, vol. 10, no. 3, 2012, pp. 57-62.
Vancouver Şık B, Erkaymaz T, Yıldız G. Çevre Dostu Bir Analiz Tekniği Olarak Misellar Sıvı Kromatografisi ve Gıda Analizlerinde Kullanımı. Akademik Gıda. 2012;10(3):57-62.

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